Ultrafast charge/discharge solid-state thin-film supercapacitors via regulating the microstructure of transition-metal-oxide

2017 ◽  
Vol 5 (6) ◽  
pp. 2759-2767 ◽  
Author(s):  
Qiying Lv ◽  
Kai Chi ◽  
Yan Zhang ◽  
Fei Xiao ◽  
Junwu Xiao ◽  
...  
Keyword(s):  
Thin Film ◽  
Solid State ◽  
Transition Metal ◽  
Metal Oxide ◽  
Frequency Response ◽  
Rate Capability ◽  
Transition Metal Oxide ◽  
Asymmetric Supercapacitor ◽  
Charge Discharge

A transition-metal-oxide-based asymmetric supercapacitor shows ultrafast rate capability and fast frequency response through regulating the microstructure of a vertical porous Fe2O3nanowall electrode.

P-doped ternary transition metal oxide as electrode material of asymmetric supercapacitor

2020 ◽  
Vol 28 ◽  
pp. 101248 ◽  
Author(s):  
Ting Xing ◽  
Yinhui Ouyang ◽  
Yulian Chen ◽  
Liping Zheng ◽  
Chun Wu ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Oxide ◽  
Electrode Material ◽  
Transition Metal Oxide ◽  
Asymmetric Supercapacitor

Opportunities for transition metal oxide devices in solid state random number generators

2019 ◽  
Author(s):  
Wellington Avelino ◽  
Bernardo L. Marques ◽  
Leonardo R. Fonseca ◽  
Douglas A. Ohlberg ◽  
Gilberto Medeiros-Ribeiro
Keyword(s):  
Solid State ◽  
Transition Metal ◽  
Metal Oxide ◽  
Random Number ◽  
Transition Metal Oxide ◽  
Random Number Generators

Pulsed laser deposition and characterization of LiMn2O4 thin Films for applications in Li Ion rechargeable battery systems

1999 ◽  
Vol 575 ◽  
Author(s):  
D. Singh ◽  
R. Houriet ◽  
R. Vacassy ◽  
H. Hofinann ◽  
V. Craciun ◽  
...  
Keyword(s):  
Thin Films ◽  
Transition Metal ◽  
Metal Oxide ◽  
Rate Capability ◽  
Pulsed Laser ◽  
Lithium Ion ◽  
Transition Metal Oxide ◽  
Porous Electrodes ◽  
High Rate ◽  
Electrochemical Characteristics

ABSTRACTMost studies focused on fundamental aspects of cathode materials in lithium ion battery employ porous electrodes, which are made of polymer bonded transition metal oxide powders mixed with conductors such as carbon. However, the powder morphology and the presence of carbon and polymeric binders affect the physical, chemical and electrochemical behaviors significantly. Therefore, transition metal oxide based materials in thin film form, which are dense and contain no additives, are emerging as promising alternatives to study fundamental properties in lithium ion batteries. Pulsed laser ablation (PLD) was used to deposit highly textured thin and thick porous films of LiMn2O4. Effect of various parameters such as substrates and deposition conditions were studied on the microstructure of these films. Microstructure studies of these films were carried out using x-ray diffraction and scanning electron microscopy. The electrochemical measurements were carried out in a glove box using cyclic voltammetery, electrochemical cycling and AC Impedance spectroscopy in a half-cell configuration with lithium metal as an anode and reference electrode and LiMn2O4 film as a cathode. Results indicate differences in film morphology greatly effect electrochemical kinetics of Li intercalation and de-intercalation. Thin films show good electrochemical characteristics such as high rate capability, good coulombic efficiency and rechargeability till 400 cycles.

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