Direct synthesis of gasoline and diesel range branched alkanes with acetone from lignocellulose

2016 ◽  
Vol 18 (13) ◽  
pp. 3707-3711 ◽  
Author(s):  
Xueru Sheng ◽  
Ning Li ◽  
Guangyi Li ◽  
Wentao Wang ◽  
Aiqin Wang ◽  
...  

C6–C15branched alkanes were synthesized in a high carbon yield (∼80%) with acetone and hydrogen over a dual-bed catalyst system.

AIChE Journal ◽  
2016 ◽  
Vol 62 (8) ◽  
pp. 2754-2761 ◽  
Author(s):  
Xueru Sheng ◽  
Guangyi Li ◽  
Wentao Wang ◽  
Yu Cong ◽  
Xiaodong Wang ◽  
...  

CrystEngComm ◽  
2021 ◽  
Author(s):  
Shuai Fang ◽  
Yongkui Wang ◽  
Liangchao Chen ◽  
Zhiyun Lu ◽  
Zhenghao Cai ◽  
...  

Pressure is a necessary condition for the growth of natural diamond. Studying the effect of pressure on the nitrogen content of diamond is important for exploring the growth mechanism of...


ChemSusChem ◽  
2016 ◽  
Vol 10 (1) ◽  
pp. 210-219 ◽  
Author(s):  
Melissandre Richard ◽  
Daniel Duprez ◽  
Nicolas Bion ◽  
Fabien Can

2021 ◽  
Author(s):  
Wenjing Jiang ◽  
Zhenlin Jiang ◽  
Xin Fan ◽  
Min Zhu

Abstract Bacterial cellulose (BC)decomposes easily and the carbon residue rate is low. These factors critically restrict its application in fabricating cellulosic carbon materials. Therefore, in this paper, a simple and facile method to improve the BC carbon yield is proposed based on the stretching orientation of BC. By controlling the degree of BC deformation, the orientation and crystallinity of the BC can be adjusted, thereby sensitively affecting the graphitization degree and carbon yield of carbonized BC. Samples were characterized by scanning electron microscope (SEM), X-ray diffraction (XRD), Raman scattering, and low-field nuclear magnetic resonance (LNMR). The results indicated that when the pre-stretched strain was 40%, the crystallinity and graphitization degree of BC improved, and the carbon yield increased significantly in comparison to that of untreated BC. Thus, a low-cost, facile, and environmentally friendly method of increasing the carbon yield of BC was developed in this study.


Science ◽  
2019 ◽  
Vol 366 (6472) ◽  
pp. 1514-1517 ◽  
Author(s):  
Ji Yang ◽  
Jiawang Liu ◽  
Helfried Neumann ◽  
Robert Franke ◽  
Ralf Jackstell ◽  
...  

The direct carbonylation of 1,3-butadiene offers the potential for a more cost-efficient and environmentally benign route to industrially important adipic acid derivatives. However, owing to the complex reaction network of regioisomeric carbonylation and isomerization pathways, a selective practical catalyst for this process has thus far proven elusive. Here, we report the design of a pyridyl-substituted bidentate phosphine ligand (HeMaRaphos) that, upon coordination to palladium, catalyzes adipate diester formation from 1,3-butadiene, carbon monoxide, and butanol with 97% selectivity and 100% atom-economy under industrially viable and scalable conditions (turnover number > 60,000). This catalyst system also affords access to a variety of other di- and triesters from 1,2- and 1,3-dienes.


RSC Advances ◽  
2019 ◽  
Vol 9 (41) ◽  
pp. 23727-23734 ◽  
Author(s):  
Zhuohua Sun ◽  
Daniel Buwalda ◽  
Katalin Barta

This work described a simple two-step process for the complete lignocellulose conversion to alkanes with high carbon yield.


2020 ◽  
Vol 11 (20) ◽  
pp. 3475-3480
Author(s):  
Yu-Jia Zheng ◽  
Guan-Wen Yang ◽  
Bo Li ◽  
Guang-Peng Wu

A highly stereoregular polyphosphoester with a rigid cyclohexylene structure in the main chain was constructed via ring-opening polymerization (ROP) in the presence of an organic catalyst system.


2015 ◽  
Vol 6 (33) ◽  
pp. 6088-6095 ◽  
Author(s):  
Wenjie Zheng ◽  
Nan Yan ◽  
Yutian Zhu ◽  
Wenpeng Zhao ◽  
Chunyu Zhang ◽  
...  

Highly trans-1,4-stereoregular polybutadiene (TPB) was obtained by CCTP and novel amphiphilic copolymers (TPB-b-PCL/PLA) were successfully synthesized.


2019 ◽  
Vol 17 (7) ◽  
pp. 1722-1726 ◽  
Author(s):  
Qun Cao ◽  
William I. Nicholson ◽  
Andrew C. Jones ◽  
Duncan L. Browne

An operationally simple mechanochemical method for the Pd catalysed Buchwald–Hartwig amination of arylhalides with secondary amines has been developed using a Pd PEPPSI catalyst system.


2020 ◽  
Vol 11 (6) ◽  
pp. 1531-1537 ◽  
Author(s):  
Victoria Dimakos ◽  
Daniel Gorelik ◽  
Hsin Y. Su ◽  
Graham E. Garrett ◽  
Gregory Hughes ◽  
...  

The combined action of boronic acid, photoredox catalyst and hydrogen atom transfer mediator enables the transformation of furanosides to 2-keto-3-deoxyfuranosides, a synthetic analog of the process catalyzed by the ribonucleotide reductase enzymes.


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