scholarly journals L-edge sum rule analysis on 3d transition metal sites: from d10to d0and towards application to extremely dilute metallo-enzymes

2018 ◽  
Vol 20 (12) ◽  
pp. 8166-8176 ◽  
Author(s):  
Hongxin Wang ◽  
Stephan Friedrich ◽  
Lei Li ◽  
Ziliang Mao ◽  
Pinghua Ge ◽  
...  
Keyword(s):  
Absorption Spectrum ◽  
Transition Metal ◽  
Metal Complex ◽  
Sum Rules ◽  
Sum Rule ◽  
X Ray ◽  
Metal Site ◽  
Integrated Intensity ◽  
Rule Analysis ◽  
X Ray Absorption

According to L-edge sum rules, the number of 3d vacancies at a transition metal site is directly proportional to the integrated intensity of the L-edge X-ray absorption spectrum (XAS) for the corresponding metal complex.

scholarly journals Backbonding contributions to small molecule chemisorption in a metal–organic framework with open copper(i) centers

2021 ◽  
Author(s):  
Gregory M. Su ◽  
Han Wang ◽  
Brandon R. Barnett ◽  
Jeffrey R. Long ◽  
David Prendergast ◽  
...  
Keyword(s):  
Fine Structure ◽  
Small Molecule ◽  
Metal Organic Framework ◽  
X Ray ◽  
Metal Site ◽  
Absorption Fine ◽  
Metal Organic ◽  
X Ray Absorption ◽  
Organic Framework

In situ near edge X-ray absorption fine structure spectroscopy directly probes unoccupied states associated with backbonding interactions between the open metal site in a metal–organic framework and various small molecule guests.

X-RAY ABSORPTION EDGES OF TRANSITION- METAL-DOPED Y1Ba2Cu3−xMxO7−∂

1988 ◽  
Vol 02 (05) ◽  
pp. 1153-1156 ◽  
Author(s):  
J. B. BOYCE ◽  
F. BRIDGES ◽  
T. CLAESON ◽  
T. H. GEBALLE ◽  
M. NYGREN ◽  
...  
Keyword(s):  
Transition Metal ◽  
X Ray ◽  
Metal Doped ◽  
X Ray Absorption ◽  
Absorption Edges

Sum rules for polarization-dependent x-ray absorption

1995 ◽  
Vol 51 (2) ◽  
pp. 1282-1285 ◽  
Author(s):  
A. Ankudinov ◽  
J. J. Rehr
Keyword(s):  
Sum Rules ◽  
X Ray ◽  
X Ray Absorption

107. Anisotropy effects in the linearly polarized X-ray absorption spectrum of Br2 intercalated graphite fibers and HOPG

Carbon ◽  
1984 ◽  
Vol 22 (2) ◽  
pp. 216
Author(s):  
J.L Feldman ◽  
E.F Skelton ◽  
A.C Ehrlich ◽  
D.D Dominguez ◽  
W.T Elam ◽  
...  
Keyword(s):  
Absorption Spectrum ◽  
X Ray ◽  
Intercalated Graphite ◽  
Linearly Polarized ◽  
Graphite Fibers ◽  
X Ray Absorption
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