Emission properties and Cu(i)–Cu(i) interaction in 2-coordinate dicopper(i)-bis(N-heterocyclic)carbene complexes

2016 ◽  
Vol 45 (30) ◽  
pp. 12127-12136 ◽  
Author(s):  
Michihiro Nishikawa ◽  
Taichi Sano ◽  
Masaya Washimi ◽  
Koichiro Takao ◽  
Taro Tsubomura
Keyword(s):  
Photophysical Properties ◽  
Carbene Ligands ◽  
Carbene Complexes ◽  
Dinuclear Copper ◽  
Emission Properties ◽  
Solid States

The 8-shaped dinuclear copper(i) complexes bearing two N-heterocyclic carbene ligands exhibit strong photoluminescence both in solution and the solid states. Copper(i)–copper(i) interactions play a key role in the photophysical properties.

Syntheses, Crystal Structures and Photophysical Properties of Dinuclear Copper(I) Complexes Bearing Diphenylphosphino‐Substituted Benzimidazole Ligands

2021 ◽  
Vol 6 (9) ◽  
pp. 2156-2163
Author(s):  
Mengmeng Cao ◽  
Yi Zhao ◽  
Mengsi Gu ◽  
Chunmei Liu ◽  
Qianqian Zhu ◽  
...  
Keyword(s):  
Crystal Structures ◽  
Photophysical Properties ◽  
Dinuclear Copper

Tuning the Photophysical Properties of BODIPY Molecules by π-Conjugation with Fischer Carbene Complexes

2013 ◽  
Vol 20 (5) ◽  
pp. 1367-1375 ◽  
Author(s):  
Gong Ming Chu ◽  
Andrés Guerrero-Martínez ◽  
Israel Fernández ◽  
Miguel Ángel Sierra
Keyword(s):  
Photophysical Properties ◽  
Fischer Carbene Complexes ◽  
Carbene Complexes ◽  
Fischer Carbene

Deep-Red Phosphorescent Iridium(III) Complexes with Chromophoric N-Heterocyclic Carbene Ligands: Design, Photophysical Properties, and DFT Calculations

2016 ◽  
Vol 2016 (11) ◽  
pp. 1626-1626 ◽  
Author(s):  
Pierre-Henri Lanoë ◽  
Jonny Chan ◽  
Geoffrey Gontard ◽  
Filippo Monti ◽  
Nicola Armaroli ◽  
...  
Keyword(s):  
Dft Calculations ◽  
Photophysical Properties ◽  
Carbene Ligands

Carbene Adducts of Dimethylcadmium

1999 ◽  
Vol 54 (11) ◽  
pp. 1350-1356 ◽  
Author(s):  
Anthony J. Arduengo ◽  
Jens R. Goerlicha ◽  
Fredric Davidson ◽  
William J. Marshall
Keyword(s):  
Nmr Spectroscopy ◽  
Bond Distance ◽  
Imidazole Ring ◽  
Methyl Groups ◽  
Carbene Ligands ◽  
Cadmium Complexes ◽  
Carbene Complexes ◽  
X Ray ◽  
Planar Geometries

The first examples of carbene-cadmium complexes are reported from the reactions of a variety of imidazol-2-ylidenes or imidazolin-2-ylidenes with dimethylcadmium. Four new carbene complexes are characterized by NMR spectroscopy (1H , 13C and 113Cd). The cadmium centers are strongly shifted downfield (100 -150 ppm) by interaction with the carbenes. X-ray structures are reported for three carbene-cadmium 1:1 adducts. The cadmium centers exhibit distorted trigonal-planar geometries in which the carbene ligands have an average 18.2 pm longer bond distance to cadmium compared to the methyl groups. The planes of cadmium coordination are twisted with respect to the plane of the imidazole ring. The more basic imidazolin-2-ylidene is shown to displace imidazol-2-ylidenes from the cadmium center.

Four-coordinate Cu(I) complexes supported by N-heterocyclic carbene ligands bearing electron-donating/withdrawing groups: Synthesis, structures and photophysical properties

2018 ◽  
Vol 204 ◽  
pp. 618-625 ◽  
Author(s):  
Zhiqiang Wang ◽  
Xiaojuan Sun ◽  
Weijun Fu ◽  
Chen Xu ◽  
Baoming Ji
Keyword(s):  
Photophysical Properties ◽  
Carbene Ligands

Functionalised Saturated-Backbone Carbene Ligands: Yttrium and Uranyl Alkoxy-Carbene Complexes and Bicyclic Carbene-Alcohol Adducts

2008 ◽  
Vol 14 (33) ◽  
pp. 10415-10422 ◽  
Author(s):  
Polly L. Arnold ◽  
Ian J. Casely ◽  
Zoë R. Turner ◽  
Christopher D. Carmichael
Keyword(s):  
Carbene Ligands ◽  
Carbene Complexes

scholarly journals Tritolylporphyrin dimer as a new potent hydrophobic sensitizer for photodynamic therapy of melanoma.

2001 ◽  
Vol 48 (1) ◽  
pp. 277-282 ◽  
Author(s):  
A Drzewiecka ◽  
K Urbańska ◽  
Z Matuszak ◽  
M Pineiro ◽  
L G Arnaut ◽  
...  
Keyword(s):  
Photodynamic Therapy ◽  
Quantum Yield ◽  
Singlet Oxygen ◽  
Biological Effect ◽  
Photophysical Properties ◽  
Red Light ◽  
Human Melanoma ◽  
Oxygen Production ◽  
Absorption And Emission ◽  
Emission Properties

We report the synthesis, photochemical and photophysical properties and preliminary studies on biological effect of a new tritolylporphyrin dimer (T-D). Absorption and emission properties of T-D suggest its possible use in photodynamic therapy. T-D is capable of singlet oxygen production with 0.8 quantum yield. It also has a high photostability. The photodynamic properties of the dimer were examined following the growth of SKMEL 188 (human melanoma) cells irradiated with red light (cut off < 630 nm). The surviving fraction of the cells decreased about 3-fold (vs. non-irradiated cells) for an 81 J/cm dose. Our results suggest that tritolylporphyrine dimer T-D may be an interesting hydrophobic sensitizer for photodynamic therapy.

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