Magnetic, recyclable PtyCo1−y/Ti3C2X2 (X = O, F) catalyst: a facile synthesis and enhanced catalytic activity for hydrogen generation from the hydrolysis of ammonia borane

2017 ◽  
Vol 41 (7) ◽  
pp. 2793-2799 ◽  
Author(s):  
Guangyin Fan ◽  
Xiaojing Li ◽  
Yuling Ma ◽  
Yun Zhang ◽  
Jiangtao Wu ◽  
...  

Magnetic recyclable PtyCo1−y/Ti3C2X2 (X = O, F) catalyst exhibits excellent catalytic performance for the hydrolysis of AB at room temperature.

2015 ◽  
Vol 5 (1) ◽  
pp. 525-530 ◽  
Author(s):  
Jun Li ◽  
Qi-Long Zhu ◽  
Qiang Xu

Non-noble bimetallic CuCo alloy nanoparticles were successfully encapsulated in the pores of MIL-101 without aggregation on the external surfaces of the host framework, which exhibit excellent catalytic activity for hydrolytic dehydrogenation of ammonia borane.


RSC Advances ◽  
2016 ◽  
Vol 6 (107) ◽  
pp. 105940-105947 ◽  
Author(s):  
Daohua Sun ◽  
Pengyao Li ◽  
Bin Yang ◽  
Yan Xu ◽  
Jiale Huang ◽  
...  

Monodisperse AgPd alloy NPs showed remarkable catalytic activity towards the generation of hydrogen from the methanolysis of ammonia borane at room temperature.


2012 ◽  
Vol 37 (23) ◽  
pp. 17921-17927 ◽  
Author(s):  
Hongyan Liang ◽  
Guozhu Chen ◽  
Stefano Desinan ◽  
Renzo Rosei ◽  
Federico Rosei ◽  
...  

2016 ◽  
Vol 852 ◽  
pp. 252-256
Author(s):  
Wei Dong Qi ◽  
Li Xian Sun ◽  
Fen Xu ◽  
Yong Jin Zou ◽  
Hai Liang Chu

Ammonia borane received extensive attention due to its hydrogen content as high as 19.6%. In present article we prepared the Pt-Co/C catalyst via ultrasonic immersion method and in situ reduction method. The catalyst was characterized by measuring the specific area. The influence of the catalyst on the properties of the hydrolysis of ammonia borane was tested, and the catalytic activity of the catalyst in cycle use was verified. Results shows that the catalytic activity of Pt0.5Co0.5/C is the highest, and the maximum hydrogen generation rate is 7229.613 mL/ (g ·min). It was verified that it remained good catalytic activity after cycle use for more than 10 times.


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