Arginine-assisted synthesis of palladium nanochain networks and their enhanced electrocatalytic activity for borohydride oxidation

RSC Advances ◽  
2015 ◽  
Vol 5 (23) ◽  
pp. 18111-18115 ◽  
Author(s):  
Geng-Tao Fu ◽  
Rui Wu ◽  
Chang Liu ◽  
Jun Lin ◽  
Dong-Mei Sun ◽  
...  

Three-dimensional Pd nanochain networks (Pd-NCNs) were prepared by an arginine-assisted self-assembly process, exhibiting excellent electrocatalytic performance towards the borohydride oxidation reaction.

2013 ◽  
Vol 23 (4) ◽  
pp. 403-403 ◽  
Author(s):  
Chao Wu ◽  
Xingyi Huang ◽  
Genlin Wang ◽  
Libing Lv ◽  
Gan Chen ◽  
...  

2009 ◽  
Vol 13 (04n05) ◽  
pp. 481-493 ◽  
Author(s):  
Laura P. Hernández ◽  
Almudena González-Álvarez ◽  
Ana I. Oliva ◽  
Pablo Ballester

During the last ten years, our research group has been applying metal-mediated self-assembly processes to the construction of multiporphyrin functional assemblies. The construction of well-defined and discrete supramolecular structures resulting from self-assembly requires the use of multiple and separated connections operating in one or more closed loops. Consequently, the great majority of the multiporphyrin assemblies that we have prepared are of cyclic nature. We have placed special emphasis not only on the characterization in solution of the formed assemblies but also on the thermodynamic characterization of the assembly process and in the assessment of cooperativity. Finally, we also present examples in which functionality has been derived from the three-dimensional structures of multicomponent assemblies.


2007 ◽  
Vol 35 (3) ◽  
pp. 502-507 ◽  
Author(s):  
J.A.R. Worrall ◽  
M. Górna ◽  
X.Y. Pei ◽  
D.R. Spring ◽  
R.L. Nicholson ◽  
...  

The principles of self-assembly are described for naturally occurring macromolecules and for complex assemblies formed from simple synthetic constituents. Many biological molecules owe their function and specificity to their three-dimensional folds, and, in many cases, these folds are specified entirely by the sequence of the constituent amino acids or nucleic acids, and without the requirement for additional machinery to guide the formation of the structure. Thus sequence may often be sufficient to guide the assembly process, starting from denatured components having little or no folds, to the completion state with the stable, equilibrium fold that encompasses functional activity. Self-assembly of homopolymeric structures does not necessarily preserve symmetry, and some polymeric assemblies are organized so that their chemically identical subunits pack stably in geometrically non-equivalent ways. Self-assembly can also involve scaffolds that lack structure, as seen in the multi-enzyme assembly, the degradosome. The stable self-assembly of lipids into dynamic membraneous sheets is also described, and an example is shown in which a synthetic detergent can assemble into membrane layers.


2018 ◽  
Vol 6 (26) ◽  
pp. 12759-12767 ◽  
Author(s):  
Guangran Xu ◽  
Rui Si ◽  
Jiayin Liu ◽  
Luyao Zhang ◽  
Xia Gong ◽  
...  

A new directed self-assembly strategy is developed to achieve 3D Pt/Pd nanocrystal superlattices with enhanced electrocatalytic performance for methanol oxidation reaction due to the enriched metallic Pt active sites by appropriate Pd alloying and surface nitrogen doping.


2013 ◽  
Vol 1 (26) ◽  
pp. 7612 ◽  
Author(s):  
Tao Wu ◽  
Mingxi Chen ◽  
Lei Zhang ◽  
Xiaoyang Xu ◽  
Yu Liu ◽  
...  

2016 ◽  
Vol 11 (1) ◽  
pp. 4-8
Author(s):  
Mustafa Emre Karagozler ◽  
Seth Copen Goldstein ◽  
David S. Ricketts

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