Non-noble bimetallic CuCo nanoparticles encapsulated in the pores of metal–organic frameworks: synergetic catalysis in the hydrolysis of ammonia borane for hydrogen generation

2015 ◽  
Vol 5 (1) ◽  
pp. 525-530 ◽  
Author(s):  
Jun Li ◽  
Qi-Long Zhu ◽  
Qiang Xu
Keyword(s):  
Catalytic Activity ◽  
Hydrogen Generation ◽  
Metal Organic Frameworks ◽  
Ammonia Borane ◽  
Alloy Nanoparticles ◽  
Metal Organic ◽  
Hydrolysis Of

Non-noble bimetallic CuCo alloy nanoparticles were successfully encapsulated in the pores of MIL-101 without aggregation on the external surfaces of the host framework, which exhibit excellent catalytic activity for hydrolytic dehydrogenation of ammonia borane.

From Ru nanoparticle-encapsulated metal–organic frameworks to highly catalytically active Cu/Ru nanoparticle-embedded porous carbon

2017 ◽  
Vol 5 (10) ◽  
pp. 4835-4841 ◽  
Author(s):  
Pradip Pachfule ◽  
Xinchun Yang ◽  
Qi-Long Zhu ◽  
Nobuko Tsumori ◽  
Takeyuki Uchida ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
High Temperature ◽  
Porous Carbon ◽  
Metal Organic Frameworks ◽  
Ammonia Borane ◽  
Carbon Composites ◽  
High Catalytic Activity ◽  
Catalytically Active ◽  
Metal Organic

High-temperature pyrolysis of Ru nanoparticle-encapsulated MOF (Ru@HKUST-1) afforded ultrafine Cu/Ru nanoparticle-embedded porous carbon composites (Cu/Ru@C), which show high catalytic activity for ammonia borane hydrolysis.

A MOF-derived CuCo(O)@ carbon–nitrogen framework as an efficient synergistic catalyst for the hydrolysis of ammonia borane

2020 ◽  
Vol 7 (10) ◽  
pp. 2043-2049 ◽  
Author(s):  
Yao Yuan ◽  
Xiaoyu Chen ◽  
Xing Zhang ◽  
Zumin Wang ◽  
Ranbo Yu
Keyword(s):  
Porous Carbon ◽  
Metal Organic Frameworks ◽  
Ammonia Borane ◽  
Carbon Framework ◽  
Metal Organic ◽  
Hydrolysis Of

A CuCo(O)-embedded nitrogen-enriched porous carbon framework catalyst derived from doped metal–organic frameworks for efficient hydrolysis of ammonia borane.

scholarly journals Monodisperse AgPd alloy nanoparticles as a highly active catalyst towards the methanolysis of ammonia borane for hydrogen generation

RSC Advances ◽  
2016 ◽  
Vol 6 (107) ◽  
pp. 105940-105947 ◽  
Author(s):  
Daohua Sun ◽  
Pengyao Li ◽  
Bin Yang ◽  
Yan Xu ◽  
Jiale Huang ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Room Temperature ◽  
Hydrogen Generation ◽  
Active Catalyst ◽  
Ammonia Borane ◽  
Alloy Nanoparticles ◽  
Highly Active

Monodisperse AgPd alloy NPs showed remarkable catalytic activity towards the generation of hydrogen from the methanolysis of ammonia borane at room temperature.

Ni–Pt nanoparticles growing on metal organic frameworks (MIL-96) with enhanced catalytic activity for hydrogen generation from hydrazine at room temperature

2015 ◽  
Vol 44 (13) ◽  
pp. 6212-6218 ◽  
Author(s):  
Lan Wen ◽  
Xiaoqiong Du ◽  
Jun Su ◽  
Wei Luo ◽  
Ping Cai ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Room Temperature ◽  
Hydrogen Generation ◽  
Metal Organic Frameworks ◽  
Pt Nanoparticles ◽  
Metal Organic ◽  
Hydrogen Selectivity

3.2 nm NiPt nanoparticles have been successfully grown on the surface of MIL-96, which exhibit 100% hydrogen selectivity and the highest catalytic activity toward dehydrogenation of hydrazine with TOF value of 114.3 h−1 at room temperature.

NiPt–MnOx supported on N-doped porous carbon derived from metal–organic frameworks for highly efficient hydrogen generation from hydrazine

2016 ◽  
Vol 4 (15) ◽  
pp. 5616-5622 ◽  
Author(s):  
Bingquan Xia ◽  
Teng Liu ◽  
Wei Luo ◽  
Gongzhen Cheng
Keyword(s):  
Catalytic Activity ◽  
Porous Carbon ◽  
Hydrogen Generation ◽  
Metal Organic Frameworks ◽  
Porous Carbons ◽  
Nitrogen Doped ◽  
Highly Efficient ◽  
Different Temperatures ◽  
Metal Organic

Nitrogen-doped porous carbons derived from ZIF-7 annealing at different temperatures have been synthesized and used as support matrices to anchor NiPt alloy and MnOx NPs. The resulting (Ni3Pt7)0.5–(MnOx)0.5/NPC-900 exhibits superior catalytic activity with TOF values of 706 and 120 h−1 at 323 K and 298 K respectively, higher than most reported values.

PtCo Nanoparticles Supported on Carbon for Hydrolysis of Ammonia Borane

2016 ◽  
Vol 852 ◽  
pp. 252-256
Author(s):  
Wei Dong Qi ◽  
Li Xian Sun ◽  
Fen Xu ◽  
Yong Jin Zou ◽  
Hai Liang Chu
Keyword(s):  
Catalytic Activity ◽  
Reduction Method ◽  
Hydrogen Generation ◽  
Specific Area ◽  
Ammonia Borane ◽  
In Situ Reduction ◽  
Immersion Method ◽  
Good Catalytic Activity ◽  
Hydrolysis Of

Ammonia borane received extensive attention due to its hydrogen content as high as 19.6%. In present article we prepared the Pt-Co/C catalyst via ultrasonic immersion method and in situ reduction method. The catalyst was characterized by measuring the specific area. The influence of the catalyst on the properties of the hydrolysis of ammonia borane was tested, and the catalytic activity of the catalyst in cycle use was verified. Results shows that the catalytic activity of Pt0.5Co0.5/C is the highest, and the maximum hydrogen generation rate is 7229.613 mL/ (g ·min). It was verified that it remained good catalytic activity after cycle use for more than 10 times.

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