Hierarchical three-dimensional branched hematite nanorod arrays with enhanced mid-visible light absorption for high-efficiency photoelectrochemical water splitting

Nanoscale ◽  
2016 ◽  
Vol 8 (25) ◽  
pp. 12697-12701 ◽  
Author(s):  
Degao Wang ◽  
Guoliang Chang ◽  
Yuying Zhang ◽  
Jie Chao ◽  
Jianzhong Yang ◽  
...  

Author(s):  
Xin Zou ◽  
Xueyang Han ◽  
Chengxiong Wang ◽  
Yunkun Zhao ◽  
Chun Du ◽  
...  

Ta3N5 is regarded as a promising candidate material with adequate visible light absorption and band structure for photoelectrochemical water splitting. However, the performance of Ta3N5 is severely limited by the...





2020 ◽  
Vol 53 (6) ◽  
pp. 1425-1433
Author(s):  
Aya Amin ◽  
Ali El-dissouky

Although alloying and nanostructuring offer a great opportunity for enhancing photoelectrochemical behavior and band gap tuning, these methods have not been investigated extensively. This article reports the synthesis of Cu2ZnNiO3 complex oxide nanowires (∼200 nm) grown on German silver alloy via a one-step optimized hydrothermal route and their utilization to split water photoelectrochemically. Surface characterizations were used to elucidate the formation mechanism of the Cu2ZnNiO3 complex oxide nanowires. The nanowires exhibited an exceptional visible light absorption extending from 400 to 1400 nm wavelengths with a tuned band gap of ∼2.88 eV calculated from the corresponding Tauc plot. In tests to split water photoelectrochemically, the nanowires generated a significant photocurrent of up to −2.5 mA cm−2 at −0.8 V versus Ag/AgCl and exhibited an exceptional photostability which exceeded 2 h under light-off conditions with no photocurrent decay. Band edge positions related to water redox potentials were estimated via Mott–Schottky and diffuse reflectance spectroscopy analysis with the density of charge carriers reaching as high as 5.15 × 1018 cm−3. Moreover, the nanowires generated ∼1100 µmol of H2 in 5 h. These photoelectrochemical results are much higher than the reported values for similar structures of copper oxide, zinc oxide and nickel oxide separately under the same conditions, which can be attributed to the advantages of Cu, Zn and Ni oxides (such as visible light absorption, photostability, and efficient charge carrier generation and transport) being combined in one single material. These promising results make German silver a robust material toward photoelectrochemical water splitting.





2019 ◽  
Vol 7 (17) ◽  
pp. 10225-10230 ◽  
Author(s):  
Ali Imran Channa ◽  
Xin Tong ◽  
Jing-Yin Xu ◽  
Yongchen Liu ◽  
Changmeng Wang ◽  
...  

Near-infrared-emitting CuGaS2/CdS QDs with enhanced visible light absorption were developed to achieve high efficiency photoelectrochemical cells.



2019 ◽  
Vol 7 (10) ◽  
pp. 5702-5711 ◽  
Author(s):  
Yawei Wang ◽  
Shu Jin ◽  
Guoxiang Pan ◽  
Zuxin Li ◽  
Long Chen ◽  
...  

Zr doping maintains the visible light absorption of LaTaON2 and contributes to enhanced photocatalytic activities for water splitting.



2014 ◽  
Vol 2 (42) ◽  
pp. 17820-17827 ◽  
Author(s):  
Chengzhi Wang ◽  
Zhuo Chen ◽  
Haibo Jin ◽  
Chuanbao Cao ◽  
Jingbo Li ◽  
...  

Transition metal doping substantially improves the performance of TiO2 nanorods for photoelectrochemical water splitting in the visible light region.



CrystEngComm ◽  
2017 ◽  
Vol 19 (14) ◽  
pp. 1938-1946 ◽  
Author(s):  
Jan Kegel ◽  
Jennifer Halpin ◽  
Fathima Laffir ◽  
Ian M. Povey ◽  
Martyn E. Pemble


2019 ◽  
Vol 44 (29) ◽  
pp. 14561-14570 ◽  
Author(s):  
Xin Zhao ◽  
Wenzhong Wang ◽  
Yujie Liang ◽  
Lizhen Yao ◽  
Junli Fu ◽  
...  


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