2D Coordination Polymer Derived Co3O4Nanocrystals as High Performance Anode Material of Lithium-Ion Batteries

NANO ◽  
2018 ◽  
Vol 13 (12) ◽  
pp. 1850139 ◽  
Author(s):  
Hao Wen ◽  
Changdong Shi ◽  
Yuanrui Gao ◽  
Hongren Rong ◽  
Yanyong Sha ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Lithium Ion Batteries ◽  
Anode Material ◽  
Anode Materials ◽  
High Performance ◽  
Rate Capability ◽  
Lithium Ion ◽  
Reversible Capacity ◽  
One Step ◽  
A Current

Co3O4 nanocrystals have been synthesized via an ordinary one-step calcination of a cobalt-based 2D coordination polymer [Co(tfbdc)(4,4[Formula: see text]-bpy)(H2O)2]. As an anode material for lithium-ion batteries, the obtained Co3O4 nanocrystals exhibit high reversible capacity, excellent cyclic stability and better rate capability. The reversible capacity of the Co3O4 nanocrystals maintains 713[Formula: see text]mA[Formula: see text]h[Formula: see text]g[Formula: see text] after 50 cycles at a current density of 50[Formula: see text]mA[Formula: see text]g[Formula: see text]. Our results confirm that searching for metal oxides nanomaterials used as anode materials of lithium ion batteries via the calcinations of 2D coordination polymer is a new route.

Synthesis and Electrochemical Performance of SnO2/Graphene Hybrid Anode for Lithium Ion Batteries

2013 ◽  
Vol 1540 ◽  
Author(s):  
Chia-Yi Lin ◽  
Chien-Te Hsieh ◽  
Ruey-Shin Juang
Keyword(s):  
Electrochemical Performance ◽  
Lithium Ion Batteries ◽  
Anode Material ◽  
High Performance ◽  
Coulombic Efficiency ◽  
Rate Capability ◽  
Lithium Ion ◽  
Reversible Capacity ◽  
Cycling Performance ◽  
Homogeneous Distribution

ABSTRACTAn efficient microwave-assisted polyol (MP) approach is report to prepare SnO2/graphene hybrid as an anode material for lithium ion batteries. The key factor to this MP method is to start with uniform graphene oxide (GO) suspension, in which a large amount of surface oxygenate groups ensures homogeneous distribution of the SnO2 nanoparticles onto the GO sheets under the microwave irradiation. The period for the microwave heating only takes 10 min. The obtained SnO2/graphene hybrid anode possesses a reversible capacity of 967 mAh g-1 at 0.1 C and a high Coulombic efficiency of 80.5% at the first cycle. The cycling performance and the rate capability of the hybrid anode are enhanced in comparison with that of the bare graphene anode. This improvement of electrochemical performance can be attributed to the formation of a 3-dimensional framework. Accordingly, this study provides an economical MP route for the fabrication of SnO2/graphene hybrid as an anode material for high-performance Li-ion batteries.

Preparation of a porous Sn@C nanocomposite as a high-performance anode material for lithium-ion batteries

Nanoscale ◽  
2015 ◽  
Vol 7 (28) ◽  
pp. 11940-11944 ◽  
Author(s):  
Yanjun Zhang ◽  
Li Jiang ◽  
Chunru Wang
Keyword(s):  
Lithium Ion Batteries ◽  
Anode Material ◽  
High Performance ◽  
Rate Capability ◽  
Lithium Ion ◽  
Reversible Capacity ◽  
Facile Hydrothermal Method ◽  
Calcination Process ◽  
Long Cycle Life ◽  
Good Rate Capability

A porous Sn@C nanocomposite was prepared via a facile hydrothermal method combined with a simple post-calcination process. It exhibited excellent electrochemical behavior with a high reversible capacity, long cycle life and good rate capability when used as an anode material for lithium ion batteries.

Bimetallic coordination polymer as a promising anode material for lithium-ion batteries

2016 ◽  
Vol 52 (10) ◽  
pp. 2035-2038 ◽  
Author(s):  
Chao Li ◽  
Xiaoshi Hu ◽  
Xiaobing Lou ◽  
Qun Chen ◽  
Bingwen Hu
Keyword(s):  
Coordination Polymer ◽  
Lithium Ion Batteries ◽  
Anode Material ◽  
Coordination Polymers ◽  
Anode Materials ◽  
High Capacity ◽  
Rate Capability ◽  
Lithium Ion ◽  
Simple Method ◽  
First Time

Bimetallic coordination polymers (BiCPs) with Zn and Co were synthesized by a simple method and applied as anode materials for the first time. When used as anode materials in LIBs, the as-prepared BiCPs exhibit ultra-high capacity and impressive rate capability.

Heteroatom doped porous carbon derived from hair as an anode with high performance for lithium ion batteries

RSC Advances ◽  
2014 ◽  
Vol 4 (109) ◽  
pp. 63784-63791 ◽  
Author(s):  
Junke Ou ◽  
Yongzhi Zhang ◽  
Li Chen ◽  
Hongyan Yuan ◽  
Dan Xiao
Keyword(s):  
Lithium Ion Batteries ◽  
Anode Material ◽  
Porous Carbon ◽  
Human Hair ◽  
High Performance ◽  
Rate Capability ◽  
Lithium Ion ◽  
Reversible Capacity ◽  
Superior Performance ◽  
High Reversible Capacity

The HDPC derived from human hair shows superior performance as an anode material for LIBs with high reversible capacity (1331 mA h g−1 at 0.1 A g−1) and excellent rate capability (205 mA h g−1 at 10 A g−1).

scholarly journals Biomass-Derived Graphitic Carbon Encapsulated Fe/Fe3C Composite as an Anode Material for High-Performance Lithium Ion Batteries

Energies ◽  
2020 ◽  
Vol 13 (4) ◽  
pp. 827 ◽  
Author(s):  
Ying Liu ◽  
Xueying Li ◽  
Anupriya K. Haridas ◽  
Yuanzheng Sun ◽  
Jungwon Heo ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
Anode Material ◽  
Anode Materials ◽  
Active Sites ◽  
High Performance ◽  
Lithium Ion ◽  
Reversible Capacity ◽  
Graphitic Carbon ◽  
Li Ion Batteries ◽  
Li Ion

Lithium ion (Li-ion) batteries have been widely applied to portable electronic devices and hybrid vehicles. In order to further enhance performance, the search for advanced anode materials to meet the growing demand for high-performance Li-ion batteries is significant. Fe3C as an anode material can contribute more capacity than its theoretical one due to the pseudocapacity on the interface. However, the traditional synthetic methods need harsh conditions, such as high temperature and hazardous and expensive chemical precursors. In this study, a graphitic carbon encapsulated Fe/Fe3C (denoted as Fe/Fe3C@GC) composite was synthesized as an anode active material for high-performance lithium ion batteries by a simple and cost-effective approach through co-pyrolysis of biomass and iron precursor. The graphitic carbon shell formed by the carbonization of sawdust can improve the electrical conductivity and accommodate volume expansion during discharging. The porous microstructure of the shell can also provide increased active sites for the redox reactions. The in-situ-formed Fe/Fe3C nanoparticles show pseudocapacitive behavior that increases the capacity. The composite exhibits a high reversible capacity and excellent rate performance. The composite delivered a high initial discharge capacity of 1027 mAh g−1 at 45 mA g−1 and maintained a reversible capacity of 302 mAh g−1 at 200 mA g−1 after 200 cycles. Even at the high current density of 5000 mA g−1, the Fe/Fe3C@GC cell also shows a stable cycling performance. Therefore, Fe/Fe3C@GC composite is considered as one of the potential anode materials for lithium ion batteries.

Towards a durable high performance anode material for lithium storage: stabilizing N-doped carbon encapsulated FeS nanosheets with amorphous TiO2

2019 ◽  
Vol 7 (27) ◽  
pp. 16541-16552 ◽  
Author(s):  
Xuefang Xie ◽  
Yang Hu ◽  
Guozhao Fang ◽  
Xinxin Cao ◽  
Bo Yin ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
Anode Material ◽  
Anode Materials ◽  
High Performance ◽  
Rate Capability ◽  
Lithium Ion ◽  
Cycling Stability ◽  
Lithium Storage ◽  
Amorphous Tio2

In situ formed hierarchical FeS nanosheets supported by a TiO2/C fibrous backbone exhibit higher rate capability and cycling stability as anode materials for lithium ion batteries.

The preparation of Si/SiC composites by magnesium heat reduction of SiO2 aerogel and study on electrochemistry properties

2019 ◽  
Vol 34 (01n03) ◽  
pp. 2040011
Author(s):  
Bowen Dong ◽  
Bingbing Deng ◽  
Yangai Liu
Keyword(s):  
Lithium Ion Batteries ◽  
Anode Material ◽  
Anode Materials ◽  
High Performance ◽  
Specific Capacity ◽  
Lithium Ion ◽  
Lithium Storage ◽  
Silicon Carbon ◽  
Sic Composites ◽  
A Current

Silicon, an anode material for lithium ion batteries, has the highest theoretical specific capacity ([Formula: see text] mAh/g). The actual lithium storage capacity of [Formula: see text] mAh/g is about 10 times that of the graphite anode materials class. This study involves magnesium heat reduction of the SiO2 preparation of silicon carbon composites. The Si/SiC composite shows a high initial specific capacity of 1406.7 mAh/g with a current density of 0.1 A/g. The morphology and pore size inherited from the SiO2 aerogel counteracts the volume expansion during the lithiation/delithiation process. This paper provides an articulate methodology for designing silicon anode material for high-performance rechargeable lithium-ion batteries.

Nitrogen-rich porous carbon derived from biomass as a high performance anode material for lithium ion batteries

2015 ◽  
Vol 3 (12) ◽  
pp. 6534-6541 ◽  
Author(s):  
Junke Ou ◽  
Yongzhi Zhang ◽  
Li Chen ◽  
Qian Zhao ◽  
Yan Meng ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
Anode Material ◽  
Porous Carbon ◽  
High Performance ◽  
Rate Capability ◽  
Lithium Ion ◽  
Reversible Capacity ◽  
Superior Performance ◽  
High Reversible Capacity

The OHC shows superior performance as an anode material for LIBs with a high reversible capacity (1181 mA h g−1 at 0.1 A g−1) and an excellent rate capability (304 mA h g−1 at 5 A g−1).

SiO2@NiO core–shell nanocomposites as high performance anode materials for lithium-ion batteries

RSC Advances ◽  
2015 ◽  
Vol 5 (77) ◽  
pp. 63012-63016 ◽  
Author(s):  
Yourong Wang ◽  
Wei Zhou ◽  
Liping Zhang ◽  
Guangsen Song ◽  
Siqing Cheng
Keyword(s):  
Lithium Ion Batteries ◽  
Anode Materials ◽  
High Performance ◽  
Coulombic Efficiency ◽  
Rate Capability ◽  
Lithium Ion ◽  
Cycling Stability ◽  
Core Shell ◽  
Excellent Cycling Stability

A SiO2@NiO core–shell electrode exhibits almost 100% coulombic efficiency, excellent cycling stability and rate capability after the first few cycles.

A comparative study of ordered mesoporous carbons with different pore structures as anode materials for lithium-ion batteries

RSC Advances ◽  
2015 ◽  
Vol 5 (53) ◽  
pp. 42922-42930 ◽  
Author(s):  
Diganta Saikia ◽  
Tzu-Hua Wang ◽  
Chieh-Ju Chou ◽  
Jason Fang ◽  
Li-Duan Tsai ◽  
...  
Keyword(s):  
Comparative Study ◽  
Lithium Ion Batteries ◽  
Anode Materials ◽  
Rate Capability ◽  
Lithium Ion ◽  
Reversible Capacity ◽  
Cycling Stability ◽  
Mesoporous Carbons ◽  
Ordered Mesoporous Carbons ◽  
Ordered Mesoporous

Ordered mesoporous carbons CMK-3 and CMK-8 with different mesostructures are evaluated as anode materials for lithium-ion batteries. CMK-8 possesses higher reversible capacity, better cycling stability and rate capability than CMK-3.

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