An rht-type metal–organic framework constructed from an unsymmetrical ligand exhibiting high hydrogen uptake capability

In the field of energy storage, recently investigated nanocomposites show promise in terms of high hydrogen uptake and release with enhancement in the reaction kinetics. Among several, carbonaceous nanovariants like carbon nanotubes (CNTs), fullerenes, and graphitic nanofibers reveal reversible hydrogen sorption characteristics at 77 K, due to their van der Waals interaction. The spillover mechanism combining Pd nanoparticles on the host metal-organic framework (MOF) show room temperature uptake of hydrogen. Metal or complex hydrides either in the nanocomposite form and its subset, nanocatalyst dispersed alloy phases illustrate the concept of nanoengineering and nanoconfinement of particles with tailor-made properties for reversible hydrogen storage. Another class of materials comprising polymeric nanostructures such as conducting polyaniline and their functionalized nanocomposites are versatile hydrogen storage materials because of their unique size, high specific surface-area, pore-volume, and bulk properties. The salient features of nanocomposite materials for reversible hydrogen storage are reviewed and discussed.

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Realization of both high hydrogen selectivity and capacity in a guest responsive metal–organic framework

Journal of Materials Chemistry A ◽

10.1039/c3ta12761c ◽

2013 ◽

Vol 1 (43) ◽

pp. 13502 ◽

Cited By ~ 5

Author(s):

Trevor A. Makal ◽

Wenjuan Zhuang ◽

Hong-Cai Zhou

Keyword(s):

Metal Organic Framework ◽

High Hydrogen ◽

Metal Organic ◽

Hydrogen Selectivity ◽

Selectivity And Capacity ◽

Organic Framework

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Mixed-linker approach in designing porous zirconium-based metal–organic frameworks with high hydrogen storage capacity

Chemical Communications ◽

10.1039/c6cc03787a ◽

2016 ◽

Vol 52 (50) ◽

pp. 7826-7829 ◽

Cited By ~ 18

Author(s):

Ayesha Naeem ◽

Valeska P. Ting ◽

Ulrich Hintermair ◽

Mi Tian ◽

Richard Telford ◽

...

Keyword(s):

Hydrogen Storage ◽

High Selectivity ◽

Storage Capacity ◽

Metal Organic Framework ◽

Metal Organic Frameworks ◽

Hydrogen Uptake ◽

Hydrogen Storage Capacity ◽

High Hydrogen ◽

Metal Organic ◽

Adsorption Of Co

New zirconium based metal–organic framework (UBMOF-31) synthesised using mixed-linker strategy showing permanent porosity, excellent hydrogen uptake, and high selectivity for adsorption of CO2 over N2.

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Inside Cover: Molecular Sieve Membrane: Supported Metal-Organic Framework with High Hydrogen Selectivity (Angew. Chem. Int. Ed. 3/2010)

Angewandte Chemie International Edition ◽

10.1002/anie.200906852 ◽

2009 ◽

Vol 49 (3) ◽

pp. 464-464 ◽

Cited By ~ 7

Author(s):

Yan-Shuo Li ◽

Fang-Yi Liang ◽

Helge Bux ◽

Armin Feldhoff ◽

Wei-Shen Yang ◽

...

Keyword(s):

Molecular Sieve ◽

Metal Organic Framework ◽

High Hydrogen ◽

Metal Organic ◽

Hydrogen Selectivity ◽

Organic Framework ◽

Supported Metal

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Hydrogen Uptake by an Inclined Polycatenated Dynamic Metal–Organic Framework Based Material

Inorganic Chemistry ◽

10.1021/acs.inorgchem.6b02719 ◽

2016 ◽

Vol 56 (2) ◽

pp. 713-716 ◽

Cited By ~ 20

Author(s):

Dilip Kumar Maity ◽

Arijit Halder ◽

Goutam Pahari ◽

Fazle Haque ◽

Debajyoti Ghoshal

Keyword(s):

Metal Organic Framework ◽

Hydrogen Uptake ◽

Metal Organic ◽

Organic Framework

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High Hydrogen Release Catalytic Activity by Quasi-MOF Prepared via Post-Synthetic Pore Engineering

Sustainable Energy & Fuels ◽

10.1039/d1se00661d ◽

2021 ◽

Author(s):

Minoo Bagheri ◽

Mohammad Yaser Mohammad Yaser Masoomi ◽

Esther Dominguez ◽

Hermenegildo Garcia

Keyword(s):

Catalytic Activity ◽

Metal Organic Framework ◽

Hydrogen Release ◽

Structural Defects ◽

High Hydrogen ◽

Metal Organic ◽

Organic Framework

The catalytic activity of metal-organic framewroks (MOFs) depends largely on the presence of structural defects. In the present stuyd, cobalt based metal-organic framework TMU-10, [Co6(oba)5(OH)2(H2O)2(DMF)4]n·2DMF has been submitted under controlled...

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