Porous films by the self-assembly of inorganic rod-b-coil block copolymers: mechanistic insights into the vesicle-to-pore morphological evolution
Keyword(s):
The Self
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The self-assembly in thin films of polyphosphazene block copolymers combining a rigid ([N = P(O2C12H8)], O2C12H8= 2,2′-dioxy-1,1′-biphenyl) and a flexible ([N = PMePh]) blocks, led to the spontaneous formation of porous films through a vesicle-to-pore morphological evolutions pathway.