Amino-functionalized silica-encapsulated Mn/ZnS quantum dots for the room-temperature phosphorescence determination of graphene oxide in environmental water samples

2015 ◽  
Vol 7 (18) ◽  
pp. 7874-7878 ◽  
Author(s):  
Yaping Zhong ◽  
Qingpu Wang ◽  
Yu He ◽  
Yili Ge ◽  
Gongwu Song

We developed a simple and sensitive room-temperature phosphorescence method for the determination of graphene oxide in environmental water samples using amino-functionalized silica-encapsulated Mn/ZnS quantum dots.

2014 ◽  
Vol 86 (24) ◽  
pp. 12279-12284 ◽  
Author(s):  
Sandra Benítez-Martínez ◽  
Ángela Inmaculada López-Lorente ◽  
Miguel Valcárcel

2017 ◽  
Vol 41 (12) ◽  
pp. 4763-4766 ◽  
Author(s):  
Dan Li ◽  
Zhefeng Fan

A room-temperature phosphorescence sensor was constructed based on MPA-capped Mn-doped ZnS QDs for the detection of MBT in water samples.


2017 ◽  
Vol 100 (3) ◽  
pp. 804-809 ◽  
Author(s):  
Neha Srivastava ◽  
Supriya Kumari ◽  
Kishore Nair ◽  
Samsul Alam ◽  
Syed K Raza

Abstract The present paper depicts a novel method based on magneticSPE (MSPE) for the determination of organophosphorus pesticides (OPs) such as phorate, malathion, and chlorpyrifos in environmental water samples. In this study, C18 functionalized silica-coated core-shell iron oxide magnetic nanoparticles (MNPs) were used as a surface-engineered magnetic sorbent for theselective extraction of pesticides from aqueous samples, followed by GC-MS and GC–tandem MS analysis for confirmative determination of the analytes. Various important method parameters, including quantity of MNP adsorbent, volume of sample, effective time for extraction, nature of the desorbing solvent, and pH of the aqueous sample, were investigated and optimized to obtain maximum method performance. Under the optimized instrumental analysis conditions, good linearity (r2 value ≥0.994) was achieved at the concentration range of 0.5–500 μg/L. Recoveries were in therange of 79.2–96.3 and 80.4–97.5% in selective-ion monitoring and multiple reaction monitoring (MRM) modes, respectively, at the spiking concentrations of 1, 5, and 10 μg/L. MRM mode showed better sensitivity, selectivity, and low-level detection (0.5 μg/L) of analytes. The novel MSPE method is a simple, cheap, rapid, and eco-friendly method for the determination of OPs in environmental water samples.


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