Tandem rhodium catalysis: exploiting sulfoxides for asymmetric transition-metal catalysis
2015 ◽
Vol 13
(21)
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pp. 5844-5847
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Keyword(s):
Sulfoxides are uncommon substrates for transition-metal catalysis due to their propensity to inhibit catalyst turnover. We have developed the first DKR of racemic allylic sulfoxides where rhodium catalyzed both sulfoxide epimerization and alkene hydrogenation.
Keyword(s):
2008 ◽
Vol 41
(9)
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pp. 1120-1132
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Keyword(s):