Constructing two dimensional amide porous polymer to promote selective oxidation reactions

2017 ◽  
Vol 7 (14) ◽  
pp. 3143-3150 ◽  
Author(s):  
Rajiv Khatioda ◽  
Dhrubajyoti Talukdar ◽  
Basanta Saikia ◽  
Kusum K. Bania ◽  
Bipul Sarma
Keyword(s):  
Free Radical ◽  
Selective Oxidation ◽  
Porous Polymer ◽  
Radical Mechanism ◽  
Two Dimensional ◽  
Oxidation Reactions ◽  
Free Radical Mechanism ◽  
Selective Oxidation Reactions ◽  
Organic Catalyst

Rare example of carboxamide linked 2D COF has been synthesized and applied as robust organic catalyst for selective oxidation reactions with no metal add-ons. The reaction undergoes free radical mechanism aided by the conjugated π-cloud and amide functionality present in the COF.

Comparative QSAR evidence for a free-radical mechanism of phenol-induced toxicity

2000 ◽  
Vol 127 (1) ◽  
pp. 61-72 ◽  
Author(s):  
Corwin Hansch ◽  
Susan C. McKarns ◽  
Carr J. Smith ◽  
David J. Doolittle
Keyword(s):  
Free Radical ◽  
Radical Mechanism ◽  
Free Radical Mechanism

ChemInform Abstract: Characteristics of Selective Oxidation Reactions

ChemInform ◽  
2012 ◽  
Vol 43 (15) ◽  
pp. no-no
Author(s):  
Robert Schloegl ◽  
Christian Hess
Keyword(s):  
Selective Oxidation ◽  
Oxidation Reactions ◽  
Selective Oxidation Reactions

Synthesis of pure and uniform nano-sized TS-1 crystal with high titanium content and high space-time yield

2021 ◽  
Author(s):  
Lejian Zhang ◽  
Xiaoxiao Zhu ◽  
Xinping Wang ◽  
Chuan Shi
Keyword(s):  
Selective Oxidation ◽  
Cost Efficiency ◽  
Environmental Issues ◽  
Titanium Content ◽  
Space Time ◽  
Titanium Silicalite ◽  
Oxidation Reactions ◽  
High Space ◽  
Space Time Yield ◽  
Selective Oxidation Reactions

Anatase-free titanium silicalite-1 (TS-1) zeolite with high framework titanium content is highly required for catalysing selective oxidation reactions, while its synthesis generally suffers from cost, efficiency and environmental issues. Herein,...

Dirhodium(II)-Catalyzed Diamination Reaction via a Free Radical Pathway

2021 ◽  
Author(s):  
Zhiying Fan ◽  
Zhifan Wang ◽  
Ruoyi Shi ◽  
Yuanhua Wang
Keyword(s):  
Free Radical ◽  
Bond Formation ◽  
Mechanistic Study ◽  
Radical Mechanism ◽  
Free Radical Mechanism

Unlike C-N bond formation with classical dirhodium(II)-nitrenoids as the key intermediate, dirhodium(II)-catalyzed 1,2-and 1,3-diamination reactions are realized by a free radical mechanism. A mechanistic study revealed that the reactions undergo...

scholarly journals Selective Oxidation Reactions of Natural Compounds with Hydrogen Peroxide Mediated by Methyltrioxorhenium

Molecules ◽  
2013 ◽  
Vol 18 (11) ◽  
pp. 13754-13768 ◽  
Author(s):  
Maria Amato ◽  
Francesco Ballistreri ◽  
Andrea Pappalardo ◽  
Gaetano Tomaselli ◽  
Rosa Toscano ◽  
...  
Keyword(s):  
Hydrogen Peroxide ◽  
Selective Oxidation ◽  
Natural Compounds ◽  
Oxidation Reactions ◽  
Selective Oxidation Reactions
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