Effect of electron donor-acceptor interaction on the thermal stability of supramolecular side chain liquid crystalline polymers based on poly(3-carboxypropylmethylsiloxane)

2002 ◽  
Vol 29 (5) ◽  
pp. 675-685 ◽  
Author(s):  
Suat Hong Goh ◽  
Yee Hing Lai
2011 ◽  
Vol 181-182 ◽  
pp. 197-200
Author(s):  
Yu Lei Zhao ◽  
Wei Min Zhang ◽  
Ji Lei Li ◽  
Fan Fan Yu ◽  
Jia Ling Pu

A new type of able liquid crystalline polymer with a coumarin-containing mesogenic side group that could be photo-crosslinked was synthesized in this paper. The structure of the intermediates, monomers and polymers were characterized with FTIR and 1HNMR measurement. DSC, TG, and hot stage polarized optical microscopy were employed to study the phase transition temperature, mesophase texture, and thermal stability of the liquid crystalline polymers. The results indicated that both the monomer and polymer exhibited liquid-crystalline features over a wide temperature range.


1989 ◽  
Vol 175 ◽  
Author(s):  
M. Maeda ◽  
R.S. Kumar ◽  
A. Blumstein ◽  
S.K. Tripathy ◽  
P. Sixou ◽  
...  

AbstractIn an attempt to synthesize side chain liquid crystalline polymers containing NLO active moieties, a number of psubstituted aromatic azomethine phenols with donor-acceptor substituents such as N≡C and NO2 were prepared and incorporated into a polymer chain as side groups.Liquid crystalline properties of intermediate compounds composed of such moieties were explored separately and in mixtures. Phase diagrams were established. These intermediate compounds of M2C8 and M5C8 show interesting mesogenic properties.Methacrylic esters with such moieties were also synthesized. Homopolymer and copolymer systems with donor-acceptor substituents were obtained. Such copolymers also display liquid crystalline properties.


1993 ◽  
Vol 50 (9) ◽  
pp. 687-691 ◽  
Author(s):  
Seiji UJIIE ◽  
Tamami FUKUI ◽  
Kazuko HIGAKI ◽  
Satoshi TAKAHASHI ◽  
Kazuyoshi IIMURA

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