Bimetallic coordination polymer as a promising anode material for lithium-ion batteries

Bimetallic coordination polymers (BiCPs) with Zn and Co were synthesized by a simple method and applied as anode materials for the first time. When used as anode materials in LIBs, the as-prepared BiCPs exhibit ultra-high capacity and impressive rate capability.

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Graphene Oxide-Induced Carbon Nanoporous Framework towards Advanced Composite Anode Material for Lithium-Ion Batteries

Journal of Electrochemical Energy Conversion and Storage ◽

10.1115/1.4052857 ◽

2021 ◽

pp. 1-17

Author(s):

Guangfeng Shi ◽

Jiale Zhou ◽

Rong Zeng ◽

Bing Na ◽

Shufen Zou

Keyword(s):

Graphene Oxide ◽

Lithium Ion Batteries ◽

Anode Material ◽

Anode Materials ◽

Specific Capacity ◽

High Capacity ◽

Rate Capability ◽

Lithium Ion ◽

Composite Anode ◽

Advanced Composite

Abstract Porous structures in anode materials are of importance to accommodate volume dilation of active matters. In the present case, a carbon nanoporous framework is hydrothermally synthesized from glucose in the presence of graphene oxide (GO), together with in situ active Fe3O4 nanoparticles within it. The composite anode material has outstanding electrochemical performance, including high specific capacity, excellent cyclic stability and superior rate capability. The specific capacity stays at 830.8 mAhg−1 after 200 cycles at 1 A/g, equivalent to a high capacity retention of 88.7%. The findings provide valuable clues to tailor morphology of hydrothermally carbonized glucose for advanced composite anode materials of lithium-ion batteries.

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Facile preparation of monodisperse NiCo2O4 porous microcubes as a high capacity anode material for lithium ion batteries

Inorganic Chemistry Frontiers ◽

10.1039/c7qi00648a ◽

2018 ◽

Vol 5 (3) ◽

pp. 559-567 ◽

Cited By ~ 18

Author(s):

Yanming Wang ◽

Jia Li ◽

Sheng Chen ◽

Bing Li ◽

Guangping Zhu ◽

...

Keyword(s):

Lithium Ion Batteries ◽

Anode Material ◽

Anode Materials ◽

High Capacity ◽

Rate Capability ◽

Lithium Ion ◽

Cycling Stability ◽

Facile Preparation

Monodisperse NiCo2O4 porous microcubes were used as anode materials for lithium-ion batteries, and they exhibit outstanding rate capability and cycling stability.

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2D Coordination Polymer Derived Co3O4Nanocrystals as High Performance Anode Material of Lithium-Ion Batteries

NANO ◽

10.1142/s1793292018501394 ◽

2018 ◽

Vol 13 (12) ◽

pp. 1850139 ◽

Cited By ~ 2

Author(s):

Hao Wen ◽

Changdong Shi ◽

Yuanrui Gao ◽

Hongren Rong ◽

Yanyong Sha ◽

...

Keyword(s):

Coordination Polymer ◽

Lithium Ion Batteries ◽

Anode Material ◽

Anode Materials ◽

High Performance ◽

Rate Capability ◽

Lithium Ion ◽

Reversible Capacity ◽

One Step ◽

A Current

Co3O4 nanocrystals have been synthesized via an ordinary one-step calcination of a cobalt-based 2D coordination polymer [Co(tfbdc)(4,4[Formula: see text]-bpy)(H2O)2]. As an anode material for lithium-ion batteries, the obtained Co3O4 nanocrystals exhibit high reversible capacity, excellent cyclic stability and better rate capability. The reversible capacity of the Co3O4 nanocrystals maintains 713[Formula: see text]mA[Formula: see text]h[Formula: see text]g[Formula: see text] after 50 cycles at a current density of 50[Formula: see text]mA[Formula: see text]g[Formula: see text]. Our results confirm that searching for metal oxides nanomaterials used as anode materials of lithium ion batteries via the calcinations of 2D coordination polymer is a new route.

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Diamondoid-structured polymolybdate-based metal–organic frameworks as high-capacity anodes for lithium-ion batteries

Chemical Communications ◽

10.1039/c6cc10208e ◽

2017 ◽

Vol 53 (37) ◽

pp. 5204-5207 ◽

Cited By ~ 55

Author(s):

Yuan-Yuan Wang ◽

Mi Zhang ◽

Shun-Li Li ◽

Shu-Ran Zhang ◽

Wei Xie ◽

...

Keyword(s):

Lithium Ion Batteries ◽

Anode Material ◽

Coordination Polymers ◽

Metal Organic Frameworks ◽

High Capacity ◽

Lithium Ion ◽

Metal Organic

Two novel isostructural polyoxometalate (POM)-based coordination polymers were obtained. The results reveal that NENU-507 could be directly utilized as an anode material for lithium-ion batteries with outstanding performance.

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Firework-shaped TiO2 microspheres embedded with few-layer MoS2 as an anode material for excellent performance lithium-ion batteries

Journal of Materials Chemistry A ◽

10.1039/c4ta06607c ◽

2015 ◽

Vol 3 (12) ◽

pp. 6392-6401 ◽

Cited By ~ 85

Author(s):

Bangjun Guo ◽

Ke Yu ◽

Hao Fu ◽

Qiqi Hua ◽

Ruijuan Qi ◽

...

Keyword(s):

Lithium Ion Batteries ◽

Anode Material ◽

Composite Electrode ◽

High Capacity ◽

Rate Capability ◽

Lithium Ion ◽

Cycling Performance ◽

Excellent Performance ◽

Tio2 Microspheres ◽

Novel Strategy

Firework-shaped TiO2 microspheres embedded with few-layer MoS2 are prepared by a novel strategy, and the composite electrode exhibits excellent cycling performance, high capacity and rate capability compared to pure MoS2 and TiO2 electrodes.

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Hierarchical NiCoO2 nanosheets supported on amorphous carbon nanotubes for high-capacity lithium-ion batteries with a long cycle life

Journal of Materials Chemistry A ◽

10.1039/c4ta02003k ◽

2014 ◽

Vol 2 (32) ◽

pp. 13069-13074 ◽

Cited By ~ 82

Author(s):

Xin Xu ◽

Bitao Dong ◽

Shujiang Ding ◽

Chunhui Xiao ◽

Demei Yu

Keyword(s):

Carbon Nanotubes ◽

Lithium Ion Batteries ◽

Amorphous Carbon ◽

Anode Materials ◽

High Capacity ◽

Rate Capability ◽

Lithium Ion ◽

Cycling Performance ◽

Cycle Life ◽

Long Cycle Life

NiCoO2 nanosheets@amorphous CNT composites show enhanced cycling performance and rate capability as anode materials for lithium-ion batteries.

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NANOPOROUS COPPER–SILICON COMPOSITE PREPARED BY CHEMICAL DEALLOYING AS ANODE MATERIAL FOR LITHIUM-ION BATTERIES

Functional Materials Letters ◽

10.1142/s1793604713500331 ◽

2013 ◽

Vol 06 (03) ◽

pp. 1350033 ◽

Cited By ~ 3

Author(s):

GUIJING LI ◽

YANYAN SONG ◽

LINPING ZHANG ◽

XIN WEI ◽

XIAOPING SONG ◽

...

Keyword(s):

Lithium Ion Batteries ◽

Anode Material ◽

High Capacity ◽

Lithium Ion ◽

Reversible Capacity ◽

Simple Method ◽

Electrochemical Tests ◽

Nanoporous Copper ◽

Excellent Electrochemical Performance ◽

Melt Spun

A novel and simple method has been developed to prepare the Cu-Si composite as anode material for lithium-ion batteries. Nanoporous Cu-Si composite with pore sizes of 1~30 nm was prepared by dealloying the melt-spun Al-Cu-Si-Ce ribbons in a 5 wt.% HCl solution. Electrochemical tests revealed that the nanoporous Cu-Si electrodes exhibited highly reversible capacity of 2317 mAhg-1 and retained a capacity of 1030 mAhg-1 over 20 cycles. The excellent electrochemical performance is attributed to the unique porous structure of the Cu-Si composite. Our results demonstrate that this novel composite is a promising anode candidate for high-capacity rechargeable lithium-ion batteries.

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Pineapple-shaped ZnCo2O4 microspheres as anode materials for lithium ion batteries with prominent rate performance

Journal of Materials Chemistry A ◽

10.1039/c5ta00830a ◽

2015 ◽

Vol 3 (16) ◽

pp. 8683-8692 ◽

Cited By ~ 93

Author(s):

Lingyun Guo ◽

Qiang Ru ◽

Xiong Song ◽

Shejun Hu ◽

Yudi Mo

Keyword(s):

Lithium Ion Batteries ◽

Anode Material ◽

Anode Materials ◽

Specific Capacity ◽

Rate Capability ◽

Lithium Ion ◽

Rate Performance ◽

High Specific Capacity ◽

Excellent Cycling Stability ◽

Porous Nanostructure

The as-prepared pineapple-shaped ZCO with a porous nanostructure shows a high specific capacity, superior rate capability and excellent cycling stability when used as an anode material for LIBs.

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Polyoxometalate-based metallogels as anode materials for lithium ion batteries

Dalton Transactions ◽

10.1039/c9dt01750j ◽

2019 ◽

Vol 48 (28) ◽

pp. 10422-10426 ◽

Cited By ~ 8

Author(s):

Xing Meng ◽

Hai-Ning Wang ◽

Yan-Hong Zou ◽

Lu-Song Wang ◽

Zi-Yan Zhou

Keyword(s):

Lithium Ion Batteries ◽

Anode Materials ◽

Rate Capability ◽

Lithium Ion ◽

Reversible Capacity ◽

High Rate ◽

High Rate Capability ◽

High Reversible Capacity ◽

First Time ◽

Good Cycling Stability

POM-based metallogels are employed as anode materials for the first time, which exhibit high reversible capacity, high rate capability, and good cycling stability.

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