Room temperature formation of organic–inorganic lead halide perovskites: design of nanostructured and highly reactive intermediates

2017 ◽  
Vol 5 (7) ◽  
pp. 3599-3608 ◽  
Author(s):  
Hong Zhang ◽  
Dan Li ◽  
Jiaqi Cheng ◽  
Francis Lin ◽  
Jian Mao ◽  
...  

We propose a room-temperature scheme of ligand-promoted formation of high-quality perovskite films through the judicious design of nanostructured PbI2·(L)x intermediates, where L denotes the ligand. The mechanisms and features of the ideal ligand have been investigated through a combined experimental and theoretical study.

Author(s):  
YingFeng Ruan ◽  
Pengju Guo ◽  
Zhiping Zheng ◽  
Qiuyun Fu ◽  
Rongda Zhou ◽  
...  

As a typical representative of all-inorganic lead halide perovskites, cesium lead bromine (CsPbBr3) has been regarded as the workhorse of next-generation room temperature X-ray detectors in recent years.


2016 ◽  
Vol 1735 ◽  
Author(s):  
Youzhen Li ◽  
Xuemei Xu ◽  
Chenggong Wang ◽  
Congong Wang ◽  
Fangyan Xie ◽  
...  

ABSTRACTLead halide perovskites have proven their great power conversion efficiency (PCE) in the last few years and attracted more and more attentions. Evaporation is an important method to get high quality perovskite films, especially for surface and interface investigation, which is important for the solar cell performance. In this paper, we present our investigations on growing PbI2 and CH3NH3I films by evaporation, and then CH3NH3PbI3 films by co-evaporation. X-ray photoemisson spectroscopy (XPS) was used to characterize the films. The results showed that CH3NH3I film was not stable in vacuum. Both N and I decreased in vacuum with time elapsing. PbI2 and CH3NH3PbI3 films are quite stable. The atomic ratio of CH3NH3PbI3 films (C: N: Pb: I =1.29:1.07:1.00:2.94) is very close to the ideal CH3NH3PbI3, which indicates that evaporation is a good method to get high quality perovskite films with accurate atomic ratio.


2019 ◽  
Vol 10 (9) ◽  
pp. 2270-2277 ◽  
Author(s):  
Ji-Hyun Cha ◽  
Kyungkyou Noh ◽  
Wenping Yin ◽  
Yongju Lee ◽  
Yongmin Park ◽  
...  

2015 ◽  
Vol 137 ◽  
pp. 253-257 ◽  
Author(s):  
Yajie Jiang ◽  
Martin A. Green ◽  
Rui Sheng ◽  
Anita Ho-Baillie

2021 ◽  
Vol 126 (21) ◽  
Author(s):  
Yeongsu Cho ◽  
Samuel M. Greene ◽  
Timothy C. Berkelbach

2022 ◽  
Vol 572 ◽  
pp. 151485
Author(s):  
Beichen Liu ◽  
Xubo Jia ◽  
Yang Nie ◽  
Honggang Ye

Nanoscale ◽  
2021 ◽  
Author(s):  
Yue Gao ◽  
Cheng Yan ◽  
Xiaodong Peng ◽  
Wen Li ◽  
Jingjing Cao ◽  
...  

All inorganic perovskites CsPbX3 (X=Cl, Br, I), a rising star of optical materials, have shown promising application prospects in optoelectronic and photovoltaic fields. However, some open issues still exist in...


2021 ◽  
Author(s):  
Qiangwen Fan ◽  
Longwei Zhu ◽  
Xuhuai Li ◽  
Huijun Ren ◽  
Haibo Zhu ◽  
...  

Using readily accessible and high-efficiency photocatalyst for inducing chemical transformations is highly desirable. All inorganic lead halide perovskites (APbX3, X=Cl, Br, I) utilized intensively in photovoltaics on the benefit of...


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