Capturing the structural diversification upon thermal desolvation of a robust metal organic framework via a single-crystal-to-single-crystal transformation

CrystEngComm ◽  
2015 ◽  
Vol 17 (46) ◽  
pp. 8801-8806 ◽  
Author(s):  
Sandeep Kumar ◽  
Sanjay K. Mandal
Keyword(s):  
Single Crystal ◽  
Metal Organic Framework ◽  
X Ray ◽  
X Ray Crystallography ◽  
Crystal Transformation ◽  
Metal Organic ◽  
Structural Diversification ◽  
Organic Framework

Using a robust 2D metal organic framework, {[Zn(bpaipa)]·DMF·2H2O}n (1), structural diversification due to thermal desolvation is captured via single-crystal-to-single-crystal transformation based on X-ray crystallography, FTIR and TGA.

scholarly journals Mapping-Out Catalytic Processes in a Metal-Organic Framework with Single-Crystal X-ray Crystallography

2017 ◽  
Vol 129 (29) ◽  
pp. 8532-8536 ◽  
Author(s):  
Alexandre Burgun ◽  
Campbell J. Coghlan ◽  
David M. Huang ◽  
Wenqian Chen ◽  
Satoshi Horike ◽  
...  
Keyword(s):  
Single Crystal ◽  
Metal Organic Framework ◽  
X Ray ◽  
X Ray Crystallography ◽  
Metal Organic ◽  
Catalytic Processes ◽  
Organic Framework

scholarly journals Mapping-Out Catalytic Processes in a Metal-Organic Framework with Single-Crystal X-ray Crystallography

2017 ◽  
Vol 56 (29) ◽  
pp. 8412-8416 ◽  
Author(s):  
Alexandre Burgun ◽  
Campbell J. Coghlan ◽  
David M. Huang ◽  
Wenqian Chen ◽  
Satoshi Horike ◽  
...  
Keyword(s):  
Single Crystal ◽  
Metal Organic Framework ◽  
X Ray ◽  
X Ray Crystallography ◽  
Metal Organic ◽  
Catalytic Processes ◽  
Organic Framework

Single Crystal X-ray Diffraction Studies of Carbon Dioxide and Fuel-Related Gases Adsorbed on the Small Pore Scandium Terephthalate Metal Organic Framework, Sc2(O2CC6H4CO2)3

Langmuir ◽  
2009 ◽  
Vol 25 (6) ◽  
pp. 3618-3626 ◽  
Author(s):  
Stuart R. Miller ◽  
Paul A. Wright ◽  
Thomas Devic ◽  
Christian Serre ◽  
Gérard Férey ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Single Crystal ◽  
Metal Organic Framework ◽  
X Ray Diffraction ◽  
X Ray ◽  
Small Pore ◽  
Metal Organic ◽  
Organic Framework

A Mn(II) Metal-Organic Framework Constructed from a Tetrahedral Silicon-Cored Ligand

2013 ◽  
Vol 275-277 ◽  
pp. 2367-2370
Author(s):  
Qing Yu Ma ◽  
Rui Fang Guan ◽  
Guo Zhong Li ◽  
Deng Xu Wang
Keyword(s):  
Single Crystal ◽  
Metal Organic Framework ◽  
Diffusion Method ◽  
X Ray Diffraction ◽  
X Ray ◽  
Slow Diffusion ◽  
Sheet Structure ◽  
Metal Organic ◽  
1D Chains ◽  
Organic Framework

A novel metal-organic framework, MnCl2(BIPS)2•2CH3OH•2H2O (1) were synthesized from MnCl2 and a tetrahedral silicon-cored ligand, Me2Si(p-C6H4-imdazol-1-yl)2 (BIPS) under the slow diffusion method. The structure was determined by single-crystal X-ray diffraction. Complex 1 is a 2D sheet structure constructed from 1D chains with 34-atom metallamacrocycles.

Solvent‐Vapor‐Induced Reversible Single‐Crystal‐to‐Single‐Crystal Transformation of a Triphosphaazatriangulene‐Based Metal–Organic Framework

2019 ◽  
Vol 59 (4) ◽  
pp. 1435-1439 ◽  
Author(s):  
Soichiro Nakatsuka ◽  
Yusuke Watanabe ◽  
Yoshinobu Kamakura ◽  
Satoshi Horike ◽  
Daisuke Tanaka ◽  
...  
Keyword(s):  
Single Crystal ◽  
Metal Organic Framework ◽  
Solvent Vapor ◽  
Crystal Transformation ◽  
Metal Organic ◽  
Organic Framework

scholarly journals Single crystal structure and photocatalytic behavior of grafted uranyl on the Zr-node of a pyrene-based metal–organic framework

CrystEngComm ◽  
2020 ◽  
Vol 22 (11) ◽  
pp. 2097-2102 ◽  
Author(s):  
Julia G. Knapp ◽  
Xuan Zhang ◽  
Tatyana Elkin ◽  
Laura E. Wolfsberg ◽  
Sylvia L. Hanna ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Single Crystal ◽  
Metal Organic Framework ◽  
Uranyl Ion ◽  
Single Crystal Structure ◽  
X Ray Diffraction ◽  
X Ray ◽  
Photo Oxidation ◽  
Metal Organic ◽  
Organic Framework

The zirconium MOF NU-1000 was post-synthetically modified through solvothermal deposition to include the uranyl ion and characterized via single-crystal X-ray diffraction; photo-oxidation was also performed.

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