scholarly journals Solid–ionic liquid interfaces: pore filling revisited

2014 ◽  
Vol 16 (44) ◽  
pp. 24359-24372 ◽  
Author(s):  
M. T. Heinze ◽  
J. C. Zill ◽  
J. Matysik ◽  
W. D. Einicke ◽  
R. Gläser ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Ionic Liquids ◽  
Mesoporous Silica ◽  
Chemical Properties ◽  
Liquid Interface ◽  
Pore Geometry ◽  
Liquid Interfaces ◽  
Pore Filling ◽  
Strength Of Interaction ◽  
Physico Chemical

The strength of interaction at the mesoporous silica–ionic liquid interface and the pore geometry affect the materials' morphology and the physico-chemical properties of the ionic liquids.

Density Measurement of Pyridine Based Ionic Liquids and Methanol Binary Mixtures

2013 ◽  
Vol 675 ◽  
pp. 248-251
Author(s):  
Zhuo Li ◽  
Chang Ping Li
Keyword(s):  
Ionic Liquid ◽  
Ionic Liquids ◽  
Energy Storage ◽  
Binary Mixtures ◽  
Density Measurement ◽  
Chemical Properties ◽  
Storage Material ◽  
Physico Chemical ◽  
New Energy ◽  
Energy Storage Material

As a new environmentally friendly solvent, ionic liquids have been investigated widely. The lack of physico-chemical properties data of ionic liquids has become a bottleneck that restricts their applications. In this study, the investigation of the density for binary mixtures of CnpyNTf2 (n = 2, 4, 5) and methanol is measured using Westphal balance. This study would be very important for the application of binary mixtures of ionic liquid and methanol in developing new energy storage material.

Tailoring ionic liquid catalysts: structure, acidity and catalytic activity of protonic ionic liquids based on anionic clusters, [(HSO4)(H2SO4)x]− (x = 0, 1, or 2)

2014 ◽  
Vol 16 (7) ◽  
pp. 3463-3471 ◽  
Author(s):  
Karolina Matuszek ◽  
Anna Chrobok ◽  
Fergal Coleman ◽  
Kenneth R. Seddon ◽  
Małgorzata Swadźba-Kwaśny
Keyword(s):  
Ionic Liquid ◽  
Catalytic Activity ◽  
Ionic Liquids ◽  
Chemical Properties ◽  
Esterification Reaction ◽  
Anionic Clusters ◽  
Physico Chemical

The speciation of a family of inexpensive, easily prepared protonic ionic liquids, their physico-chemical properties and their performance as catalysts in the model esterification reaction have been correlated.

Synthesis and characterization of 2′,3′-epoxy propyl-N-methyl-2-oxopyrrolidinium salicylate ionic liquid and study of its interaction with water or methanol

RSC Advances ◽  
2016 ◽  
Vol 6 (66) ◽  
pp. 61566-61575 ◽  
Author(s):  
A. Vasanthakumar ◽  
I. Bahadur ◽  
G. Redhi ◽  
R. M. Gengan
Keyword(s):  
Ionic Liquid ◽  
Ionic Liquids ◽  
Chemical Properties ◽  
Synthesis And Characterization ◽  
Physico Chemical

Important physico-chemical properties of ionic liquids (ILs) can be manipulated by adjusting the nature of the cation or anion.

Thermodynamics of ionic liquid evaporation under vacuum

2018 ◽  
Vol 20 (33) ◽  
pp. 21262-21268 ◽  
Author(s):  
Shohei Horike ◽  
Masato Ayano ◽  
Masahiro Tsuno ◽  
Tatsuya Fukushima ◽  
Yasuko Koshiba ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Ionic Liquids ◽  
Chemical Properties ◽  
Physico Chemical ◽  
Liquid Evaporation ◽  
Evaporation Dynamics

The low volatility of ionic liquids (ILs) is one of their most interesting physico-chemical properties; however, the general understanding of their evaporation dynamics under vacuum is still lagging.

15N NMR studies provide insights into physico-chemical properties of room-temperature ionic liquids

2021 ◽  
Author(s):  
Christoph Wiedemann ◽  
David Fushman ◽  
Frank Bordusa
Keyword(s):  
Ionic Liquids ◽  
Room Temperature ◽  
Chemical Properties ◽  
Room Temperature Ionic Liquids ◽  
15N Nmr ◽  
Nmr Studies ◽  
Physico Chemical ◽  
Alternative Solvents

Ionic liquids (ILs) have gained a lot of attention as alternative solvents in many fields of science in the last two decades. It is known that the type of anion...

scholarly journals Mesoporous Silica Nanoparticles for Targeting Subcellular Organelles

2020 ◽  
Vol 21 (24) ◽  
pp. 9696
Author(s):  
Miguel Gisbert-Garzarán ◽  
Daniel Lozano ◽  
María Vallet-Regí
Keyword(s):  
Mesoporous Silica ◽  
Silica Nanoparticles ◽  
State Of The Art ◽  
Mesoporous Silica Nanoparticles ◽  
Drug Distribution ◽  
Chemical Properties ◽  
Drug Carriers ◽  
Subcellular Organelles ◽  
Physico Chemical ◽  
Tumoral Cells

Current chemotherapy treatments lack great selectivity towards tumoral cells, which leads to nonspecific drug distribution and subsequent side effects. In this regard, the use of nanoparticles able to encapsulate and release therapeutic agents has attracted growing attention. In this sense, mesoporous silica nanoparticles (MSNs) have been widely employed as drug carriers owing to their exquisite physico-chemical properties. Because MSNs present a surface full of silanol groups, they can be easily functionalized to endow the nanoparticles with many different functionalities, including the introduction of moieties with affinity for the cell membrane or relevant compartments within the cell, thus increasing the efficacy of the treatments. This review manuscript will provide the state-of-the-art on MSNs functionalized for targeting subcellular compartments, focusing on the cytoplasm, the mitochondria, and the nucleus.

Ionic Liquids in Analytical Chemistry: Applications and Recent Trends

2021 ◽  
Vol 17 ◽  
Author(s):  
Giuseppe Maria Merone ◽  
Angela Tartaglia ◽  
Enrica Rosato ◽  
Cristian D’Ovidio ◽  
Abuzar Kabir ◽  
...  
Keyword(s):  
Analytical Chemistry ◽  
Ionic Liquids ◽  
Stationary Phases ◽  
Extraction Procedure ◽  
Chemical Properties ◽  
Electrochemical Analysis ◽  
Physico Chemical ◽  
Recent Trends ◽  
Number Of Publications ◽  
Physical And Chemical

Background: Ionic liquids (ILs) are a unique class of compounds consisting exclusively of cations and anions that possess distinctive properties such as low volatility, high thermal stability, miscibility with water and organic solvents, electrolytic conductivity and non-flammability. Ionic liquids have been defined as "design solvents", because it is possible to modify their physical and chemical properties by appropriately choosing cations and anions, in order to meet the specific characteristics based on their potential application. Introduction: Due of their tunable nature and properties, ILs are considered as the perfect candidates for numerous applications in analytical chemistry including sample preparation, stationary phases in liquid or gas chromatography, additives in capillary electrophoresis, or in mass spectrometry for spectral and electrochemical analysis. In the last years, the number of publications regarding ILs has rapidly increased, highlighting the broad applications of these compounds in various fields of analytical chemistry. Results: This review first described the main physico-chemical characteristics of ionic liquids, and subsequently reported the various applications in different subdisciplines of analytical chemistry, including the extraction procedure and separation techniques. Furthermore, in each paragraph the most recent applications of ionic liquids in the food, environmental, biological, etc. fields have been described. Conclusion: Overall, the topic discussed highlights the key role of ionic liquids in analytical chemistry, giving hints for their future applications in chemistry but also in biology and medicine.

ChemInform Abstract: Physico-Chemical Properties of Task-Specific Ionic Liquids

ChemInform ◽  
2013 ◽  
Vol 44 (31) ◽  
pp. no-no
Author(s):  
Luis C. Branco ◽  
Goncalo V. S. M. Carrera ◽  
Joao Aires-de-Sousa ◽  
Ignacio Lopez Martin ◽  
Raquel Frade ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Chemical Properties ◽  
Physico Chemical

ChemInform Abstract: Physico-Chemical Properties and Phase Behavior of Piperidinium-Based Ionic Liquids

ChemInform ◽  
2012 ◽  
Vol 43 (24) ◽  
pp. no-no
Author(s):  
Urszula Domanska ◽  
Marta Krolikowska ◽  
Kamil Paduszynski
Keyword(s):  
Ionic Liquids ◽  
Phase Behavior ◽  
Chemical Properties ◽  
Physico Chemical

Viscosity models for ionic liquids and their mixtures

2020 ◽  
Author(s):  
Anya Fettouma Bouarab ◽  
Jean-Philippe Harvey ◽  
Christian Robelin
Keyword(s):  
Ionic Liquids ◽  
Process Optimization ◽  
Chemical Properties ◽  
Viscosity Models ◽  
Physico Chemical

As the field of ionic liquids matures to more industrially implemented applications, robust models of their physico-chemical properties become necessary for process optimization. Viscosity is a particularly difficult property to...

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