Kinetic investigations of Cl atom initiated photo-oxidation reactions of cyclic unsaturated hydrocarbons in the gas phase: an experimental and theoretical study

2017 ◽  
Vol 41 (15) ◽  
pp. 7491-7505 ◽  
Author(s):  
S. Vijayakumar ◽  
C. B. Ramya ◽  
Avinash Kumar ◽  
B. Rajakumar
Keyword(s):  
Gas Phase ◽  
Oxidation Kinetics ◽  
Theoretical Study ◽  
Oxidation Reactions ◽  
Unsaturated Hydrocarbons ◽  
Photo Oxidation ◽  
Kinetic Investigations ◽  
Kinetics Of ◽  
Cl Atom

Cl atom initiated photo oxidation kinetics of cyclohexene and cycloheptene.

Kinetic investigations of chlorine atom initiated photo oxidation reactions of 2,3-dimethyl-1,3-butadiene in the gas phase: an experimental and theoretical study

RSC Advances ◽  
2016 ◽  
Vol 6 (72) ◽  
pp. 67739-67750 ◽  
Author(s):  
S. Vijayakumar ◽  
B. Rajakumar
Keyword(s):  
Experimental Method ◽  
Gas Phase ◽  
Chlorine Atom ◽  
Theoretical Study ◽  
Relative Rate ◽  
Rate Coefficients ◽  
Oxidation Reactions ◽  
Photo Oxidation ◽  
P Rate ◽  
Kinetic Investigations

Rate coefficients for the reaction of chlorine atoms with 2,3-dimethyl-1,3-butadiene were measured over the temperature range of 269–393 K by using a relative rate experimental method with reference to isoprene and 1-pentene.

Experimental and computational kinetic investigations for the reactions of Cl atoms with unsaturated ketones in the gas phase

2017 ◽  
Vol 41 (23) ◽  
pp. 14299-14314 ◽  
Author(s):  
S. Vijayakumar ◽  
Avinash Kumar ◽  
B. Rajakumar
Keyword(s):  
Gas Phase ◽  
Unsaturated Ketones ◽  
Photo Oxidation ◽  
Kinetic Investigations ◽  
Cl Atoms ◽  
Cl Atom

Cl atom initiated photo oxidation of unsaturated ketones.

Gas-Phase Anionic Metal Clusters are Model Systems for Surface Oxidation: Kinetics of the Reactions of Mn– with O2 (M = V, Cr, Co, Ni; n = 1–15)

2021 ◽  
Vol 125 (10) ◽  
pp. 2069-2076
Author(s):  
Brendan C. Sweeny ◽  
David C. McDonald ◽  
Nicholas S. Shuman ◽  
Albert A. Viggiano ◽  
Juergen Troe ◽  
...  
Keyword(s):  
Gas Phase ◽  
Oxidation Kinetics ◽  
Metal Clusters ◽  
Surface Oxidation ◽  
Model Systems ◽  
Kinetics Of

Theoretical study of the mechanisms for the homogenous gas-phase elimination kinetics of some 2-hydroxynitroalkanes

2006 ◽  
Vol 19 (12) ◽  
pp. 836-840 ◽  
Author(s):  
Rafael Añez ◽  
Rodolfo Izquierdo ◽  
Alba Vidal ◽  
Tania Cordova ◽  
Aníbal Sierraalta ◽  
...  
Keyword(s):  
Gas Phase ◽  
Theoretical Study ◽  
Elimination Kinetics ◽  
Kinetics Of ◽  
Phase Elimination

Gas phase interaction with catalytic oxidation reactions

1972 ◽  
Vol 326 (1565) ◽  
pp. 215-227 ◽  
Keyword(s):  
Carbon Dioxide ◽  
Maleic Anhydride ◽  
Catalytic Oxidation ◽  
Gas Phase ◽  
Major Part ◽  
Oxidation Reactions ◽  
Mixed Gas ◽  
Kinetics Of ◽  
Oxidation Of Benzene ◽  
Homogeneous Decomposition

Studies of the catalytic oxidation of benzene to maleic anhydride and carbon dioxide over vanadia/molybdena catalysts show that the major part of the reaction involves interacting gas and gas-solid processes. The results are consistent with a mechanism in which a benzeneoxygen adduct is formed catalytically, desorbs and then reacts to give maleic anhydride entirely in the gas phase. On the basis of this proposed mechanism, the kinetics of individual reactions have been investigated in some depth. The over-oxidation of maleic anhydride has been found to be not significant under the conditions of reaction. The kinetic relationships governing the homogeneous decomposition of the adduct and the oxidation of the adduct to maleic anhydride and to carbon dioxide have been established. The results show that essentially all of the anhydride originates from mixed gas-solid/gas reaction while substantial amounts of carbon dioxide are produced entirely catalytically.

A Combined Experimental and Theoretical Study of the Homogeneous, Unimolecular Decomposition Kinetics of 3-Chloropivalic Acid in the Gas Phase

2001 ◽  
Vol 105 (10) ◽  
pp. 1869-1875 ◽  
Author(s):  
Gabriel Chuchani ◽  
Alexandra Rotinov ◽  
Juan Andrés ◽  
Luís R. Domingo ◽  
V. Sixte Safont
Keyword(s):  
Gas Phase ◽  
Theoretical Study ◽  
Decomposition Kinetics ◽  
Unimolecular Decomposition ◽  
Kinetics Of
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