Relationships between main-chain chirality and photophysical properties in chiral conjugated polymers

2014 ◽  
Vol 2 (35) ◽  
pp. 7336-7347 ◽  
Author(s):  
Chao Zheng ◽  
Zhongfu An ◽  
Yosuke Nakai ◽  
Taiju Tsuboi ◽  
Yang Wang ◽  
...  
Keyword(s):  
Conjugated Polymers ◽  
Main Chain ◽  
Photophysical Properties

The different effects of binaphthyl enantiomers on the photophysical properties of chiral conjugated polymers were observed and analyzed for chiro-optic investigations.

Synthesis and photophysical properties of novel conjugated polymers with 4,5-diaza-9,9′-spirobifluorene fragments in the main chain

2012 ◽  
Vol 442 (2) ◽  
pp. 50-56 ◽  
Author(s):  
M. L. Keshtov ◽  
S. I. Pozin ◽  
D. V. Marochkin ◽  
V. P. Perevalov ◽  
P. V. Petrovskii ◽  
...  
Keyword(s):  
Conjugated Polymers ◽  
Main Chain ◽  
Photophysical Properties

scholarly journals New Approach in the Application of Conjugated Polymers: The Light-Activated Source of Versatile Singlet Oxygen Molecule

Materials ◽  
2021 ◽  
Vol 14 (5) ◽  
pp. 1098
Author(s):  
Agata Blacha-Grzechnik
Keyword(s):  
Conjugated Polymers ◽  
Singlet Oxygen ◽  
Near Infrared ◽  
Photophysical Properties ◽  
Short Review ◽  
The Novel ◽  
New Approach ◽  
Intermolecular Energy ◽  
Intermolecular Energy Transfer ◽  
High Absorption

For many years, the research on conjugated polymers (CPs) has been mainly focused on their application in organic electronics. Recent works, however, show that due to the unique optical and photophysical properties of CPs, such as high absorption in UV–Vis or even near-infrared (NIR) region and efficient intra-/intermolecular energy transfer, which can be relatively easily optimized, CPs can be considered as an effective light-activated source of versatile and highly reactive singlet oxygen for medical or catalytic use. The aim of this short review is to present the novel possibilities that lie dormant in those exceptional polymers with the extended system of π-conjugated bonds.

Conjugated Polymers with Main Chain Chirality. 3. Synthesis of Optically Active Poly(aryleneethynylene)s

1996 ◽  
Vol 29 (15) ◽  
pp. 5083-5090 ◽  
Author(s):  
Liang Ma ◽  
Qiao-Sheng Hu ◽  
Kwon Yon Musick ◽  
Dilrukshi Vitharana ◽  
Chi Wu ◽  
...  
Keyword(s):  
Conjugated Polymers ◽  
Main Chain ◽  
Optically Active

scholarly journals Synthesis of Polyazobenzenes Exhibiting Photoisomerization and Liquid Crystallinity

Polymers ◽  
2019 ◽  
Vol 11 (2) ◽  
pp. 348 ◽  
Author(s):  
Masashi Otaki ◽  
Reiji Kumai ◽  
Hajime Sagayama ◽  
Hiromasa Goto
Keyword(s):  
Conjugated Polymers ◽  
Main Chain ◽  
Cross Coupling ◽  
Industrial Applications ◽  
Optical Absorption Spectroscopy ◽  
X Ray Diffraction ◽  
Liquid Crystallinity ◽  
X Ray ◽  
Cis And Trans ◽  
Chain Type

While only a few studies have investigated the synthesis of main chain-type polyazobenzenes, they continue to draw an increasing amount of attention owing to their industrial applications in holography, dyes, and functional adhesives. In this study, dibromoazobenzene was prepared as a monomer for constructing azo-based π-conjugated polymers. Miyaura–Suzuki cross-coupling polymerization was conducted to develop copolymers containing an azobenzene unit as a photoisomerization block and a pyrimidine-based liquid crystal generator block. The prepared polymers exhibited thermotropic liquid crystallinity and underwent cis and trans photoisomerization upon irradiation with ultraviolet and visible light. Furthermore, the photoisomerization behavior was examined using optical absorption spectroscopy and synchrotron X-ray diffraction spectrometry.

Synthesis and photophysical properties of photochromic phenyl-substituted polyphenylenes with main-chain azobenzene fragments

2007 ◽  
Vol 49 (2) ◽  
pp. 176-182 ◽  
Author(s):  
M. L. Keshtov ◽  
O. V. Venidiktova ◽  
V. A. Barachevskii ◽  
V. A. Vasnev ◽  
P. V. Petrovskii ◽  
...  
Keyword(s):  
Main Chain ◽  
Photophysical Properties

The effect of the macrocyclic encapsulation on the photophysical properties of conjugated polymers

2018 ◽  
Author(s):  
Aurica Farcas ◽  
Mihaela Balan-Porcarasu ◽  
Ana-Maria Resmerita ◽  
Mihai Asandulesa ◽  
Angela Rotaru ◽  
...  
Keyword(s):  
Conjugated Polymers ◽  
Photophysical Properties

Synthesis and Photophysical Properties of Conjugated Polymers with Pendant 9,10-Anthraquinone Units

2008 ◽  
Vol 112 (16) ◽  
pp. 4953-4960 ◽  
Author(s):  
Rafael Gómez ◽  
Raúl Blanco ◽  
Dirk Veldman ◽  
José L. Segura ◽  
René A. J. Janssen
Keyword(s):  
Conjugated Polymers ◽  
Photophysical Properties
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