Three-dimensional freestanding hierarchically porous carbon materials as binder-free electrodes for supercapacitors: high capacitive property and long-term cycling stability

2016 ◽  
Vol 4 (15) ◽  
pp. 5623-5631 ◽  
Author(s):  
Fujun Miao ◽  
Changlu Shao ◽  
Xinghua Li ◽  
Kexin Wang ◽  
Na Lu ◽  
...  

Three-dimensional freestanding hierarchically porous carbon was successfully fabricated and assembled in a symmetric supercapacitor presenting outstanding electrochemical performance.

RSC Advances ◽  
2016 ◽  
Vol 6 (65) ◽  
pp. 59976-59983 ◽  
Author(s):  
Yan Zhang ◽  
Jie Xu ◽  
Yayun Zheng ◽  
Xiaoyang Hu ◽  
Yuanyuan Shang ◽  
...  

Three-dimensional interconnected CuS nanowalls with rough surfaces on Ni foam were obtained through a facial ​ synthetic route. The binder-free electrode exhibits high electrochemical performance with excellent cycling stability.


2021 ◽  
Vol 4 (1) ◽  
Author(s):  
Tomoki Ogoshi ◽  
Yuma Sakatsume ◽  
Katsuto Onishi ◽  
Rui Tang ◽  
Kazuma Takahashi ◽  
...  

AbstractCarbon materials with controlled pore sizes at the nanometer level have been obtained by template methods, chemical vapor desorption, and extraction of metals from carbides. However, to produce porous carbons with controlled pore sizes at the Ångstrom-level, syntheses that are simple, versatile, and reproducible are desired. Here, we report a synthetic method to prepare porous carbon materials with pore sizes that can be precisely controlled at the Ångstrom-level. Heating first induces thermal polymerization of selected three-dimensional aromatic molecules as the carbon sources, further heating results in extremely high carbonization yields (>86%). The porous carbon obtained from a tetrabiphenylmethane structure has a larger pore size (4.40 Å) than those from a spirobifluorene (4.07 Å) or a tetraphenylmethane precursor (4.05 Å). The porous carbon obtained from tetraphenylmethane is applied as an anode material for sodium-ion battery.


2015 ◽  
Vol 3 (18) ◽  
pp. 9438-9445 ◽  
Author(s):  
Chao Wu ◽  
Lijun Fu ◽  
Joachim Maier ◽  
Yan Yu

A novel free-standing cathode film consisting of hierarchically porous carbon-encapsulated sulfur has been designed and fabricated for Li–sulfur batteries.


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