Methanol Reforming Processes for Fuel Cell Applications

Hydrogen production through methanol reforming processes has been stimulated over the years due to increasing interest in fuel cell technology and clean energy production. Among different types of methanol reforming, the steam reforming of methanol has attracted great interest as reformate gas stream where high concentration of hydrogen is produced with a negligible amount of carbon monoxide. In this review, recent progress of the main reforming processes of methanol towards hydrogen production is summarized. Different catalytic systems are reviewed for the steam reforming of methanol: mainly copper- and group 8-10-based catalysts, highlighting the catalytic key properties, while the promoting effect of the latter group in copper activity and selectivity is also discussed. The effect of different preparation methods, different promoters/stabilizers, and the formation mechanism is analyzed. Moreover, the integration of methanol steam reforming process and the high temperature–polymer electrolyte membrane fuel cells (HT-PEMFCs) for the development of clean energy production is discussed.

Evaporation of Methanol Solution for a Methanol Steam Reforming System

In a methanol-reforming system, because the mixture of methanol and water must be evaporated before reaching the reforming reaction zone, having an appropriate evaporator design is a fundamental requirement for completing the reforming reaction. This study investigates the effect of the evaporator design for the stable reforming of methanol–water mixtures. Four types of evaporator are compared at the same heat duty of the methanol-reforming system. The four evaporators are planar heat exchangers containing a microchannel structure, cylindrical shell-and-tube evaporators, zirconia balls for internal evaporation, and combinations of cylindrical shell-tubes and zirconia balls. The results show that the evaporator configuration is critical in performing stable reform reactions, especially for the flow-field mode of the evaporator. Additionally, the combination of both internal and external evaporation methods generates the highest performance for the methanol-reforming system, with the methanol conversion reaching almost 98%.