Synthesis of diblock and triblock copolymers containing dendrons via ?living? controlled radical polymerization

2002 ◽  
Vol 51 (12) ◽  
pp. 1334-1339 ◽  
Author(s):  
You-Liang Zhao ◽  
Jing Jiang ◽  
Chuan-Fu Chen ◽  
Fu Xi
Keyword(s):  
Radical Polymerization ◽  
Triblock Copolymers ◽  
Controlled Radical Polymerization ◽  
Living Controlled Radical Polymerization

Cyclodextrin-Complexed RAFT Agents for the Ambient Temperature Aqueous Living/Controlled Radical Polymerization of Acrylamido Monomers

2011 ◽  
Vol 44 (18) ◽  
pp. 7220-7232 ◽  
Author(s):  
Bernhard V. K. J. Schmidt ◽  
Martin Hetzer ◽  
Helmut Ritter ◽  
Christopher Barner-Kowollik
Keyword(s):  
Ambient Temperature ◽  
Radical Polymerization ◽  
Controlled Radical Polymerization ◽  
Living Controlled Radical Polymerization

scholarly journals The living dead – common misconceptions about reversible deactivation radical polymerization

2016 ◽  
Vol 3 (6) ◽  
pp. 471-477 ◽  
Author(s):  
Martina H. Stenzel ◽  
Christopher Barner-Kowollik
Keyword(s):  
Radical Polymerization ◽  
Soft Matter ◽  
Controlled Radical Polymerization ◽  
Reversible Deactivation ◽  
Living Dead ◽  
Reversible Deactivation Radical Polymerization ◽  
Living Controlled Radical Polymerization ◽  
Common Misconceptions

We illustrate common misconceptions and errors when interpreting polymerization data from ‘Living/controlled’ radical polymerization, preferably termed ‘reversible deactivation radical polymerization’ (RDRP). Avoiding the discussed errors leads to better defined materials for soft matter materials applications.

Synthesis and thermal properties of triblock copolymers of methyl methacrylate using combination of anionic and controlled radical polymerization: Poly(methyl methacrylate) center block bearing different microstructures

e-Polymers ◽  
2012 ◽  
Vol 12 (1) ◽  
Author(s):  
Zhengji Song ◽  
Carole Pelletier ◽  
Yinghua Qi ◽  
Jasim Ahmed ◽  
Sunil K. Varshney ◽  
...  
Keyword(s):  
Molecular Weight ◽  
Thermal Properties ◽  
Block Copolymers ◽  
Methyl Methacrylate ◽  
Radical Polymerization ◽  
Triblock Copolymers ◽  
Controlled Radical Polymerization ◽  
Alkyl Methacrylate ◽  
Poly Methyl Methacrylate ◽  
H Nmr

AbstractABA and/or ABC type triblock copolymers were synthesized by living anionic and controlled radical polymerization in which poly(methyl methacrylate) was used as central block. The structural composition of these block copolymers were determined by 1H NMR. The block length/molecular weight and microstructure of these polymers were measured by SEC. The microstructure of resultant central alkyl methacrylate block can be tailored from highly syndiotactic to highly isotactic structure by varying the solvent and/or initiator. The thermal and rheological properties of center poly(methyl methacrylate) block and poly(styreneb- methyl methacrylate-b- styrene) tri block copolymers were studied in detail.

scholarly journals A well-defined, versatile photoinitiator (salen)Co–CO2CH3 for visible light-initiated living/controlled radical polymerization

2015 ◽  
Vol 6 (5) ◽  
pp. 2979-2988 ◽  
Author(s):  
Yaguang Zhao ◽  
Mengmeng Yu ◽  
Shuailin Zhang ◽  
Zhenqiang Wu ◽  
Yuchu Liu ◽  
...  
Keyword(s):  
Visible Light ◽  
Radical Polymerization ◽  
Living Radical Polymerization ◽  
Controlled Radical Polymerization ◽  
Salen Complex ◽  
Living Controlled Radical Polymerization

A well-defined organocobalt salen complex (salen)Co–CO2CH3 is used as a versatile photoinitiator for visible light-initiated living radical polymerization.

Double thermoresponsive di- and triblock copolymers based on N-vinylcaprolactam and N-vinylpyrrolidone: synthesis and comparative study of solution behaviour

2014 ◽  
Vol 5 (22) ◽  
pp. 6534-6544 ◽  
Author(s):  
Anthony Kermagoret ◽  
Kevin Mathieu ◽  
Jean-Michel Thomassin ◽  
Charles-André Fustin ◽  
Roland Duchêne ◽  
...  
Keyword(s):  
Comparative Study ◽  
Radical Polymerization ◽  
Triblock Copolymers ◽  
Controlled Radical Polymerization ◽  
Thermally Induced ◽  
Solution Behaviour

Controlled radical polymerization produces poly(N-vinylamide)s with thermally induced multistep assembly.

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