cis-Specific cyanofluorination of vinyl azides enabled by electron-donor–acceptor complexes: synthesis of α-azido-β-fluoronitriles

2017 ◽  
Vol 53 (91) ◽  
pp. 12321-12324 ◽  
Author(s):  
Shu-Wei Wu ◽  
Jia-Li Liu ◽  
Feng Liu
Keyword(s):  
Electron Donor ◽  
Quaternary Carbon ◽  
Donor Acceptor ◽  
Vinyl Azides

The reaction protocol is operationally simple and conducted under an aerobic atmosphere, allowing highly functionalized α-azido-β-fluoronitriles bearing a quaternary carbon to be furnished, that are difficult to access by existing methods.

Metal-Free Photoinduced Hydroalkylation Cascade Enabled by an Electron-Donor-Acceptor Complex

2020 ◽  
Author(s):  
José Tiago Menezes Correia ◽  
Gustavo Piva da Silva ◽  
Camila Menezes Kisukuri ◽  
Elias André ◽  
Bruno Pires ◽  
...  
Keyword(s):  
Electron Donor ◽  
Functional Group ◽  
Photoexcited Electron ◽  
One Pot ◽  
Quaternary Centers ◽  
Metal Free ◽  
Acceptor Complex ◽  
Catalyst Free ◽  
Donor Acceptor ◽  
Radical Cascade

A metal- and catalyst-free photoinduced radical cascade hydroalkylation of 1,7-enynes has been disclosed. The process is triggered by a SET event involving a photoexcited electron-donor-aceptor complex between NHPI ester and Hantzsch ester, which decomposes to afford a tertiary radical that is readily trapped by the enyne. <a>The method provides an operationally simple, robust and step-economical approach to the construction of diversely functionalized dihydroquinolinones bearing quaternary-centers. A sequential one-pot hydroalkylation-isomerization approach is also allowed giving access to a family of quinolinones. A wide substrate scope and high functional group tolerance was observed in both approaches</a>.

Capturing polycyclic aromatic sulfur heterocycles in electron donor–acceptor complexes

2021 ◽  
Vol 31 (3) ◽  
pp. 326-329
Author(s):  
Olga E. Eremina ◽  
Mariia V. Samodelova ◽  
Mariia V. Ferree ◽  
Tatyana N. Shekhovtsova ◽  
Irina A. Veselova
Keyword(s):  
Electron Donor ◽  
Polycyclic Aromatic Sulfur Heterocycles ◽  
Polycyclic Aromatic ◽  
Donor Acceptor ◽  
Sulfur Heterocycles

Electrochromic 2,4,6-triphenyl-1,3,5-triazine based esters with electron donor-acceptor structure

2019 ◽  
Vol 67 ◽  
pp. 302-310 ◽  
Author(s):  
Weijing Zhang ◽  
Chunrong Zhu ◽  
Zhenjie Huang ◽  
Chengbin Gong ◽  
Qian Tang ◽  
...  
Keyword(s):  
Electron Donor ◽  
Donor Acceptor
Sign in / Sign up

Export Citation Format

Share Document