Iron(0) mediated C–H activation of 1-hexyne: a mechanistic study using time-resolved infrared spectroscopy

2016 ◽  
Vol 45 (31) ◽  
pp. 12292-12296
Author(s):  
Jan H. Blank ◽  
Rajesh K. Raju ◽  
Tao Yan ◽  
Edward N. Brothers ◽  
Marcetta Y. Darensbourg ◽  
...  
Keyword(s):  
Infrared Spectroscopy ◽  
Mechanistic Study ◽  
Tricarbonyl Complex ◽  
Time Resolved ◽  
Iron Tricarbonyl ◽  
Time Resolved Infrared Spectroscopy

Photolysis of an iron tricarbonyl complex in the presence of 1-hexyne results in the formation of an intermediate Fe-(η2-1-hexyne) species which converts to the C–H activated Fe–CCR product.

scholarly journals Flexible to rigid: IR spectroscopic investigation of a rhenium-tricarbonyl-complex at a buried interface

2021 ◽  
Vol 23 (7) ◽  
pp. 4311-4316
Author(s):  
Kerstin T. Oppelt ◽  
Laurent Sevéry ◽  
Mirjam Utters ◽  
S. David Tilley ◽  
Peter Hamm
Keyword(s):  
Infrared Spectroscopy ◽  
Spectroscopic Investigation ◽  
Tricarbonyl Complex ◽  
Time Resolved ◽  
Time Resolved Infrared Spectroscopy ◽  
Ir Spectroscopic ◽  
Rhenium Tricarbonyl

Immobilized rhenium tricarbonyl complexes were embedded in ALD deposited ZrO2, and investigated by (time resolved) infrared spectroscopy. The initially solvent exposed molecules react on the change of their environment.

A quantum cascade laser setup for studying irreversible photoreactions in H2O with nanosecond resolution and microlitre consumption

2020 ◽  
Vol 22 (45) ◽  
pp. 26459-26467
Author(s):  
Jessica L. Klocke ◽  
Tilman Kottke
Keyword(s):  
Infrared Spectroscopy ◽  
Quantum Cascade Laser ◽  
Time Resolved ◽  
Quantum Cascade ◽  
Time Resolved Infrared Spectroscopy ◽  
Laser Setup

Flavin photoreduction in H2O is elucidated by developing a quantum cascade laser setup for time-resolved infrared spectroscopy on irreversible reactions.

Water Transport in Proton Exchange Membranes: Insights from Time-Resolved Infrared Spectroscopy

2019 ◽  
Vol 33 (1) ◽  
pp. 1029-1033 ◽  
Author(s):  
Daniel Hallinan ◽  
Maria Grazia De Angelis ◽  
Marco Giacinti Baschetti ◽  
Giulio Sarti ◽  
Yossef A. Elabd
Keyword(s):  
Infrared Spectroscopy ◽  
Water Transport ◽  
Proton Exchange Membranes ◽  
Proton Exchange ◽  
Time Resolved ◽  
Time Resolved Infrared Spectroscopy

scholarly journals Probing the Contributions to DNA Hybridization Dynamics with Time-Resolved Infrared Spectroscopy

2021 ◽  
Vol 120 (3) ◽  
pp. 8a-9a
Author(s):  
Brennan Ashwood ◽  
Paul J. Sanstead ◽  
Qing Dai ◽  
Chuan He ◽  
Andrei Tokmakoff
Keyword(s):  
Infrared Spectroscopy ◽  
Dna Hybridization ◽  
Time Resolved ◽  
Time Resolved Infrared Spectroscopy
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