One-pot sustainable synthesis of tertiary alcohols by combining ruthenium-catalysed isomerisation of allylic alcohols and chemoselective addition of polar organometallic reagents in deep eutectic solvents

2017 ◽  
Vol 19 (13) ◽  
pp. 3069-3077 ◽  
Author(s):  
Luciana Cicco ◽  
María J. Rodríguez-Álvarez ◽  
Filippo M. Perna ◽  
Joaquín García-Álvarez ◽  
Vito Capriati
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Deep Eutectic Solvents ◽  
Allylic Alcohols ◽  
One Pot ◽  
Organometallic Reagents ◽  
Tertiary Alcohols

Transition-metal complexes and polarised organometallic reagents play together in Deep Eutectic Solvents.

scholarly journals Isomerization of allylic alcohols in water catalyzed by transition metal complexes

2019 ◽  
Vol 393 ◽  
pp. 118-148 ◽  
Author(s):  
Franco Scalambra ◽  
Pablo Lorenzo-Luis ◽  
Isaac de los Rios ◽  
Antonio Romerosa
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Allylic Alcohols

scholarly journals Programming cascade reactions interfacing biocatalysis with transition-metal catalysis in Deep Eutectic Solvents as biorenewable reaction media

2018 ◽  
Vol 20 (15) ◽  
pp. 3468-3475 ◽  
Author(s):  
Luciana Cicco ◽  
Nicolás Ríos-Lombardía ◽  
María J. Rodríguez-Álvarez ◽  
Francisco Morís ◽  
Filippo M. Perna ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Deep Eutectic Solvents ◽  
Cascade Reactions ◽  
Transition Metal Catalysis ◽  
Secondary Alcohols ◽  
Metal Catalysis ◽  
Eutectic Mixtures ◽  
Reaction Media

Transition-metal complexes and purified ketoreductases work together in eutectic mixtures for the synthesis of enantiopure secondary alcohols.

Versatile O- and S-functionalized 1,2,3-triazoliums: ionic liquids for the Baylis–Hillman reaction and ligand precursors for stable MIC-transition metal complexes

2015 ◽  
Vol 39 (3) ◽  
pp. 1587-1591 ◽  
Author(s):  
Daniel Mendoza-Espinosa ◽  
Rodrigo González-Olvera ◽  
Cecilia Osornio ◽  
Guillermo E. Negrón-Silva ◽  
Rosa Santillan
Keyword(s):  
Ionic Liquids ◽  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
High Performance ◽  
One Pot ◽  
Ligand Precursors ◽  
The One ◽  
Triazolium Salts

A series of O- and S-functionalized triazolium salts display high performance in the Baylis–Hillman addition and allow the one-pot formation of MIC-transition metal complexes.

scholarly journals The First One-Pot Synthesis of Metal-Organic Frameworks Functionalised with Two Transition-Metal Complexes

2014 ◽  
Vol 21 (2) ◽  
pp. 861-866 ◽  
Author(s):  
Ana E. Platero-Prats ◽  
Antonio Bermejo Gómez ◽  
Louise Samain ◽  
Xiaodong Zou ◽  
Belén Martín-Matute
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Metal Organic Frameworks ◽  
One Pot ◽  
One Pot Synthesis ◽  
Metal Organic

scholarly journals One-pot Synthesis of Dihydropyrimidinones Using Polyoxometalate Tri-supported Transition Metal Complexes

2011 ◽  
Vol 55 (4) ◽  
pp. 666-672
Author(s):  
Razieh Fazaeli ◽  
Hamid Aliyan ◽  
Foroogh Mohammadifar ◽  
Amir Abbas Zamani ◽  
Mohammad Javad Bagi
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
One Pot ◽  
One Pot Synthesis
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