Role of acid sites and surface hydroxyl groups in isophthalonitrile hydrogenation catalyzed by supported Ni–Co catalysts

For hydrogenation of isophthalonitrile, the metal sites catalyzed the hydrogenation reactions, while the acid sites (including the original and new ones) and the surface hydroxyl groups catalyzed the condensation side reactions.

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Advantageous Role of Ir0 Supported on TiO2 Nanosheets in Photocatalytic CO2 Reduction to CH4: Fast Electron Transfer and Rich Surface Hydroxyl Groups

ACS Applied Materials & Interfaces ◽

10.1021/acsami.0c19233 ◽

2021 ◽

Vol 13 (5) ◽

pp. 6219-6228

Author(s):

Kunlin Tang ◽

Zhiqiang Wang ◽

Weixin Zou ◽

Hongyu Guo ◽

Yuchao Wu ◽

...

Keyword(s):

Electron Transfer ◽

Fast Electron ◽

Co2 Reduction ◽

Hydroxyl Groups ◽

Surface Hydroxyl ◽

Surface Hydroxyl Groups ◽

Tio2 Nanosheets

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Defective magnesium ferrite nano-platelets for the adsorption of As(V): The role of surface hydroxyl groups

Environmental Pollution ◽

10.1016/j.envpol.2017.12.050 ◽

2018 ◽

Vol 235 ◽

pp. 11-19 ◽

Cited By ~ 18

Author(s):

Can Wu ◽

Jingwei Tu ◽

Chen Tian ◽

Junjie Geng ◽

Zhang Lin ◽

...

Keyword(s):

Hydroxyl Groups ◽

Magnesium Ferrite ◽

Surface Hydroxyl ◽

Surface Hydroxyl Groups

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Bidimensional Solvation and Delocalisation of Electrons at the Surface of an Insulating Oxide: The Role of Surface Hydroxyl Groups on MgO

ChemPhysChem ◽

10.1002/cphc.200400466 ◽

2004 ◽

Vol 5 (12) ◽

pp. 1897-1900 ◽

Cited By ~ 9

Author(s):

Mario Chiesa ◽

Maria Cristina Paganini ◽

Elio Giamello

Keyword(s):

Hydroxyl Groups ◽

Surface Hydroxyl ◽

Surface Hydroxyl Groups

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Role of surface hydroxyl groups of acid-treated natural zeolite on the heterogeneous catalytic ozonation of methylene blue contaminated waters

Chemical Engineering Journal ◽

10.1016/j.cej.2012.09.069 ◽

2012 ◽

Vol 211-212 ◽

pp. 388-395 ◽

Cited By ~ 50

Author(s):

Héctor Valdés ◽

Rolando F. Tardón ◽

Claudio A. Zaror

Keyword(s):

Methylene Blue ◽

Natural Zeolite ◽

Catalytic Ozonation ◽

Hydroxyl Groups ◽

Surface Hydroxyl ◽

Heterogeneous Catalytic ◽

Surface Hydroxyl Groups ◽

Contaminated Waters

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Role of surface hydroxyl groups in promoting room temperature CO sensing by Pd-modified nanocrystalline SnO2

Journal of Solid State Chemistry ◽

10.1016/j.jssc.2010.07.017 ◽

2010 ◽

Vol 183 (10) ◽

pp. 2389-2399 ◽

Cited By ~ 63

Author(s):

Artem V. Marikutsa ◽

Marina N. Rumyantseva ◽

Lada V. Yashina ◽

Alexander M. Gaskov

Keyword(s):

Room Temperature ◽

Hydroxyl Groups ◽

Surface Hydroxyl ◽

Surface Hydroxyl Groups

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Role of Surface Hydroxyl Groups on Single-Atomic Rh1/ZrO2 Catalyst for Direct Methane Oxidation

Chemical Communications ◽

10.1039/d0cc07514k ◽

2021 ◽

Author(s):

Gunjoo Kim ◽

Gihun Kwon ◽

Hyunjoo Lee

Keyword(s):

Hydrothermal Treatment ◽

Methane Oxidation ◽

Hydroxyl Groups ◽

Surface Hydroxyl ◽

Surface Hydroxyl Groups ◽

Rh Catalyst ◽

Zro2 Catalyst

Single atomic Rh catalyst immobilized on zirconia (Rh1/ZrO2) was modified by hydrothermal treatment to have surface hydroxyl groups and used for direct methane oxidation. Both O2 and H2O2 were used...

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Effect of activation temperature on acidity of alumina, silica-alumina and cobalt-molybdenum-alumina catalysts

Collection of Czechoslovak Chemical Communications ◽

10.1135/cccc19851268 ◽

1985 ◽

Vol 50 (6) ◽

pp. 1268-1273 ◽

Cited By ~ 3

Author(s):

Zdeněk Vít

Keyword(s):

Acid Sites ◽

Hydroxyl Groups ◽

Activation Temperature ◽

Cumene Cracking ◽

Surface Hydroxyl ◽

Catalytic Activities ◽

Surface Hydroxyl Groups ◽

Silica Alumina ◽

Effect Of Surface ◽

Alumina Catalysts

The effect of surface dehydration on the acidity of silica-alumina and cobalt-molybdenum-alumina catalysts has been studied and compared with alumina. The catalysts were characterized by surface hydroxyl groups concentrations, acid sites concentrations and by catalytic activities in paraldehyde depolymerisation and cumene cracking. It was found that the acidity of alumina and cobalt-molybdenum-alumina catalysts increases significantly with surface dehydration and attains maximum after activation at 500-550 °C. Silica-alumina is strongly acidic even in the hydrated state, the acidity being formed already at relatively low temperature around 100 °C.

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