Intriguing differences in hydrogen adsorption in CPO-27 materials induced by metal substitution

2015 ◽  
Vol 3 (9) ◽  
pp. 4827-4839 ◽  
Author(s):  
Mali H. Rosnes ◽  
Martin Opitz ◽  
Matthias Frontzek ◽  
Wiebke Lohstroh ◽  
Jan Peter Embs ◽  
...  
Keyword(s):  
Comparative Study ◽  
Gas Adsorption ◽  
Hydrogen Adsorption ◽  
Isosteric Heat ◽  
Heat Of Adsorption ◽  
Hydrogen Gas ◽  
The Other ◽  
Metal Substitution ◽  
Isosteric Heat Of Adsorption ◽  
Open Metal Sites

We present a comparative study of hydrogen gas adsorption experiments on CPO-27–Cu and –Mn. The initial isosteric heat of adsorption in CPO-27–Cu is low for a material containing open metal sites and in contrast to the other members of the CPO-27 series, including the Mn compound.

Determination of the Isosteric Heat of Adsorption of Hydrogen on the Multi-Walled Carbon Nanotubes

2012 ◽  
Vol 512-515 ◽  
pp. 1484-1491 ◽  
Author(s):  
Qing Rong Zheng ◽  
Shuai Gao ◽  
Chen Jie
Keyword(s):  
Carbon Nanotubes ◽  
Hydrogen Adsorption ◽  
Isosteric Heat ◽  
Heat Of Adsorption ◽  
Step Method ◽  
Surface Loading ◽  
Isosteric Heat Of Adsorption ◽  
Hydrogen Molecules ◽  
Multi Walled Carbon Nanotubes ◽  
Walled Carbon Nanotubes

The isosteric heat of adsorption was used to study the interaction between hydrogen molecules and the Multi-Walled Carbon Nanotubes (MWCNTs). Characterizations of the MWCNTs sample were carried out based on the N2 adsorption isotherm at 77 K and the images from TEM and HRTEM. Step by step method was used to volumetrically measure hydrogen adsorption isotherms at equilibrium temperature-pressures from 123-310 K and 0-12.3 MPa. Isosteric heats of adsorption at seven excess adsorption amounts and that at zero surface loading were respectively determined by the slopes of the adsorption isosteres and the plot of the temperature dependence of the Henry’s constants. Results show that the limit of the isosteric heat of adsorption at zero surface loading is about and the mean under the experimental condition is about . The values are in the same grade as those of hydrogen on the activated coconut charcoal but smaller than those of hydrogen on the graphitized carbon black P33, the activated carbon AX-21 and the Single-Walled Carbon Nanotubes (SWCNTs). Conclusions are drawn that relatively lower adsorption amounts and the isosteric heat of hydrogen adsorption on the MWCNTs could be ascribed to the small specific surface area and the large mesopores.

Equilibrium Analysis of Hydrogen Adsorption on Activated Carbon

2012 ◽  
Vol 472-475 ◽  
pp. 1652-1658
Author(s):  
Qing Rong Zheng ◽  
Shuai Gao ◽  
Chen Jie
Keyword(s):  
Activated Carbon ◽  
Hydrogen Storage ◽  
Surface Coverage ◽  
Hydrogen Adsorption ◽  
Isosteric Heat ◽  
Heat Of Adsorption ◽  
Equilibrium Analysis ◽  
Isosteric Heat Of Adsorption ◽  
Adsorption Data ◽  
Adsorption Isosteres

For developing carbon based adsorbents for hydrogen storage, Staram PCTPro E&E was employed and activated carbon SAC-02 having specific surface area about 2074m2/g was selected to measure isotherms of hydrogen adsorption respectively from temperature range 77.15K-110.15K and 253.15K-293.15K. Isosteres of hydrogen adsorption on the activated carbon was then plotted to determine the isosteric heat of hydrogen adsorption, and temperature dependent of Henry law constants were further applied to set the limit isosteric heat of adsorption at zero surface coverage. Results show that the isosteric heat of adsorption is about 3.6-5.4kJ/mol with a mean value 4.38kJ/mol at zero surface coverage. Results also reveal that adsorption isosteres of adsorption data at different temperature regions bring about a different isosteric heat of adsorption due to the variation in contributions from thermal motion of adsorbate molecules. Conclusions are drawn that adsorption isosteres on the adsorption data in correspondence with the lowest and highest temperatures of the hydrogen storage system should be carried out to determine the isosteric heat of adsorption for effectively managing the thermal effect.

The isosteric heat of adsorption on heterogeneous surfaces

1975 ◽  
Vol 51 (3) ◽  
pp. 491-498 ◽  
Author(s):  
Josef Koubek ◽  
Josef Pašek ◽  
Jiří Volf
Keyword(s):  
Isosteric Heat ◽  
Heat Of Adsorption ◽  
Heterogeneous Surfaces ◽  
Isosteric Heat Of Adsorption ◽  
Adsorption On Heterogeneous Surfaces

scholarly journals A computational approach towards understanding hydrogen gas adsorption in Co–MIL-88A

RSC Advances ◽  
2017 ◽  
Vol 7 (63) ◽  
pp. 39583-39593 ◽  
Author(s):  
Nguyen Thi Xuan Huynh ◽  
O My Na ◽  
Viorel Chihaia ◽  
Do Ngoc Son
Keyword(s):  
Gas Adsorption ◽  
Hydrogen Adsorption ◽  
Computational Approach ◽  
Hydrogen Gas ◽  
Hollow Site

The hydrogen adsorption is most favorable at the hollow site of Co–MIL-88A.

Energy, Enthalpy, and Isosteric Heat of Adsorption of Phosphate on Hydrous Al Oxide

1996 ◽  
Vol 183 (1) ◽  
pp. 131-134 ◽  
Author(s):  
A.K. Helmy ◽  
E.A. Ferreiro ◽  
S.G. de Bussetti
Keyword(s):  
Isosteric Heat ◽  
Heat Of Adsorption ◽  
Isosteric Heat Of Adsorption ◽  
Al Oxide

Isosteric heat of adsorption and the vacancy solution model

AIChE Journal ◽  
1987 ◽  
Vol 33 (3) ◽  
pp. 510-514 ◽  
Author(s):  
Orhan Talu ◽  
R. L. Kabel
Keyword(s):  
Isosteric Heat ◽  
Heat Of Adsorption ◽  
Solution Model ◽  
Isosteric Heat Of Adsorption

scholarly journals Experimental studies on equilibrium adsorption isosteres and determination of the thermodynamic quantities of polar media on alumina Al2O3

2017 ◽  
Vol 4 (1) ◽  
pp. 34-45 ◽  
Author(s):  
Albena Yonova
Keyword(s):  
Active Sites ◽  
Adsorption Process ◽  
Surface Acidity ◽  
Experimental Studies ◽  
Isosteric Heat ◽  
Heat Of Adsorption ◽  
Equilibrium Adsorption ◽  
Thermodynamic Quantities ◽  
Isosteric Heat Of Adsorption ◽  
Adsorption Isosteres

Abstract The present work is a revieif of theoretical and experimental study on the adsorption performance of the adsorbent Alumina (Al2O3) used in the adsorption system. An experimental investigation on the equilibrium adsorption isosteres at low pressure (< 1 atm) of working pairs Al2O3/H2O and Al2O3/C2H6O2 is carried out. The isovolume measurement method is adopted in the test setup to directly measure the saturated vapor pressures of working pairs at vapor-liquid equilibrium (dG=0 and dμi=0). Quantity adsorbed is determined from pressure, volume and temperature using gas law. The isosteric heat of adsorption is calculated from the slope of the plot of lnP versus 1/T different amounts of adsorbate onto adsorbent as follows: 0,01 vol% Al2O3/H2O; 0,03 vol% Al2O3/H2O; 0,1 vol% Al2O3/H2O; 0,01 vol% Al2O3/C2H6O2; 0,03 vol% Al2O3/C2H6O2; 0,1 vol% Al2O3/C2H6O2. This study shows that adsorption working pair Al2O3 C2H6O2 has better adsorption performances than those of the A2O3/H2O. Surface acidity! is a most important property! far both adsorption and catalysis and therefore is examined structure of active sites of alumina surface. Thermodynamic parameters such as isosteric heat of adsorption, isosteric enthalpy and entropy of adsorption are critical design variables in estimating the performance and predicting the mechanism of an adsorption process and are also one of the basic requirements for the characterization and optimization of an adsorption process

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