Atmospheric chemistry of ethers, esters, and alcohols on the lifetimes, temperature dependence, and kinetic isotope effect: an example of CF3CX2CX2CX2OX with OX reactions (X = H, D)

RSC Advances ◽

10.1039/c6ra04902h ◽

2016 ◽

Vol 6 (42) ◽

pp. 36096-36108 ◽

Author(s):

Feng-Yang Bai ◽

Xu Wang ◽

Yan-Qiu Sun ◽

Rong-Shun Wang ◽

Xiu-Mei Pan

Keyword(s):

Temperature Dependence ◽

Isotope Effect ◽

Atmospheric Chemistry ◽

Theoretical Basis ◽

Kinetic Isotope Effect ◽

Kinetic Isotope ◽

Kinetics Of ◽

Sound Theoretical Basis

Mechanisms and kinetics of the reaction of CF3CX2CX2CX2OX with OX (X= H, D) radical are investigated on a sound theoretical basis.

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ChemInform Abstract: KINETICS OF THE REACTIONS OF CYCLOPROPANE DERIVATEVES PART 4, KINETIC ISOTOPE EFFECT IN THE ISOMERIZATION OF CYCLOPROPYLAMIN

Chemischer Informationsdienst ◽

10.1002/chin.197343158 ◽

1973 ◽

Vol 4 (43) ◽

pp. no-no

Author(s):

D. A. LUCKRAFT ◽

P. J. ROBINSON

Keyword(s):

Isotope Effect ◽

Kinetic Isotope Effect ◽

Kinetic Isotope ◽

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Temperature dependence of stable carbon kinetic isotope effect for the oxidation reaction of ethane by OH radicals: Experimental and theoretical studies

Journal of Geophysical Research Atmospheres ◽

10.1002/2017jd026950 ◽

2017 ◽

Vol 122 (15) ◽

pp. 8310-8324 ◽

Author(s):

T. Piansawan ◽

M. Saccon ◽

L. Vereecken ◽

I. Gensch ◽

A. Kiendler-Scharr

Keyword(s):

Temperature Dependence ◽

Isotope Effect ◽

Oxidation Reaction ◽

Kinetic Isotope Effect ◽

Oh Radicals ◽

Theoretical Studies ◽

Stable Carbon ◽

Kinetic Isotope ◽

Experimental And Theoretical Studies

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Atmospheric chemistry of alkyl iodides: theoretical studies on the mechanisms and kinetics of CH3I/C2H5I + NO3 reactions

RSC Advances ◽

10.1039/c5ra16215g ◽

2015 ◽

Vol 5 (107) ◽

pp. 88087-88095 ◽

Author(s):

Feng-Yang Bai ◽

Xu Wang ◽

Yan-Qiu Sun ◽

Xiu-Mei Pan

Keyword(s):

Atmospheric Chemistry ◽

Theoretical Basis ◽

Theoretical Studies ◽

Alkyl Iodides ◽

Kinetics Of ◽

Sound Theoretical Basis

Mechanisms and kinetics of the reactions of the NO3 radical with CH3I and C2H5I have been investigated from a sound theoretical basis.

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Kinetics and anomalous temperature dependence of the kinetic isotope effect of reactions of cycloalkanes C5H10, C6H12 and C6D12 with OH radicals in aqueous solutions

Theoretical and Experimental Chemistry ◽

10.1007/s11237-008-9002-4 ◽

2008 ◽

Vol 44 (1) ◽

pp. 37-41 ◽

Author(s):

V. L. Lobachev ◽

E. S. Rudakov ◽

Ya. V. Matvienko ◽

L. K. Volkova

Keyword(s):

Aqueous Solutions ◽

Temperature Dependence ◽

Isotope Effect ◽

Kinetic Isotope Effect ◽

Oh Radicals ◽

Anomalous Temperature Dependence ◽

Anomalous Temperature ◽

Kinetic Isotope

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Deuterium Kinetic Isotope Effect and Temperature Dependence in the Reactions of CH[2Π] with Methane and Acetylene

The Journal of Physical Chemistry A ◽

10.1021/jp9630333 ◽

1997 ◽

Vol 101 (10) ◽

pp. 1881-1886 ◽

Author(s):

Holger Thiesemann ◽

John MacNamara ◽

Craig A. Taatjes

Keyword(s):

Temperature Dependence ◽

Isotope Effect ◽

Kinetic Isotope Effect ◽

Kinetic Isotope

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Temperature dependence of the primary kinetic isotope effect for hydride transfer mediated by a NAD(P)H-model; discrimination between bent and linear transition states

Recueil des Travaux Chimiques des Pays-Bas ◽

10.1002/recl.19831020612 ◽

2010 ◽

Vol 102 (6) ◽

pp. 339-340 ◽

Author(s):

W. van Gerresheim ◽

J. W. Verhoeven

Keyword(s):

Temperature Dependence ◽

Isotope Effect ◽

Kinetic Isotope Effect ◽

Transition States ◽

Hydride Transfer ◽

Model Discrimination ◽

Kinetic Isotope

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Quantum Mechanical Tunneling in Homodienyl Sigmatropic [1,5]-Hydrogen Shifts of (Hydroxymethyl)styrylcyclopropanes

Australian Journal of Chemistry ◽

10.1071/ch9901071 ◽

1990 ◽

Vol 43 (6) ◽

pp. 1071 ◽

Author(s):

GG Pegg ◽

GV Meehan

Keyword(s):

Low Temperature ◽

Temperature Dependence ◽

Isotope Effect ◽

Kinetic Isotope Effect ◽

Natural Compounds ◽

Quantum Mechanical ◽

Strong Temperature Dependence ◽

Quantum Mechanical Tunneling ◽

Hydrogen Migration ◽

Kinetic Isotope

The strong temperature dependence of the deuterium kinetic isotope effect observed for homodienyl [1,5]-hydrogen migration of [hydroxy (D)methyl] styrylcyclopropanes (1c,d) in hexane solvent is suggestive of a significant tunnelling contribution to the mechanism. While the hydroxy substituent at the migration origin appears to influence the thermolytic behaviour of these molecules, attempts to promote oxy anionic homodienyl rearrangement in the isotopically natural compounds (1a,b) at low temperature were unsuccessful.

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Additions and Corrections - Role of Solvent in the Mechanism of Amine Oxide Thermolysis Elucidated by the Temperature Dependence of a Kinetic Isotope Effect

Journal of the American Chemical Society ◽

10.1021/ja00388a606 ◽

1982 ◽

Vol 104 (24) ◽

pp. 6888-6888

Author(s):

Harold Kwart ◽

Martin Brechibiel

Keyword(s):

Temperature Dependence ◽

Isotope Effect ◽

Kinetic Isotope Effect ◽

Amine Oxide ◽

Kinetic Isotope ◽

Role Of Solvent

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An Examination of the Relationship Between Transition State Geometry in Hydron Transfer Reactions and the Temperature Dependence of the Primary Kinetic Isotope Effect

Israel Journal of Chemistry ◽

10.1002/ijch.198500123 ◽

1985 ◽

Vol 26 (4) ◽

pp. 378-386 ◽

Author(s):

Duncan J. Mclennan ◽

Peter M.W. Gill

Keyword(s):

Transition State ◽

Temperature Dependence ◽

Isotope Effect ◽

Kinetic Isotope Effect ◽

Transfer Reactions ◽

Kinetic Isotope ◽

Transition State Geometry ◽

The Relationship

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Formal kinetics of some competing bimolecular reactions, and how the kinetic isotope effect influences the distribution of isotopic molecules

Bulletin of the Academy of Sciences of the USSR Division of Chemical Science ◽

10.1007/bf00921341 ◽

1962 ◽

Vol 11 (11) ◽

pp. 1876-1888 ◽

Author(s):

G. A. Skrobogatov

Keyword(s):

Isotope Effect ◽

Kinetic Isotope Effect ◽

Bimolecular Reactions ◽

Kinetic Isotope ◽

Formal Kinetics ◽

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