The synergistic effect of H2O and DMF towards stable and 20% efficiency inverted perovskite solar cells

2017 ◽  
Vol 10 (3) ◽  
pp. 808-817 ◽  
Author(s):  
Chien-Hung Chiang ◽  
Mohammad Khaja Nazeeruddin ◽  
Michael Grätzel ◽  
Chun-Guey Wu

A high quality thick (500 nm) CH3NH3PbI3perovskite absorber with a horizontal grain size up to 3 μm and a lateral size equal to the film thickness was prepared by the synergistic effect of a H2O additive and DMF vapor treatmentviaa two-step spin coating method.

2019 ◽  
Vol 7 (32) ◽  
pp. 19008-19016 ◽  
Author(s):  
Yuxiao Guo ◽  
Xingtian Yin ◽  
Jie Liu ◽  
Wenxiu Que

An efficient and facile one-step spin-coating method assisted by a preheating process was applied for the fabrication of high-quality CsPbIBr2 films.


2019 ◽  
Vol 7 (9) ◽  
pp. 4977-4987 ◽  
Author(s):  
Jiangzhao Chen ◽  
Seul-Gi Kim ◽  
Xiaodong Ren ◽  
Hyun Suk Jung ◽  
Nam-Gyu Park

Fabrication of high-quality perovskite films with a large grain size and fewer defects is always crucial to achieve efficient and stable perovskite solar cells (PSCs).


Crystals ◽  
2021 ◽  
Vol 11 (12) ◽  
pp. 1521
Author(s):  
Jiabin Hao ◽  
Zeming Wang ◽  
Huiying Hao ◽  
Guanlei Wang ◽  
Hongcheng Gao ◽  
...  

So far, it is still a great challenge to prepare high efficiency organic–inorganic perovskite solar cells in ambient air. Specifically, moisture is easily combined with the perovskite material during the spin-coating process, which result in porous perovskite films with poor surface morphology. In this study, we investigated crystalline Ag-doped perovskite films by a one-step spin-coating method in air with 30–40% relative humidity (RH), in which ethyl acetate (EA) was used as antisolvent can absorb moisture in air to reduced nucleation density. More significantly, EA is a feasible and environmentally friendly solvent to replace highly toxic solvent. Moreover, 1.0% Ag-doped device shows a highest power conversion efficiency (PCE) of 14.36%. The improved performance is not only ascribed to the superior CH3NH3PbI3 film with high crystallinity but to the versatile tunability of energy band structure.


2021 ◽  
Vol 927 (1) ◽  
pp. 012001
Author(s):  
D A Yusra ◽  
N Mufti ◽  
A F Muyasaroh ◽  
E Latifah

Abstract The poor stability of perovskite materials is a problem of concern in commercialization. In this study, we investigated the doping of magnesium cations (Mg2+) in PbI2 to improve the stability and efficiency of perovskite solar cells. The doping effect of Mg2+ can increase the crystallization rate. The perovskite film fabricated structure consists of ITO/TiO2/perovskite/CuO. The fabrication method used is a two-stage spin coating. The concentrations of MgAc2 were used 0, 0.75, 1, and 1.25 mg ml−1. The characterizations used are XRD (X-Ray Diffraction), UV-Vis, SEM-EDX. While the performance of solar cells is measured using a solar simulator. The XRD pattern shows that the sample has a crystal structure of MAPbI3, PbI2, and CuO phases. The MAPbI3 lattice parameter increased with increasing Mg acetate concentration. The grain size of the perovskite layer is between 5 - 15 μm, with a thickness of about 30 μm. The efficiency of perovskite solar cells increases with the increasing concentration of MgAc2.


2016 ◽  
Vol 4 (5) ◽  
pp. 1947-1952 ◽  
Author(s):  
M. I. El-Henawey ◽  
Ryan S. Gebhardt ◽  
M. M. El-Tonsy ◽  
Sumit Chaudhary

The two step sequential deposition of CH3NH3PbI3-based perovskite solar cells has been modified by applying toluene and chlorobenzene vapors during the preparation of PbI2 films leading to the growth of the PbI2 grain size.


2017 ◽  
Vol 9 (32) ◽  
pp. 26937-26947 ◽  
Author(s):  
Jionghua Wu ◽  
Xin Xu ◽  
Yanhong Zhao ◽  
Jiangjian Shi ◽  
Yuzhuan Xu ◽  
...  

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