Synthesis and characterization of black pigments based on calcium manganese oxides for high near-infrared (NIR) reflectance

RSC Advances ◽  
2016 ◽  
Vol 6 (93) ◽  
pp. 90952-90957 ◽  
Author(s):  
Ryohei Oka ◽  
Toshiyuki Masui

Ca2Mn0.85Ti0.15O4 was synthesized as an inorganic black pigment with thermal barrier properties, and its NIR solar reflectance value was much greater than those of the conventional NIR reflective black pigments.

RSC Advances ◽  
2018 ◽  
Vol 8 (35) ◽  
pp. 19690-19700 ◽  
Author(s):  
Cheng Ding ◽  
Aijun Han ◽  
Mingquan Ye ◽  
Yu Zhang ◽  
Lingyun Yao ◽  
...  

A series of new yellow pigments was synthesized (BiP1−xVxO4), coatings colored with synthesized pigments have high NIR solar reflectance.


Author(s):  
Z. Zhou ◽  
N. Eguchi ◽  
H. Shirasawa ◽  
A. Ohmori

Abstract Hybrid plasma spraying combined with YAG laser irradiation was studied in order to obtain the optimum zirconia coatings for thermal barrier use. Zirconia coatings of approximately 150 ;Um in thickness were formed on the NiCrAlY under coated steel substrates both by means of conventional plasma spraying and hybrid plasma spraying under a variety of conditions. Post-laser irradiation was also conducted on the plasma as-sprayed coating for comparison. The microstructure of each coating was studied in detail and, for some representative coatings, thermal barrier properties were evaluated by hot erosion and a hot oxidation test. With hybrid spraying, performed under optimum conditions, it was found that a microstructure with appropriate partial densification and without connected porosities was formed and that cracks, which are generally produced in the post-laser irradiation treatment, were completely inhibited. In addition, hybrid spraying formed a smooth coating surface. These microstructural changes resulted in improved coating properties with regard to hardness, high temperature erosion resistance and oxidation resistance.


Materials ◽  
2021 ◽  
Vol 14 (16) ◽  
pp. 4653
Author(s):  
Jakub Herman ◽  
Piotr Harmata ◽  
Michał Czerwiński ◽  
Olga Strzeżysz ◽  
Marta Pytlarczyk ◽  
...  

The synthesis and characterization of new deuterated liquid crystal (LC) compounds based on phenyl tolane core is described in this paper. The work presents an alternative molecular approach to the conventional LC design. Correlations between molecular structure and mesomorphic and optical properties for compounds which are alkyl-hydrogen terminated and alkyl-deuterium, have been drawn. The compounds are characterized by mass spectrometry (electron ionization) analysis and infrared spectroscopy. They show enantiotropic nematic behavior in a broad temperature range, confirmed by a polarizing thermomicroscopy and differential scanning calorimetry. Detailed synthetic procedures are attached. Synthesized compounds show a significantly reduced absorption in the near-infrared (NIR) and medium-wavelength infrared (MWIR) radiation range, and stand as promising components of medium to highly birefringent liquid crystalline mixtures.


2019 ◽  
Vol 33 (36) ◽  
pp. 1950461 ◽  
Author(s):  
Yan Qi ◽  
Bingqian Bi ◽  
Yilin Yan ◽  
Lecheng Tian

In this study, a leaf-like [Formula: see text] mixed phase nanosheets array was successfully prepared by anodization. XRD, EDS, and XPS analysis confirmed the formation of [Formula: see text] mixed phase nanostructures. SEM images indicate that the fabricated [Formula: see text] mixed phase nanosheets almost grow vertically on the substrate. The average height of nanosheets is approximately 500 nm. The optical absorption of the mixed phase covers the entire wavelength region of visible light and a little part of the near-infrared region of short wavelength.


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