Radical Propagation Kinetics ofN-Vinylpyrrolidone in Organic Solvents Studied by Pulsed-Laser Polymerization-Size-Exclusion Chromatography (PLP-SEC)

2014 ◽  
Vol 215 (23) ◽  
pp. 2327-2336 ◽  
Author(s):  
Lucia Uhelská ◽  
Dušan Chorvát ◽  
Robin A. Hutchinson ◽  
Sandhya Santanakrishnan ◽  
Michael Buback ◽  
...  
Keyword(s):  
Organic Solvents ◽  
Size Exclusion Chromatography ◽  
Pulsed Laser ◽  
Size Exclusion ◽  
Exclusion Chromatography ◽  
Radical Propagation ◽  
Pulsed Laser Polymerization

scholarly journals Radical Propagation Kinetics ofN-Vinylpyrrolidone in Organic Solvents Studied by Pulsed-Laser Polymerization-Size-Exclusion Chromatography (PLP-SEC)

2015 ◽  
Vol 216 (2) ◽  
pp. 235-235
Author(s):  
Lucia Uhelská ◽  
Dušan Chorvát ◽  
Robin A. Hutchinson ◽  
Sandhya Santanakrishnan ◽  
Michael Buback ◽  
...  
Keyword(s):  
Organic Solvents ◽  
Size Exclusion Chromatography ◽  
Pulsed Laser ◽  
Size Exclusion ◽  
Exclusion Chromatography ◽  
Radical Propagation ◽  
Pulsed Laser Polymerization

Investigating the propagation kinetics of a novel class of nitrogen-containing methacrylates via PLP-SEC

2016 ◽  
Vol 7 (26) ◽  
pp. 4342-4351 ◽  
Author(s):  
Katrin B. Kockler ◽  
Friederike Fleischhaker ◽  
Christopher Barner-Kowollik
Keyword(s):  
Size Exclusion Chromatography ◽  
Rate Coefficient ◽  
Pulsed Laser ◽  
Propagation Rate ◽  
Size Exclusion ◽  
Arrhenius Parameters ◽  
Exclusion Chromatography ◽  
Kinetics Of ◽  
Propagation Rate Coefficient ◽  
Pulsed Laser Polymerization

The Mark–Houwink–Kuhn–Sakurada parameters as well as Arrhenius parameters of the propagation rate coefficient for a new group of nitrogen-containing methacrylates were determined via triple detector SEC and pulsed laser polymerization–size exclusion chromatography, respectively.

Depropagation Kinetics of Sterically Demanding Monomers:  A Pulsed Laser Size Exclusion Chromatography Study

2005 ◽  
Vol 38 (14) ◽  
pp. 5944-5954 ◽  
Author(s):  
Zachary Szablan ◽  
Martina H. Stenzel ◽  
Thomas P. Davis ◽  
Leonie Barner ◽  
Christopher Barner-Kowollik
Keyword(s):  
Size Exclusion Chromatography ◽  
Pulsed Laser ◽  
Size Exclusion ◽  
Sterically Demanding ◽  
Exclusion Chromatography ◽  
Kinetics Of

Critically evaluated propagation rate coefficients in free-radical polymerizations: Part III. Methacrylates with cyclic ester groups (IUPAC Technical Report)

2003 ◽  
Vol 75 (8) ◽  
pp. 1091-1096 ◽  
Author(s):  
Sabine Beuermann
Keyword(s):  
Free Radical ◽  
Size Exclusion Chromatography ◽  
Ambient Pressure ◽  
Pulsed Laser ◽  
Propagation Rate ◽  
Size Exclusion ◽  
Rate Coefficients ◽  
Arrhenius Relation ◽  
Technical Report ◽  
Exclusion Chromatography

Propagation rate coefficients, kp, as a function of temperature, are reported for bulk free-radical homopolymerizations of oxiranylmethyl, cyclohexyl, and benzyl methacrylate at ambient pressure and low conversion. The data were obtained from experiments combining pulsed-laser initiated polymerization and size-exclusion chromatography. The data determined from experiments carried out in independent laboratories obey the consistency criteria established for this technique. The rate coefficients for the three monomers are well represented by a single Arrhenius relation.

Determination of vinyl acetate propagation rate coefficients via high frequency pulsed laser polymerization

e-Polymers ◽  
2009 ◽  
Vol 9 (1) ◽  
Author(s):  
Thomas Junkers ◽  
Dominik Voll ◽  
Christopher Barner-Kowollik
Keyword(s):  
Vinyl Acetate ◽  
Pulsed Laser ◽  
Propagation Rate ◽  
Size Exclusion ◽  
Rate Coefficients ◽  
Exclusion Chromatography ◽  
Propagation Rate Coefficient ◽  
Good Agreement ◽  
Pulsed Laser Polymerization

AbstractNew data on the propagation rate coefficient, kp, of vinyl acetate (VAc) are obtained via the IUPAC recommended method of pulsed laser polymerization - size exclusion chromatography (PLP-SEC) operated at 500 Hz laser repetition rate. An apparent dependency of the experiment’s outcome on the laser pulsing rate is identified with kp being about 25 % larger at 500 Hz compared to 100 Hz. The temperature dependence of kp was determined to fit ln kp = 17.12 - 2621 K/T; data is in generally good agreement with literature values when the previous underestimation of kp by 100 Hz laser pulsing experiments is taken into account.

Preferential solvation of a dicyanate ester monomer and poly(sulfone) in different organic solvents by size-exclusion chromatography

2002 ◽  
Vol 942 (1-2) ◽  
pp. 53-61 ◽  
Author(s):  
Ileana B Recalde ◽  
Iolanda Porcar ◽  
Agustı́n Campos ◽  
Clara M Gómez
Keyword(s):  
Organic Solvents ◽  
Size Exclusion Chromatography ◽  
Preferential Solvation ◽  
Size Exclusion ◽  
Exclusion Chromatography
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