Investigating the propagation kinetics of a novel class of nitrogen-containing methacrylates via PLP-SEC

Polymer Chemistry ◽

10.1039/c6py00867d ◽

2016 ◽

Vol 7 (26) ◽

pp. 4342-4351 ◽

Author(s):

Katrin B. Kockler ◽

Friederike Fleischhaker ◽

Christopher Barner-Kowollik

Keyword(s):

Size Exclusion Chromatography ◽

Rate Coefficient ◽

Pulsed Laser ◽

Propagation Rate ◽

Size Exclusion ◽

Arrhenius Parameters ◽

Exclusion Chromatography ◽

Kinetics Of ◽

Propagation Rate Coefficient ◽

Pulsed Laser Polymerization

The Mark–Houwink–Kuhn–Sakurada parameters as well as Arrhenius parameters of the propagation rate coefficient for a new group of nitrogen-containing methacrylates were determined via triple detector SEC and pulsed laser polymerization–size exclusion chromatography, respectively.

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Determination of Propagation Rate Coefficient for the Polymerization of N-Vinylpyrrolidone in Aqueous Solution by Pulsed Electron Polymerization and Size Exclusion Chromatography

ACS Macro Letters ◽

10.1021/mz500294c ◽

2014 ◽

Vol 3 (7) ◽

pp. 639-642 ◽

Author(s):

Nina Bartoszek ◽

Piotr Sawicki ◽

Sławomir Kadłubowski ◽

Piotr Ulański ◽

Janusz M. Rosiak

Keyword(s):

Aqueous Solution ◽

Size Exclusion Chromatography ◽

Rate Coefficient ◽

Propagation Rate ◽

Size Exclusion ◽

Exclusion Chromatography ◽

Propagation Rate Coefficient

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Determination of vinyl acetate propagation rate coefficients via high frequency pulsed laser polymerization

10.1515/epoly.2009.9.1.931 ◽

2009 ◽

Vol 9 (1) ◽

Author(s):

Thomas Junkers ◽

Dominik Voll ◽

Christopher Barner-Kowollik

Keyword(s):

Vinyl Acetate ◽

Pulsed Laser ◽

Propagation Rate ◽

Size Exclusion ◽

Rate Coefficients ◽

Exclusion Chromatography ◽

Propagation Rate Coefficient ◽

Good Agreement ◽

Pulsed Laser Polymerization

AbstractNew data on the propagation rate coefficient, kp, of vinyl acetate (VAc) are obtained via the IUPAC recommended method of pulsed laser polymerization - size exclusion chromatography (PLP-SEC) operated at 500 Hz laser repetition rate. An apparent dependency of the experiment’s outcome on the laser pulsing rate is identified with kp being about 25 % larger at 500 Hz compared to 100 Hz. The temperature dependence of kp was determined to fit ln kp = 17.12 - 2621 K/T; data is in generally good agreement with literature values when the previous underestimation of kp by 100 Hz laser pulsing experiments is taken into account.

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Radical Propagation Kinetics ofN-Vinylpyrrolidone in Organic Solvents Studied by Pulsed-Laser Polymerization-Size-Exclusion Chromatography (PLP-SEC)

Macromolecular Chemistry and Physics ◽

10.1002/macp.201400329 ◽

2014 ◽

Vol 215 (23) ◽

pp. 2327-2336 ◽

Author(s):

Lucia Uhelská ◽

Dušan Chorvát ◽

Robin A. Hutchinson ◽

Sandhya Santanakrishnan ◽

Michael Buback ◽

...

Keyword(s):

Organic Solvents ◽

Size Exclusion Chromatography ◽

Pulsed Laser ◽

Size Exclusion ◽

Exclusion Chromatography ◽

Radical Propagation ◽

Pulsed Laser Polymerization

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Pulsed-laser polymerization-gel permeation chromatographic determination of the propagation-rate coefficient for the methyl acrylate dimer: A sterically hindered monomer

Journal of Polymer Science Part A Polymer Chemistry ◽

10.1002/pola.10034 ◽

2001 ◽

Vol 39 (22) ◽

pp. 3902-3915 ◽

Author(s):

Kenta Tanaka ◽

Bunichiro Yamada ◽

Christopher M. Fellows ◽

Robert G. Gilbert ◽

Thomas P. Davis ◽

...

Keyword(s):

Methyl Acrylate ◽

Rate Coefficient ◽

Pulsed Laser ◽

Chromatographic Determination ◽

Propagation Rate ◽

Gel Permeation ◽

Sterically Hindered ◽

Propagation Rate Coefficient ◽

Pulsed Laser Polymerization

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Pseudostationary Pulsed Laser Polymerization: A Simple Method for the Direct Determination of Axial Dispersion as Occurring in Size Exclusion Chromatography

Macromolecular Theory and Simulations ◽

10.1002/mats.200390027 ◽

2003 ◽

Vol 12 (4) ◽

pp. 259-269 ◽

Author(s):

Andreas Kornherr ◽

Oskar Friedrich Olaj ◽

Irene Schnöll-Bitai ◽

Gerhard Zifferer

Keyword(s):

Size Exclusion Chromatography ◽

Pulsed Laser ◽

Direct Determination ◽

Axial Dispersion ◽

Size Exclusion ◽

Simple Method ◽

Exclusion Chromatography ◽

Pulsed Laser Polymerization

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Pulsed Laser Polymerization of Styrene in Microemulsion: Determination of Band Broadening in Size Exclusion Chromatography with Multimodal Distributions

Macromolecular Chemistry and Physics ◽

10.1002/macp.200400477 ◽

2005 ◽

Vol 206 (6) ◽

pp. 649-657 ◽

Author(s):

Christoph Mader ◽

Irene Schnöll-Bitai

Keyword(s):

Size Exclusion Chromatography ◽

Pulsed Laser ◽

Size Exclusion ◽

Band Broadening ◽

Multimodal Distributions ◽

Exclusion Chromatography ◽

Pulsed Laser Polymerization

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Pulsed-Laser Polymerization Measurements of the Propagation Rate Coefficient for Butyl Acrylate

Macromolecules ◽

10.1021/ma950747n ◽

1996 ◽

Vol 29 (6) ◽

pp. 1918-1927 ◽

Author(s):

Robert A. Lyons ◽

Jelica Hutovic ◽

Mark C. Piton ◽

David I. Christie ◽

Paul A. Clay ◽

...

Keyword(s):

Butyl Acrylate ◽

Rate Coefficient ◽

Pulsed Laser ◽

Propagation Rate ◽

Propagation Rate Coefficient ◽

Pulsed Laser Polymerization

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Determination of Propagation Rate Coefficient of Free-Radical Polymerization of N-Vinylcarbazole by Pulsed-Laser Polymerization

Polymer Journal ◽

10.1295/polymj.31.878 ◽

1999 ◽

Vol 31 (10) ◽

pp. 878-882 ◽

Author(s):

Masataka Ohoka ◽

Sadahito Misumi ◽

Masahide Yamamoto

Keyword(s):

Free Radical ◽

Radical Polymerization ◽

Rate Coefficient ◽

Pulsed Laser ◽

Free Radical Polymerization ◽

Propagation Rate ◽

Propagation Rate Coefficient ◽

Pulsed Laser Polymerization

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Exploiting the pulsed laser polymerization-size exclusion chromatography technique to retrieve kinetic parameters in radical polymerization: State-of-the-art and future challenges

Advances in Polymer Reaction Engineering - Advances in Chemical Engineering ◽

10.1016/bs.ache.2020.08.001 ◽

2020 ◽

pp. 59-95

Author(s):

Yoshi W. Marien ◽

Mariya Edeleva ◽

Paul H.M. Van Steenberge ◽

Dagmar R. D'hooge

Keyword(s):

Kinetic Parameters ◽

Radical Polymerization ◽

Size Exclusion Chromatography ◽

State Of The Art ◽

Pulsed Laser ◽

Size Exclusion ◽

Future Challenges ◽

Exclusion Chromatography ◽

Pulsed Laser Polymerization

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Determination of the propagation rate coefficient for 3-[tris(trimethylsilyloxy)silyl] propyl methacrylate by pulsed-laser polymerization

Polymer ◽

10.1016/s0032-3861(99)00319-5 ◽

2000 ◽

Vol 41 (4) ◽

pp. 1441-1447 ◽

Author(s):

L Muratore

Keyword(s):

Rate Coefficient ◽

Pulsed Laser ◽

Propagation Rate ◽

Propyl Methacrylate ◽

Propagation Rate Coefficient ◽

Pulsed Laser Polymerization

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