Dual metal nanoparticles within multicompartmentalized mesoporous organosilicas for efficient sequential hydrogenation

Controlling localization of multiple metal nanoparticles on a single support is at the cutting edge of designing cascade catalysts, but is still a scientific and technological challenge because of the lack of nanostructured materials that can not only host metal nanoparticles in different sub-compartments but also enable efficient molecular transport between different metals. Herein we report a multicompartmentalized mesoporous organosilica with spatially separated sub-compartments that are connected by short nanochannels. Such a unique structure allows co-localization of Ru and Pd nanoparticles in a nanoscale proximal fashion. The so designed cascade catalyst exhibits an order of magnitude activity enhancement in the sequential hydrogenation of nitroarenes to cyclohexylamines compared with its mono/bi-metallic counterparts. Crucially, an interesting phenomenon of neighboring metal-assisted hydrogenation via hydrogen spillover is observed, contributing to the significant enhancement in catalytic efficiency. The multicompartmentalized architectures along with the revealed mechanism of accelerated hydrogenation provide vast opportunity for designing efficient cascade catalysts.

Agent-Based Modeling for By-Product Metal Supply—A Case Study on Indium

With rapid development and deployment of clean energy technology, demand for certain minor metals has increased significantly. However, many such metals are by-products of various host metals and are economically infeasible to extract independently. Meanwhile, by-product metals present in the mined ores may not be extracted even if they are sent to smelters along with host metal concentrates if it is not economically favorable for the producers. This dependency poses potential supply risks to by-product metals. Indium is a typical by-product metal, mainly from zinc mining and refining, and is important for flat panel displays, high efficiency lighting, and emerging thin-film solar panel production. Current indium supply–demand forecast models tend to overlook the volatile and competitive nature of minor metal market and are mostly based on top-down approaches. Therefore, a bottom-up agent-based model can shed new light on the market dynamics and possible outcome of future indium supply–demand relationship. A multi-layered model would also be helpful for identifying possible bottlenecks of indium supply and finding solutions. This work takes indium as an example of minor metal market and sets up an agent-based model to predict future market situation and supply–demand balance. The market is modeled as a Cournot competition oligopolistic market by refineries with capacity restriction based on host metal production. The model maintains active Nash equilibrium each year to simulate competitions between suppliers. The model is validated and verified by historical data and sensitivity analysis. Several scenarios are also explored to illustrate possible uncertainties of the market.

An Evaluation of the Shielding Effectiveness of Tellurite Glass with Composition 85TeO2-5Nb2O5-5ZnO-5Ag2O for Diagnostic Radiology Application

The metal oxide glasses have attracted huge interest as promising types of shielding materials to replace the toxic, heavy and costly conventional shielding materials. In this work, the physical and the shielding effectiveness of Tellurite glass sample (S1) contain host metal oxides (85TeO2-5Nb2O5-5ZnO-5Ag2O) were evaluatedatphoton energies range between 15keVand1MeV.The shielding parameters of the proposed glass system such as linear attenuation coefficients, HVL, MFP, Zeff, and Neffwere evaluated. The proposed samples showed a superior performance at the diagnostic energy range between 40 and 90 keV and a comparable shielding effectiveness above 90keV when compared with other commercial standard shielding materials.

Host genotype and genetic diversity shape the evolution of a novel bacterial infection

Pathogens continue to emerge from increased contact with novel host species. Whilst these hosts can represent distinct environments for pathogens, the impacts of host genetic background on how a pathogen evolves post-emergence are unclear. In a novel interaction, we experimentally evolved a pathogen (Staphylococcus aureus) in populations of wild nematodes (Caenorhabditis elegans) to test whether host genotype and genetic diversity affect pathogen evolution. After ten rounds of selection, we found that pathogen virulence evolved to vary across host genotypes, with differences in host metal ion acquisition detected as a possible driver of increased host exploitation. Diverse host populations selected for the highest levels of pathogen virulence, but infectivity was constrained, unlike in host monocultures. We hypothesise that population heterogeneity might pool together individuals that contribute disproportionately to the spread of infection or to enhanced virulence. The genomes of evolved populations were sequenced, and it was revealed that pathogens selected in distantly-related host genotypes diverged more than those in closely-related host genotypes. S. aureus nevertheless maintained a broad host range. Our study provides unique empirical insight into the evolutionary dynamics that could occur in other novel infections of wildlife and humans.

Facilitating hydrogen atom migration via a dense phase on palladium islands to a surrounding silver surface

The migration of species across interfaces can crucially affect the performance of heterogeneous catalysts. A key concept in using bimetallic catalysts for hydrogenation is that the active metal supplies hydrogen atoms to the host metal, where selective hydrogenation can then occur. Herein, we demonstrate that, following dihydrogen dissociation on palladium islands, hydrogen atoms migrate from palladium to silver, to which they are generally less strongly bound. This migration is driven by the population of weakly bound states on the palladium at high hydrogen atom coverages which are nearly isoenergetic with binding sites on the silver. The rate of hydrogen atom migration depends on the palladium−silver interface length, with smaller palladium islands more efficiently supplying hydrogen atoms to the silver. This study demonstrates that hydrogen atoms can migrate from a more strongly binding metal to a more weakly binding surface under special conditions, such as high dihydrogen pressure.

Spin transition properties of metal (Zn, Mn) diluted Fe(phen)2(NCS)2 spin-crossover thin films

We report here the effect of metal (Zn and Mn) dilution on the spin transition of Fe(phen)2(NCS)2 thin film spin-crossover (SCO) complex. The SCO complexes are deposited on glass and indium-tin-oxide (ITO) coated glass by dip-coating technique. The growth of the films is clearly confirmed by the appearance of the sharp optical absorption band at 521–540 nm corresponding to 1A1g to 1T1g ligand field absorption of the SCO complex. Although the microstructure of the films remains unaffected by metal dilution, substitution of Fe(II) by either Zn(II) (diamagnetic) or Mn(II) (paramagnetic) results in subtle changes in the bonding environment of the host metal as inferred form X-ray diffraction and Raman studies. The high spin to low spin (or vice versa) transition can be triggered either by electric field or magnetic field as revealed in the measured current (I)–voltage (V) profile or magnetization data of the films. The data further shows the effect of metal dilution on the spin transition temperatures(T1/2), produced hysteresis loop width and loop area, which are the crucial parameter for fabricating spin-based room temperature switching devices.

Reversible Hydrogen Storage Using Nanocomposites

In the field of energy storage, recently investigated nanocomposites show promise in terms of high hydrogen uptake and release with enhancement in the reaction kinetics. Among several, carbonaceous nanovariants like carbon nanotubes (CNTs), fullerenes, and graphitic nanofibers reveal reversible hydrogen sorption characteristics at 77 K, due to their van der Waals interaction. The spillover mechanism combining Pd nanoparticles on the host metal-organic framework (MOF) show room temperature uptake of hydrogen. Metal or complex hydrides either in the nanocomposite form and its subset, nanocatalyst dispersed alloy phases illustrate the concept of nanoengineering and nanoconfinement of particles with tailor-made properties for reversible hydrogen storage. Another class of materials comprising polymeric nanostructures such as conducting polyaniline and their functionalized nanocomposites are versatile hydrogen storage materials because of their unique size, high specific surface-area, pore-volume, and bulk properties. The salient features of nanocomposite materials for reversible hydrogen storage are reviewed and discussed.

2D Layered Double Hydroxide Nanosheets and Their Derivatives Toward Efficient Oxygen Evolution Reaction

Layered double hydroxides (LDHs) have attracted tremendous research interest in widely spreading applications. Most notably, transition-metal-bearing LDHs are expected to serve as highly active electrocatalysts for oxygen evolution reaction (OER) due to their layered structure combined with versatile compositions. Furthermore, reducing the thickness of platelet LDH crystals to nanometer or even molecular scale via cleavage or delamination provides an important clue to enhance the activity. In this review, recent progresses on rational design of LDH nanosheets are reviewed, including direct synthesis via traditional coprecipitation, homogeneous precipitation, and newly developed topochemical oxidation as well as chemical exfoliation of parent LDH crystals. In addition, diverse strategies are introduced to modulate their electrochemical activity by tuning the composition of host metal cations and intercalated counter-anions, and incorporating dopants, cavities, and single atoms. In particular, hybridizing LDHs with conductive components or in situ growing them on conductive substrates to produce freestanding electrodes can further enhance their intrinsic catalytic activity. A brief discussion on future research directions and prospects is also summarized.

Metal for the masses: how indie metal labels have adapted for the digital era

One of the areas that has most readily adapted to the changing musical environment is within metal music culture. Dedicated fans have taken responsibility upon themselves to create smaller record labels that specialize both in bringing attention to new, rising bands, as well as to do the laborious work that is needed to make sure that historical, out-of-print metal albums continue to receive new listeners. Their dedication has resulted in tightly-woven communities between these labels, the bands, and music fans, and this has contributed to the resurgence of physical mediums including vinyl and cassettes. Strategies are discussed that help push sales of physical media, including the release of special and elaborate versions of albums, often with unique packaging, or with limited color variants of vinyl editions. This article includes interviews with individuals that run underground metal labels and that host metal music streams, and they share their experience of how metal has changed as the music industry and the consumption of music has moved into the digital era, and the pros and cons that come with that, including perceptions about streaming and streaming services. Comparisons are made between major corporate labels and indie record labels, and the proactive role of indie labels in keeping musical subcultures thriving is assessed.