CeOx-modified RhNi nanoparticles grown on rGO as highly efficient catalysts for complete hydrogen generation from hydrazine borane and hydrazine

2015 ◽  
Vol 3 (46) ◽  
pp. 23520-23529 ◽  
Author(s):  
Zhujun Zhang ◽  
Zhang-Hui Lu ◽  
Hongliang Tan ◽  
Xiangshu Chen ◽  
Qilu Yao

Amorphous CeOx-doped Rh-Ni NPs grown on reduced graphene oxide nanosheets have been used as highly efficient and recyclable catalysts for complete hydrogen generation from aqueous solution of N2H4BH3 or N2H4.

2015 ◽  
Vol 3 (40) ◽  
pp. 20254-20266 ◽  
Author(s):  
Gitashree Darabdhara ◽  
Mohammed A. Amin ◽  
Gaber A. M. Mersal ◽  
Emad M. Ahmed ◽  
Manash R. Das ◽  
...  

Reduced graphene oxide nanosheets decorated with gold–palladium bimetallic nanoparticles are synthesized by a simple solution chemistry approach for efficient electrochemical hydrogen generation.


2018 ◽  
Vol 232 (3) ◽  
pp. 431-443 ◽  
Author(s):  
Xigang Du ◽  
Yonghua Duan ◽  
Jun Zhang ◽  
Gang Mi

AbstractCoMo nanoparticles (NPs) supported on reduced graphene oxide (RGO) were synthesized by a one-stepin situco-reduction of an aqueous solution of cobalt(II) chloride, sodium molybdate dihydrate and graphene oxide (GO) using NaBH4as the sole reductant under ambient conditions. The powder XRD, FTIR, EDS and TEM were employed to characterize the structure, size and composition of the CoMo/RGO catalysts. The as-synthesized Co0.9Mo0.1/RGO catalysts exhibited high catalytic activity for the hydrolytic dehydrogenation of ammonia borane (AB) at room temperature. The as-synthesized Co0.9Mo0.1/RGO nanocatalysts exhibited much higher catalytic activity than Co/RGO, Mo/RGO and the RGO-free Co0.9Mo0.1counterpart. Moreover, kinetic studies indicate that the catalytic hydrolysis of AB by Co0.9Mo0.1/RGO has first order kinetics with respect to the the catalyst concentration, but zero order kinetics with respect to the substrate concentration. The Co0.9Mo0.1/RGO catalyst has a turnover frequency (TOF) of 15.8 mol H2·(mol·Co0.9Mo0.1/RGO)−1·min−1at 25°C. Furthermore, the Co0.9Mo0.1/RGO show good recyclability for hydrogen generation from an aqueous solution of AB, which enables the practical reuse of the catalysts. Hence, this general method can be easily extended to the facile preparation of other RGO-based metallic systems.


2020 ◽  
Vol 837 ◽  
pp. 155588 ◽  
Author(s):  
Muhammad Ikram ◽  
Sarfraz Ali ◽  
Muhammad Aqeel ◽  
Anwar Ul-Hamid ◽  
Muhammad Imran ◽  
...  

2015 ◽  
Vol 44 (19) ◽  
pp. 9193-9199 ◽  
Author(s):  
Siliang Li ◽  
Hua Li ◽  
Jian Liu ◽  
Haoli Zhang ◽  
Yanmei Yang ◽  
...  

We report a novel and effective strategy to synthesize Pd/Fe3O4-PEI-RGO nanohybrids for highly efficient degradation of organic dyes.


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