scholarly journals Chemical tracer diffusion of Sr and Co in polycrystalline Ca-deficient CaMnO3−δwith CaMn2O4precipitates

2018 ◽  
Vol 20 (4) ◽  
pp. 2754-2760 ◽  
Author(s):  
Temesgen D. Desissa ◽  
Nikola Kanas ◽  
Sathya P. Singh ◽  
Kjell Wiik ◽  
Mari-Ann Einarsrud ◽  
...  

Enhanced grain boundary diffusivity on B-site of perovskite CaMnO3with CaMn2O4precipitates determines operational window of n-type oxide for thermoelectrics.

2001 ◽  
Vol 677 ◽  
Author(s):  
Irina V Belova ◽  
Graeme E Murch

ABSTRACTIn this paper we introduce a Monte Carlo method for numerical analysis of the problem of tracer diffusion in the presence of isolated grain boundaries with a variable mesh in the direction perpendicular to the grain boundary plane. A number of isoconcentration contour profiles were studied. Two different expressions for the angle between the isoconcentration contours and the grain boundary were derived for the instantaneous tracer source following procedures analogous to Fisher's and Whipple's approximations for the constant tracer source. Comparison with the numerical data was made. Both these approximations overestimate the grain boundary diffusivity.


2011 ◽  
Vol 65 (6) ◽  
pp. 513-515 ◽  
Author(s):  
Robert A. Brockman ◽  
Adam L. Pilchak ◽  
W. John Porter ◽  
Reji John

2017 ◽  
Vol 100 (12) ◽  
pp. 5379-5384 ◽  
Author(s):  
Lin Feng ◽  
Shen J. Dillon

Author(s):  
Hidehiro Yoshida ◽  
Koji Morita ◽  
Byung Nam Kim ◽  
Keijiro Hiraga ◽  
Takahisa Yamamoto ◽  
...  

2011 ◽  
Vol 4 (5) ◽  
pp. 055801 ◽  
Author(s):  
Ken Watanabe ◽  
Isao Sakaguchi ◽  
Shunichi Hishita ◽  
Naoki Ohashi ◽  
Hajime Haneda

2011 ◽  
Author(s):  
Adam L. Pilchak ◽  
Reji John ◽  
Robert A. Brockman ◽  
III Porter ◽  
W. J.

2001 ◽  
Vol 677 ◽  
Author(s):  
Irina V Belova ◽  
Graeme E Murch

ABSTRACTIn the present study we examine the well-known analysis in which the dislocation pipe diffusivity is determined by means of a grain boundary type analysis of the tail of a tracer concentration depth profile. We use a Monte Carlo grid method for testing the analysis. The results show that the analysis is really only satisfactory when the spacing between the dislocations is roughly twice the diffusion length (Dlt)½ where Dland t are the lattice diffusivity and time respectively.


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