A catalyst superior to carbon-supported-platinum for promotion of the oxygen reduction reaction: reduced-polyoxometalate supported palladium

2015 ◽  
Vol 3 (26) ◽  
pp. 13962-13969 ◽  
Author(s):  
Xiaohong Xie ◽  
Yao Nie ◽  
Siguo Chen ◽  
Wei Ding ◽  
Xueqiang Qi ◽  
...  
Keyword(s):  
Oxygen Reduction Reaction ◽  
Oxygen Reduction ◽  
Reduction Reaction ◽  
Alkaline Media ◽  
Hybrid Catalyst ◽  
Supported Platinum ◽  
Electrocatalytic Performance ◽  
Supported Palladium ◽  
Better Than

A palladium and reduced-polyoxometalate hybrid catalyst (Pd/rPOM) exhibits excellent electrocatalytic performance for ORR in alkaline media, even better than the Pt/C catalyst.

scholarly journals Oxygen reduction reaction on carbon-supported palladium nanocubes in alkaline media

2016 ◽  
Vol 64 ◽  
pp. 9-13 ◽  
Author(s):  
Madis Lüsi ◽  
Heiki Erikson ◽  
Ave Sarapuu ◽  
Kaido Tammeveski ◽  
Jose Solla-Gullón ◽  
...  
Keyword(s):  
Oxygen Reduction Reaction ◽  
Oxygen Reduction ◽  
Reduction Reaction ◽  
Alkaline Media ◽  
Supported Palladium

scholarly journals Electrocatalytic Performance of Carbon Supported WO3-Contained Pd-W Nanoalloys for Oxygen Reduction Reaction in Alkaline Media

2018 ◽  
Author(s):  
Nan Cui ◽  
Zengfeng Guo ◽  
Wenpeng Li ◽  
Xun Xu ◽  
Hongxia Zhao ◽  
...  
Keyword(s):  
Oxygen Reduction Reaction ◽  
Oxygen Reduction ◽  
Photoelectron Spectroscopy ◽  
Reduction Reaction ◽  
Alkaline Media ◽  
Alkaline Electrolyte ◽  
Atom Ratio ◽  
Onset Potential ◽  
Electrocatalytic Performance ◽  
Catalytic Stability

In this paper, we first report that WOx contained nanoalloys exhibit stable electrocatalytic performance in alkaline media, though bulk WO3 are easy to be dissolved in NaOH solutions. Carbon supported oxide-rich Pd-W alloy nanoparticles (PdW/C) with different Pd:W atom ratios were prepared by reduction-oxidation method. Among the catalysts, the oxide-rich Pd0.8W0.2/C (Pd/W = 8:2, atom ratio) exhibits the highest catalytic activity for oxygen reduction reaction. The X-ray photoelectron spectroscopy data shows that ~40% of Pd atoms and ~60% of the W atoms are in their oxides form. The Pd 3d5/2 peaks in oxide-rich Pd-W nanoalloys are positive shift compared with that of Pd/C, which indicates the electronic structure of Pd is affected by the strong interaction between Pd and W/WO3. Compare to Pd/C, the onset potential of oxygen reduction reaction at the oxide-rich Pd0.8W0.2/C is positive shifted. The current density (mA·mg Pd−1) at the oxide-rich Pd0.8W0.2/C is ~1.6 times of that at Pd/C. The oxide-rich Pd0.8W0.2/C also exhibits higher catalytic stability than Pd/C, which demonstrate that it is a prospective candidate for the cathode of fuel cells operated with alkaline electrolyte.

scholarly journals Superior FexN electrocatalyst derived from 1,1′-diacetylferrocene for oxygen reduction reaction in alkaline and acidic media

2020 ◽  
Vol 9 (1) ◽  
pp. 843-852
Author(s):  
Hunan Jiang ◽  
Jinyang Li ◽  
Mengni Liang ◽  
Hanpeng Deng ◽  
Zuowan Zhou
Keyword(s):  
Oxygen Reduction Reaction ◽  
Oxygen Reduction ◽  
Current Density ◽  
Active Sites ◽  
Reduction Reaction ◽  
Alkaline Media ◽  
Acidic Media ◽  
Onset Potential ◽  
Acidic And Alkaline Media ◽  
The Stability

AbstractAlthough Fe–N/C catalysts have received increasing attention in recent years for oxygen reduction reaction (ORR), it is still challenging to precisely control the active sites during the preparation. Herein, we report FexN@RGO catalysts with the size of 2–6 nm derived from the pyrolysis of graphene oxide and 1,1′-diacetylferrocene as C and Fe precursors under the NH3/Ar atmosphere as N source. The 1,1′-diacetylferrocene transforms to Fe3O4 at 600°C and transforms to Fe3N and Fe2N at 700°C and 800°C, respectively. The as-prepared FexN@RGO catalysts exhibited superior electrocatalytic activities in acidic and alkaline media compared with the commercial 10% Pt/C, in terms of electrochemical surface area, onset potential, half-wave potential, number of electrons transferred, kinetic current density, and exchange current density. In addition, the stability of FGN-8 also outperformed commercial 10% Pt/C after 10000 cycles, which demonstrates the as-prepared FexN@RGO as durable and active ORR catalysts in acidic media.

Mesoporous TiN as a Noncarbon Support of Ag-Rich PtAg Nanoalloy Catalysts for Oxygen Reduction Reaction in Alkaline Media

ChemSusChem ◽  
2014 ◽  
Vol 7 (12) ◽  
pp. 3356-3361 ◽  
Author(s):  
Zhiming Cui ◽  
Minghui Yang ◽  
Hao Chen ◽  
Mengtian Zhao ◽  
Francis J. DiSalvo
Keyword(s):  
Oxygen Reduction Reaction ◽  
Oxygen Reduction ◽  
Reduction Reaction ◽  
Alkaline Media

Highly active bimetallic CuFe–N–C electrocatalysts for oxygen reduction reaction in alkaline media

2019 ◽  
Vol 71 ◽  
pp. 234-241 ◽  
Author(s):  
Yun Sik Kang ◽  
Yoonhye Heo ◽  
Jae Young Jung ◽  
Yeonsun Sohn ◽  
Soo-Hyoung Lee ◽  
...  
Keyword(s):  
Oxygen Reduction Reaction ◽  
Oxygen Reduction ◽  
Reduction Reaction ◽  
Alkaline Media ◽  
Highly Active
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