Synthesis and characterization of 2′,3′-epoxy propyl-N-methyl-2-oxopyrrolidinium salicylate ionic liquid and study of its interaction with water or methanol

As a new environmentally friendly solvent, ionic liquids have been investigated widely. The lack of physico-chemical properties data of ionic liquids has become a bottleneck that restricts their applications. In this study, the investigation of the density for binary mixtures of CnpyNTf2 (n = 2, 4, 5) and methanol is measured using Westphal balance. This study would be very important for the application of binary mixtures of ionic liquid and methanol in developing new energy storage material.

Download Full-text

Tailoring ionic liquid catalysts: structure, acidity and catalytic activity of protonic ionic liquids based on anionic clusters, [(HSO4)(H2SO4)x]− (x = 0, 1, or 2)

Green Chemistry ◽

10.1039/c4gc00415a ◽

2014 ◽

Vol 16 (7) ◽

pp. 3463-3471 ◽

Cited By ~ 54

Author(s):

Karolina Matuszek ◽

Anna Chrobok ◽

Fergal Coleman ◽

Kenneth R. Seddon ◽

Małgorzata Swadźba-Kwaśny

Keyword(s):

Ionic Liquid ◽

Catalytic Activity ◽

Ionic Liquids ◽

Chemical Properties ◽

Esterification Reaction ◽

Anionic Clusters ◽

Physico Chemical

The speciation of a family of inexpensive, easily prepared protonic ionic liquids, their physico-chemical properties and their performance as catalysts in the model esterification reaction have been correlated.

Download Full-text

Dissolution of Absorbent Cotton in Ionic Liquid and Characterization of the Regenerated Cellulose

Advanced Materials Research ◽

10.4028/www.scientific.net/amr.830.163 ◽

2013 ◽

Vol 830 ◽

pp. 163-166 ◽

Cited By ~ 1

Author(s):

Ri Na Wu ◽

Hu Zhu ◽

Bei Hai He

Keyword(s):

Ionic Liquid ◽

Ionic Liquids ◽

Chemical Properties ◽

Regenerated Cellulose ◽

Absorbent Cotton ◽

Cellulose Films ◽

Cotton Linters ◽

Regenerated Cellulose Films ◽

Tga Analysis

Dissolution of absorbent cotton (DP above 4000) using ionic liquids as solvent and regeneration was investigated. The results show that 1-ally-3-methylimidazolium chloride (AMIMCl) was a good solvent to dissolve absorbent cotton and a solution of 3 wt% can be reached in 18 min at 120°C. Besides, as the dissolving temperature increased the time needed for the cotton linters to dissolve decreased. The physic-chemical properties of the regenerated cellulose films were also characterized by XRD, FTIR and TGA analysis.

Download Full-text

Synthesis and Characterization of Ru(II) Polypyridyl Complexes with 2-(4-Methylbenzoate)-1H-imidazo[4,5-f][1,10]phenantroline Ligand, and Their DNA Binding, Photocleavage, Physico-Chemical Properties, and Cytotoxicity

Russian Journal of General Chemistry ◽

10.1134/s1070363220120385 ◽

2020 ◽

Vol 90 (12) ◽

pp. 2456-2466

Author(s):

C. Nagamani ◽

P. V. Reddy ◽

M. R. Reddy ◽

K. L. Reddy ◽

S. Satyanarayana

Keyword(s):

Dna Binding ◽

Chemical Properties ◽

Synthesis And Characterization ◽

Polypyridyl Complexes ◽

Physico Chemical

Download Full-text

Synthesis and Characterization of Supported on Silica Based Ionic Liquids

Applied Mechanics and Materials ◽

10.4028/www.scientific.net/amm.727-728.34 ◽

2015 ◽

Vol 727-728 ◽

pp. 34-37

Author(s):

Li Ying Guo ◽

Jun Shi ◽

Jun Hai He ◽

Ji Yue Huang ◽

Peng Cheng Huang

Keyword(s):

Crystal Structure ◽

Ionic Liquid ◽

Ionic Liquids ◽

Chemical Structure ◽

Sol Gel ◽

Synthesis And Characterization ◽

Imidazolium Ionic Liquid ◽

Imidazolium Ionic Liquids ◽

Methyl Imidazole

Three kinds of functionalized imidazolium ionic liquid, 1-chloride (2-hydroxyethyl) -3-methyl imidazole ionic liquid [HeMIM]Cl, 1-bromide ethylamine-3-methyl imidazolium ionic liquid [AeMIM]Br and chlorinated 1-carboxyethyl-3-methyl imidazolium ionic liquid [CeMIM]Cl, were synthesized firstly. Subsequently, three kinds of supported silicon imidazolium ionic liquids were prepared from above ionic liquids with tetraethoxysilane by sol-gel method. The Chemical structure and crystal structure of the supported on silica based ionic liquids were analyzed by FTIR and XRD.

Download Full-text

ChemInform Abstract: Terpenes to Ionic Liquid: Synthesis and Characterization of Citronellal-Based Chiral Ionic Liquids.

ChemInform ◽

10.1002/chin.201005183 ◽

2010 ◽

Vol 41 (5) ◽

Author(s):

D. Nageshwar ◽

D. Muralimohan Rao ◽

Palle V. R. Acharyulu

Keyword(s):

Ionic Liquid ◽

Ionic Liquids ◽

Synthesis And Characterization ◽

Chiral Ionic Liquids

Download Full-text

Thermodynamics of ionic liquid evaporation under vacuum

Physical Chemistry Chemical Physics ◽

10.1039/c8cp02233j ◽

2018 ◽

Vol 20 (33) ◽

pp. 21262-21268 ◽

Cited By ~ 6

Author(s):

Shohei Horike ◽

Masato Ayano ◽

Masahiro Tsuno ◽

Tatsuya Fukushima ◽

Yasuko Koshiba ◽

...

Keyword(s):

Ionic Liquid ◽

Ionic Liquids ◽

Chemical Properties ◽

Physico Chemical ◽

Liquid Evaporation ◽

Evaporation Dynamics

The low volatility of ionic liquids (ILs) is one of their most interesting physico-chemical properties; however, the general understanding of their evaporation dynamics under vacuum is still lagging.

Download Full-text

Solid–ionic liquid interfaces: pore filling revisited

Physical Chemistry Chemical Physics ◽

10.1039/c4cp02749c ◽

2014 ◽

Vol 16 (44) ◽

pp. 24359-24372 ◽

Cited By ~ 19

Author(s):

M. T. Heinze ◽

J. C. Zill ◽

J. Matysik ◽

W. D. Einicke ◽

R. Gläser ◽

...

Keyword(s):

Ionic Liquid ◽

Ionic Liquids ◽

Mesoporous Silica ◽

Chemical Properties ◽

Liquid Interface ◽

Pore Geometry ◽

Liquid Interfaces ◽

Pore Filling ◽

Strength Of Interaction ◽

Physico Chemical

The strength of interaction at the mesoporous silica–ionic liquid interface and the pore geometry affect the materials' morphology and the physico-chemical properties of the ionic liquids.

Download Full-text