Magnetic NiO nanoparticles confined within open ends MWCNTs: a novel and highly active catalyst for hydrogenation and synthesis of imines

RSC Advances ◽  
2016 ◽  
Vol 6 (63) ◽  
pp. 58805-58812 ◽  
Author(s):  
Gangquan Chen ◽  
Wenbin Gao ◽  
Xuejun Wang ◽  
Hongfei Huo ◽  
Wenzhu Li ◽  
...  

The novel catalyst is highly active for hydrogenation and synthesis of imines.

2019 ◽  
Vol 43 (23) ◽  
pp. 8930-8938 ◽  
Author(s):  
Zahra Tashrifi ◽  
Saeed Bahadorikhalili ◽  
Hossein Lijan ◽  
Samira Ansari ◽  
Haleh Hamedifar ◽  
...  

A novel catalyst is synthesized based on the immobilization of palladium on γ-Fe2O3@SiO2–(CH2)3–PDTC nanoparticles and is used as a highly active catalyst for the Heck/Sonogashira coupling reactions.


2017 ◽  
Vol 41 (3) ◽  
pp. 186-191 ◽  
Author(s):  
Dayi Liu ◽  
Pingping Wang ◽  
Jingting Ai ◽  
Mingzhong Cai

The novel MCM-41-immobilised nitrogen and sulfur mixed tridentate palladium(0) complex [MCM-41-2N,S-Pd(0)] was prepared from 3-(2-aminoethylamino)propyltrimethoxysilane by immobilisation on MCM-41, followed by reaction with thiophene-2-carboxaldehyde and PdCl2 and then reduction with hydrazine hydrate. This phosphine-free heterogeneous palladium(0) complex was a highly active catalyst for the Suzuki reaction of aryl bromides in air and could be recycled at least 8 times without significant loss of activity.


2011 ◽  
Vol 7 ◽  
pp. 426-431 ◽  
Author(s):  
Jie Li ◽  
Pengcheng Huang

Tetrabutylammonium hydroxide with methanol as an additive was found to be a highly active catalyst for the cleavage of 4-aryl-2-methyl-3-butyn-2-ols. The reaction was performed at 55–75 °C and gave terminal arylacetylenes in good to excellent yields within several minutes. Compared with the usual reaction conditions (normally >110 °C, several hours), this novel catalyst system can dramatically decrease the reaction time under much milder conditions.


2021 ◽  
Author(s):  
Yufa Feng ◽  
Jinyun Liao ◽  
Xiaodong Chen ◽  
Qingyu Liao ◽  
Huize Wang ◽  
...  

Developing low-cost and highly active hydrolysis catalytic materials for the dehydrogenation of hydrogen-rich chemicals is a promising strategy to store and easily release hydrogen for fuel cell applications. In this...


Author(s):  
Ying Duan ◽  
Yangyang Ma ◽  
Yanfu Xie ◽  
Dongmi Li ◽  
Dongsheng Deng ◽  
...  

2002 ◽  
Vol 756 ◽  
Author(s):  
Jamie Holladay ◽  
Evan Jones ◽  
Daniel R. Palo ◽  
Max Phelps ◽  
Ya-Huei Chin ◽  
...  

ABSTRACTMiniature and microscale fuel processors that incorporate novel catalysts and microtechnology-based designs are discussed. The novel catalyst allows for methanol reforming at high gas hourly space velocities of 50,000 hr-1 or higher while maintaining a carbon monoxide levels at 1% or less. The microtechnology-based designs extremely compact and lightweight devices. The miniature fuel processors, with a volume less than 25 cm3, a mass less than 200 grams, and thermal efficiencies of up to 83%, nominally provide 25 to 50 watts equivalent of hydrogen, which is ample for the portable power supplies described here. With reasonable assumptions on fuel cell efficiencies, anode gas and water management, parasitic power loss, the energy density was estimated at 1700 Whr/kg. These processors have been demonstrated with a CO cleanup method and a fuel cell stack. The microscale fuel processors, with a volume of less than 0.25 cm3 and a mass of less than 1 gram, are designed to provide up to 0.3 watt equivalent of power with efficiencies over 20%.


2017 ◽  
Vol 32 (3) ◽  
pp. e4184 ◽  
Author(s):  
Yahong Yao ◽  
Yanxia Du ◽  
Jun Li ◽  
Chen Wang ◽  
Zengqi Zhang ◽  
...  

ChemInform ◽  
2004 ◽  
Vol 35 (5) ◽  
Author(s):  
Masaaki Haneda ◽  
Tomohiro Yoshinari ◽  
Kazuhito Sato ◽  
Yoshiaki Kintaichi ◽  
Hideaki Hamada

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