Control of surface alkyl catalysis with thiolate monolayers

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Chih-Heng Lien ◽  
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Pd surface modification by thiolate SAMs resulted in preferential terminal-to-internal olefin isomerization instead of hydrogenation, particularly at high conversion.

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The oxidation of phenol leading to 1,4-hydroquinone with high conversion, remarkable selectivity and excellent yields (87% isolated) has been accomplished under electrolytic conditions in an aqueous medium employing carbon-based electrode....


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Subhash Garhwal ◽  
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...  

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P. Guillemin ◽  
A. Nuttin ◽  
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pp. 227-232
Author(s):  
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