scholarly journals MeL2Zn2(μ-1,6-Ph2-N6) – a building block for new hexazene complexes

2015 ◽  
Vol 44 (35) ◽  
pp. 15703-15711 ◽  
Author(s):  
S. Gondzik ◽  
C. Wölper ◽  
R. Haack ◽  
G. Jansen ◽  
S. Schulz
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Building Block ◽  
Main Group ◽  
Group Metal ◽  
Main Group Metal

MeL2Zn2(μ-1,6-Ph2-N6) 1 (MeL = HC[C(Me)N(2,4,6-Me3C6H2)]2) serves as hexazene transfer reagent in reactions with main group metal and transition metal complexes containing M–Me units.

scholarly journals Catalysis using transition metal complexes featuring main group metal and metalloid compounds as supporting ligands

2021 ◽  
Author(s):  
Jun Takaya
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Main Group ◽  
Multidentate Ligand ◽  
Group Metal ◽  
Catalytic Application ◽  
Main Group Metal

Recent development in catalytic application of transition metal complexes having an M–E bond (E = main group metal or metalloid element), which is stabilized by a multidentate ligand, is summarized.

Novel isomorphism of two hexagonal non-centrosymmetric hybrid crystals of M(en)3Ag2I4 (M = transition metal Mn2+ or main-group metal Mg2+; en = ethylenediamine)

CrystEngComm ◽  
2018 ◽  
Vol 20 (3) ◽  
pp. 356-361 ◽  
Author(s):  
Xin Chen ◽  
Zhi-Yuan Yao ◽  
Chen Xue ◽  
Zhu-Xi Yang ◽  
Jian-Lan Liu ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Complex ◽  
Metal Complexes ◽  
Crystal Structures ◽  
Main Group ◽  
Group Metal ◽  
Main Group Metal ◽  
Hybrid Crystals ◽  
First Time

For the first time, a main-group metal complex is used as a template for the formation of hybrid crystal structures and isomorphic hybrid crystals are obtained using transition and main-group metal complexes.

Reversible Addition of Carbon Dioxide to Main Group Metal Complexes at Temperatures about 0 °C

2021 ◽  
Author(s):  
Tatyana S. Koptseva ◽  
Vladimir G. Sokolov ◽  
Sergey Yu. Ketkov ◽  
Elena A. Rychagova ◽  
Anton V. Cherkasov ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Metal Complexes ◽  
Main Group ◽  
Group Metal ◽  
Reversible Addition ◽  
Main Group Metal

scholarly journals Frustration across the periodic table: heterolytic cleavage of dihydrogen by metal complexes

2017 ◽  
Vol 375 (2101) ◽  
pp. 20170002 ◽  
Author(s):  
R. Morris Bullock ◽  
Geoffrey M. Chambers
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Molecular Complexes ◽  
Main Group ◽  
Lewis Base ◽  
Metal Compounds ◽  
Metal Catalysis ◽  
Heterolytic Cleavage ◽  
Lewis Pairs

This perspective examines frustrated Lewis pairs (FLPs) in the context of heterolytic cleavage of H 2 by transition metal complexes, with an emphasis on molecular complexes bearing an intramolecular Lewis base. FLPs have traditionally been associated with main group compounds, yet many reactions of transition metal complexes support a broader classification of FLPs that includes certain types of transition metal complexes with reactivity resembling main group-based FLPs. This article surveys transition metal complexes that heterolytically cleave H 2 , which vary in the degree that the Lewis pairs within these systems interact. Many of the examples include complexes bearing a pendant amine functioning as the base with the metal functioning as the hydride acceptor. Consideration of transition metal compounds in the context of FLPs can inspire new innovations and improvements in transition metal catalysis. This article is part of the themed issue ‘Frustrated Lewis pair chemistry’.

New main-group and early transition-metal complexes of mono-pendant arm triazacyclononane ligands

2001 ◽  
pp. 170-180 ◽  
Author(s):  
Sergei Y. Bylikin ◽  
David A. Robson ◽  
Nigel A. H. Male ◽  
Leigh H. Rees ◽  
Philip Mountford ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Main Group ◽  
Early Transition Metal ◽  
Pendant Arm ◽  
Early Transition
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