Electrochemical behaviour of chromium–graphene composite coating

RSC Advances ◽  
2016 ◽  
Vol 6 (67) ◽  
pp. 62083-62090 ◽  
Author(s):  
Rekha M. Y. ◽  
M. K. Punith Kumar ◽  
Chandan Srivastava

This work illustrates the role of graphene in enhancing the corrosion resistant properties of chromium–graphene composite coating when compared to the corrosion resistant properties of pure chromium coating containing ZnO nanoparticles.

RSC Advances ◽  
2015 ◽  
Vol 5 (32) ◽  
pp. 25603-25608 ◽  
Author(s):  
M. K. Punith Kumar ◽  
Mahander Pratap Singh ◽  
Chandan Srivastava

Synthesis and electrochemical properties of highly corrosion resistant Zn–graphene composite coating.


2021 ◽  
pp. 108589
Author(s):  
Xuesha Li ◽  
Qianqian Shen ◽  
Yu Zhang ◽  
Lili Wang ◽  
Chaoyin Nie

2015 ◽  
Vol 9 (8) ◽  
pp. 972-982 ◽  
Author(s):  
Mei M. Wang ◽  
Yi C. Wang ◽  
Xi N. Wang ◽  
Yun Liu ◽  
Hong Zhang ◽  
...  

2008 ◽  
Vol 254 (8) ◽  
pp. 2325-2330
Author(s):  
S. Nathira Begum ◽  
V.S. Muralidharan ◽  
C. Ahmed Basha

2014 ◽  
Vol 67 (5) ◽  
pp. 819
Author(s):  
Syed Mujtaba Shah ◽  
Zafar Iqbal ◽  
Muzaffar Iqbal ◽  
Naila Shahzad ◽  
Amina Hana ◽  
...  

Porphyrin dyes have an inherent tendency to aggregate. This leads to a self-quenching phenomenon that hinders electron transfer to the conduction band of semiconductors in dye-sensitized solar cells. Self-quenching adversely affects the efficiency of solar cells. Here, we report the interaction of porphyrin with pristine and acid-functionalized fullerene molecules on the surface of ZnO nanoparticles under chemisorbed conditions. Chemisorption of porphyrin only on ZnO nanoparticles instigates aggregation of the porphyrin molecules. These aggregates can be effectively broken by chemisorbing fullerene molecules on the surface of the ZnO nanoparticles. This is due to self-assembly formation processes because of porphyrin–fullerene interactions. The nanohybrid material, consisting of ZnO nanorods, acid-functionalized porphyrin, and fullerene derivatives, was characterized by UV–visible spectroscopy, fourier transform infrared spectroscopy, fluorescence spectroscopy, and transmission electron microscopy. The material generates better performing dye-sensitized solar cells when compared with those fabricated from porphyrin-based photo-active material.


2021 ◽  
Vol 316 ◽  
pp. 827-832
Author(s):  
D. V. Ardashev ◽  
L.V. Shipulin ◽  
A.S. Degtyareva-Kashutina

We considered the processes of chromium plating the inner surfaces of the components of cylinders with hydrostatic guideways. We demonstrated the various aspects of the chromium plating process – the limitations placed on the machinery depending on the dimensions of the parts to be plated and the unevenness of the deposition rate of chromium along the length of the part. We developed a diagram of an installation for the application of a hard chromium coating on inner surfaces, which includes a cathode, an anode, a tank, and a pipeline. The distinctive features of the installation are the method of supplying the electrolyte at an angle to the horizontal, which allows us to supply the electrolyte through a turbulent flow swirling along a helical path, and the use of a chromium-plated installation casing. We studied various modes for applying a hard chromium coating on the inner surfaces of a hydraulic cylinder. As a result, we determined the optimal composition of the chromium electrolyte – the ratio of chromic anhydride and sulfuric acid – which is 10:1, respectively, and experimentally selected deposition modes. Chromium coatings obtained through the use of the concentrated electrolyte, which we developed, and the chromium plating method have 5...20% greater hardness and a 10...30-times reduction in porosity with the formation of a shiny, lumpy sludge, which corresponds to corrosion-resistant and wear-resistant coatings needed to manufacture hydraulic drives with highly efficient hydrostatic guideways.


2016 ◽  
Vol 2016 ◽  
pp. 1-12 ◽  
Author(s):  
Simona Popescu ◽  
Mihaela Mîndroiu ◽  
Daniela Cabuzu ◽  
Cristian Pîrvu

Cerium oxide nanoparticles (CeO2NPs) in crystalline form have been synthesized by a coprecipitation method. CeO2nanoparticles were then embedded in polypyrrole (PPy) films during the electropolymerization of pyrrole (Py) on titanium substrate. The influence of poly(sodium 4-styrenesulfonate) (NaPSS) surfactant used during polymerization on the embedding of CeO2NPs in polypyrrole films was investigated. The new films were characterized in terms of surface analysis, wettability, electrochemical behaviour, and antibacterial effect. The surface and electrochemical characterization revealed the role of surfactant on PPy doping process cerium oxide incorporation. In the presence of surfactant, CeO2NPs are preferentially embedded in the polymeric film while, without surfactant, the ceria nanoparticles are quasiuniformly spread as agglomerates onto polymeric films. The antibacterial effect of studied PPy films was substantially improved in the presence of cerium oxide and depends by the polymerization conditions.


Sign in / Sign up

Export Citation Format

Share Document