Carrier Engineering of Zr-mediated Ta3N5 Film as Efficient Photoanode for Solar Water Splitting

Author(s):  
Xin Zou ◽  
Xueyang Han ◽  
Chengxiong Wang ◽  
Yunkun Zhao ◽  
Chun Du ◽  
...  

Ta3N5 is regarded as a promising candidate material with adequate visible light absorption and band structure for photoelectrochemical water splitting. However, the performance of Ta3N5 is severely limited by the...




2019 ◽  
Vol 7 (24) ◽  
pp. 14816-14824 ◽  
Author(s):  
Mengyuan Zhang ◽  
Huu Khue Pham ◽  
Yanan Fang ◽  
Ying Fan Tay ◽  
Fatwa F. Abdi ◽  
...  

Mixed metal vanadates are an interesting class of materials due to their favorable bandgap for visible light absorption and their catalytic activity.





Author(s):  
Abhinav Bhanawat ◽  
Keyong Zhu ◽  
Laurent Pilon

This paper aims to systematically investigate the effect of gas bubbles formation on the performance of a horizontal photoelectrode exposed to normally incident light during photoelectrochemical water splitting. The presence...



2021 ◽  
Vol 02 ◽  
Author(s):  
Yimeng Cao ◽  
Chuhong Zhu ◽  
Taotao Wang ◽  
Daochuan Jiang ◽  
Sheng Ye

: Photocatalytic water splitting for hydrogen production is a promising pathway for solar energy convention into chemicals. Among various semiconductor-based photocatalysts, cadmium sulfide (CdS) attracted extensive attentions due to the narrow band gap nature (2.4 eV) for efficient visible light absorption, suitable band position for water splitting, and outstanding photocatalytic activity. In this review, we summarize the recent advances for the synthesis of CdS, and modification strategies including heteroatom doping, loading cocatalysts, and hetero/homo-junction fabrication are also presented. Moreover, a brief perspective and challenges on CdS-based photocatalyst are also discussed.





2020 ◽  
Vol 53 (6) ◽  
pp. 1425-1433
Author(s):  
Aya Amin ◽  
Ali El-dissouky

Although alloying and nanostructuring offer a great opportunity for enhancing photoelectrochemical behavior and band gap tuning, these methods have not been investigated extensively. This article reports the synthesis of Cu2ZnNiO3 complex oxide nanowires (∼200 nm) grown on German silver alloy via a one-step optimized hydrothermal route and their utilization to split water photoelectrochemically. Surface characterizations were used to elucidate the formation mechanism of the Cu2ZnNiO3 complex oxide nanowires. The nanowires exhibited an exceptional visible light absorption extending from 400 to 1400 nm wavelengths with a tuned band gap of ∼2.88 eV calculated from the corresponding Tauc plot. In tests to split water photoelectrochemically, the nanowires generated a significant photocurrent of up to −2.5 mA cm−2 at −0.8 V versus Ag/AgCl and exhibited an exceptional photostability which exceeded 2 h under light-off conditions with no photocurrent decay. Band edge positions related to water redox potentials were estimated via Mott–Schottky and diffuse reflectance spectroscopy analysis with the density of charge carriers reaching as high as 5.15 × 1018 cm−3. Moreover, the nanowires generated ∼1100 µmol of H2 in 5 h. These photoelectrochemical results are much higher than the reported values for similar structures of copper oxide, zinc oxide and nickel oxide separately under the same conditions, which can be attributed to the advantages of Cu, Zn and Ni oxides (such as visible light absorption, photostability, and efficient charge carrier generation and transport) being combined in one single material. These promising results make German silver a robust material toward photoelectrochemical water splitting.



2020 ◽  
Vol 3 (12) ◽  
pp. 11886-11892
Author(s):  
Salim Caliskan ◽  
Jung Kyu Kim ◽  
Gill Sang Han ◽  
Fen Qin ◽  
In Sun Cho ◽  
...  


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