Potential continuous removal of toluene by ZnO nanorods grown on permeable alumina tube filters

RSC Advances ◽  
2016 ◽  
Vol 6 (57) ◽  
pp. 52360-52371 ◽  
Author(s):  
Faegheh Ghanbari ◽  
Mehdi Eskandari ◽  
Pariya Nazari ◽  
Saba Gharibzadeh ◽  
Saman Kohnehpoushi ◽  
...  

Vertical ZnO nanorods were successfully grown on the crystalline surface of an Al2O3 microfilter by the simple technique of evaporation of prepared solution at atmospheric pressure (ESAP) for photocatalytic degradation of toluene.

2016 ◽  
Vol 28 (5) ◽  
pp. 4025-4034 ◽  
Author(s):  
J. Prince Richard ◽  
I. Kartharinal Punithavathy ◽  
S. Johnson Jeyakumar ◽  
M. Jothibas ◽  
P. Praveen

2012 ◽  
Vol 85 (12) ◽  
pp. 1287-1292 ◽  
Author(s):  
Sawako Miyamoto ◽  
Tetsuya Hasegawa ◽  
Hiroyuki Takahashi ◽  
Tetsu Yonezawa ◽  
Hajime Kiyono ◽  
...  

2020 ◽  
Author(s):  
Andrew Skinner ◽  
Anthony DiBernardo ◽  
Arvid Masud ◽  
Nirupam Aich ◽  
Alexandre Pinto

The photocatalytic degradation of the azo dye tartrazine using zinc oxide (ZnO) as photocatalyst under ultraviolet light was investigated using a 2<sup>4</sup> factorial design. The variables studied were the aspect ratio of ZnO nanorods, the ZnO load, the initial pH of tartrazine solution, and the H<sub>2</sub>O<sub>2</sub> volume. These variables were studied aiming to maximize the tartrazine removal efficiency and the pseudo-1<sup>st</sup>-order rate constant of the removal process. The ZnO aspect ratio was tuned by varying the Lewis base during the synthesis, hexamethylenetetramine (HMTA) was used to prepare ZnO with low aspect ratio (ZnO_LowAR), and NaOH was used to prepare ZnO with high aspect ratio (ZnO_HighAR). The microstructural characterizations indicated that ZnO_LowAR and ZnO_HighAR nanorods have similar structural, textural and optical properties. The only exception was the dimensions of the nanorods obtained, which could result in differences in the facets exposed on each type of nanorod surface. The factorial design revealed that ZnO aspect ratio, the initial pH of tartrazine solution, and the H<sub>2</sub>O<sub>2</sub> volume all have primary significant effects, whereas the ZnO load is not significant neither in the tartrazine removal efficiency nor in the pseudo-1<sup>st</sup>-order rate constant. Statistical models considering the coefficients of the significant interactions were obtained, leading to reasonable predicted results in comparison to the results experimentally obtained. The conditions leading to highest removal efficiency (~92%) and pseudo-1<sup>st</sup>-order rate constant (3.81 x 10<sup>-2</sup> min<sup>-1</sup>) were carried out with ZnO_HighAR, initial pH 7, and without H<sub>2</sub>O<sub>2</sub>, which outperformed the TiO<sub>2</sub> P-25 under the same conditions.


2011 ◽  
Vol 93 (4) ◽  
pp. 623-634 ◽  
Author(s):  
L.A. Ghule ◽  
A.A. Patil ◽  
K.B. Sapnar ◽  
S.D. Dhole ◽  
K.M. Garadkar

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