Controlled synthesis of LiNi0.5Mn1.5O4 cathode materials with superior electrochemical performance through urea-based solution combustion synthesis

Spinel LiMn2O4 powders have been prepared at 500 for 5h by solution combustion synthesis in water or ethanol system, using lithium and manganese acetate as raw materials and no fuels. The structure and morphology of the products have been analyzed by X-ray diffraction (XRD) and scanning electron microscopy (SEM), respectively. The electrochemical performance has been charged or discharged in coin-type battery. XRD analysis indicates that the purity and crystallinity of the product prepared in ethanol are much better than these of the product prepared in water. SEM investigation indicates that the particles of the product prepared in ethanol are smaller and more dispersed than these of the products prepared in water. The product prepared in ethanol also exhibits better electrochemical performance than that of the product prepared in water. The initial discharge capacity of the product prepared in ethanol is 120mAh/g, and remains 110mAh/g after 20 cycles, at a current density of 50mA/g and in the voltage range of 3.2-4.35V.

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Solution combustion synthesis and electrochemical properties of yttrium-doped LiMnPO4/C cathode materials for lithium ion batteries

Journal of Rare Earths ◽

10.1016/j.jre.2019.06.004 ◽

2020 ◽

Vol 38 (9) ◽

pp. 976-982

Author(s):

Redouan El Khalfaouy ◽

Servet Turan ◽

Miguel A. Rodriguez ◽

Kamil Burak Dermenci ◽

Umut Savacı ◽

...

Keyword(s):

Electrochemical Properties ◽

Lithium Ion Batteries ◽

Combustion Synthesis ◽

Cathode Materials ◽

Lithium Ion ◽

Solution Combustion Synthesis ◽

Solution Combustion

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Glucose-assisted combustion synthesis of Li1.2Ni0.13Co0.13Mn0.54O2 cathode materials with superior electrochemical performance for lithium-ion batteries

RSC Advances ◽

10.1039/c6ra15639h ◽

2016 ◽

Vol 6 (82) ◽

pp. 79050-79057 ◽

Cited By ~ 12

Author(s):

Honglei Li ◽

Shichao Zhang ◽

Xin Wei ◽

Puheng Yang ◽

Zhixu Jian ◽

...

Keyword(s):

Electrochemical Performance ◽

Lithium Ion Batteries ◽

Combustion Synthesis ◽

Cathode Materials ◽

Lithium Ion ◽

Combustion Method ◽

Calcination Treatment

Lithium-rich layered Li1.2Ni0.13Co0.13Mn0.54O2 cathode materials have been successfully fabricated by a glucose-assisted combustion method combined with a calcination treatment.

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Solution combustion synthesis and enhanced electrochemical performance Li1.2Ni0.2Mn0.6O2 nanoparticles by controlling NO3–/CH3COO– ratio of the precursors

Materials Research Bulletin ◽

10.1016/j.materresbull.2015.05.005 ◽

2015 ◽

Vol 70 ◽

pp. 397-402 ◽

Cited By ~ 8

Author(s):

Qingtang Zhang ◽

Juntao Mei ◽

Xiaolong Xie ◽

Xiaomei Wang ◽

Junyan Zhang

Keyword(s):

Electrochemical Performance ◽

Combustion Synthesis ◽

Solution Combustion Synthesis ◽

Solution Combustion ◽

Enhanced Electrochemical Performance

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Electrochemical performance of porous α-LiVOPO4/C composite by solution combustion synthesis method

Materials Research Innovations ◽

10.1179/1433075x15y.0000000065 ◽

2015 ◽

Vol 19 (6) ◽

pp. 423-427 ◽

Cited By ~ 1

Author(s):

D. H. He ◽

A. P. Tang ◽

Q. W. Zhong ◽

Z. Q. He ◽

G. R. Xu ◽

...

Keyword(s):

Electrochemical Performance ◽

Combustion Synthesis ◽

Synthesis Method ◽

Solution Combustion Synthesis ◽

Solution Combustion

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LiMn2O4 Prepared by a Flameless Solution Combustion Synthesis: The Effect of Ignition Temperature

Applied Mechanics and Materials ◽

10.4028/www.scientific.net/amm.142.213 ◽

2011 ◽

Vol 142 ◽

pp. 213-216

Author(s):

Gui Yang Liu ◽

Jun Ming Guo ◽

Yan Nan Li ◽

Bao Sen Wang ◽

Ying He

Keyword(s):

Electrochemical Performance ◽

Combustion Synthesis ◽

Phase Structure ◽

Ignition Temperature ◽

Present Method ◽

Single Phase ◽

Raw Materials ◽

Solution Combustion Synthesis ◽

Solution Combustion ◽

Micro Morphology

Spinel LiMn2O4 have been prepared by a flameless solution combustion synthesis, using nitrate and acetate salts as raw materials without any fuels. The effect of ignition temperature on the phase structure, micro morphology and electrochemical performance has been studied. The results indicate that spinel LiMn2O4 with single phase can be prepared successfully by the present method at the ignition temperatures of 300-800°C and calcination temperature of 600°C for 5h. The crystallinity, dispersity of the gains and electrochemical performance of the products increase with the decreasing ignition temperatures.

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