Mechanosynthesized copper(i) complex based initiating systems for redox polymerization: towards upgraded oxidizing and reducing agents

2017 ◽  
Vol 8 (38) ◽  
pp. 5884-5896 ◽  
Author(s):  
P. Garra ◽  
F. Dumur ◽  
A. Al Mousawi ◽  
B. Graff ◽  
D. Gigmes ◽  
...  
Keyword(s):  
Free Radical ◽  
Radical Polymerization ◽  
Free Radical Polymerization ◽  
Reducing Agents ◽  
Redox Polymerization ◽  
Dibenzoyl Peroxide

Significant improvements of the recently proposed Cu(i)/VitC + water/dibenzoyl peroxide (BPO) system for the redox free radical polymerization of methacrylates in air are presented here.

Polyacrylates and Polydienes to High Conversion by a Stable Free Radical Polymerization Process:  Use of Reducing Agents

1998 ◽  
Vol 31 (21) ◽  
pp. 7559-7561 ◽  
Author(s):  
Barkev Keoshkerian ◽  
Michael Georges ◽  
Marion Quinlan ◽  
Rick Veregin ◽  
Bruce Goodbrand
Keyword(s):  
Free Radical ◽  
Radical Polymerization ◽  
Free Radical Polymerization ◽  
Reducing Agents ◽  
Polymerization Process ◽  
High Conversion ◽  
Stable Free Radical ◽  
Process Use ◽  
Stable Free Radical Polymerization

New copper(i) complex based initiating systems in redox polymerization and comparison with the amine/benzoyl peroxide reference

2017 ◽  
Vol 8 (28) ◽  
pp. 4088-4097 ◽  
Author(s):  
P. Garra ◽  
A. Kermagoret ◽  
A. Al Mousawi ◽  
F. Dumur ◽  
D. Gigmes ◽  
...  
Keyword(s):  
Free Radical ◽  
Benzoyl Peroxide ◽  
Radical Polymerization ◽  
Copper Complex ◽  
Free Radical Polymerization ◽  
Redox Polymerization ◽  
Mild Conditions

Novel copper complex based initiating systems for redox free radical polymerization (FRP) of methacrylate resins under mild conditions are proposed.

Non-isothermal Kinetics of Free Radical Polymerization of 2-Phenylethyl (Meth)acrylate

2018 ◽  
Vol 8 (3) ◽  
pp. 585-594
Author(s):  
Khdbudin Mulani ◽  
Ravindra Ghorpade ◽  
Surendra Ponrathnam ◽  
Nayaku Chavan ◽  
Kamini Donde
Keyword(s):  
Free Radical ◽  
Radical Polymerization ◽  
Free Radical Polymerization ◽  
Isothermal Kinetics ◽  
Kinetics Of

Critically evaluated rate coefficients for free-radical polymerization, 3. Propagation rate coefficients for alkyl methacrylates

2000 ◽  
Vol 201 (12) ◽  
pp. 1355-1364 ◽  
Author(s):  
Sabine Beuermann ◽  
Michael Buback ◽  
Thomas P. Davis ◽  
Robert G. Gilbert ◽  
Robin A. Hutchinson ◽  
...  
Keyword(s):  
Free Radical ◽  
Radical Polymerization ◽  
Free Radical Polymerization ◽  
Propagation Rate ◽  
Rate Coefficients ◽  
Alkyl Methacrylates

Oxygen-Initiated Free-Radical Polymerization of Alkyl Acrylates at High Temperatures

2021 ◽  
Author(s):  
Shi Liu ◽  
Lauren Chua ◽  
Ahmad Arabi Shamsabadi ◽  
Patrick Corcoran ◽  
Abhirup Patra ◽  
...  
Keyword(s):  
Free Radical ◽  
Radical Polymerization ◽  
High Temperatures ◽  
Free Radical Polymerization ◽  
Alkyl Acrylates

One-Pot Free Radical Polymerization/Hydroxyl-Isocyanate Reaction: A Facile Strategy to Synthesize Hyperbranched Glycopoly(MaM/IM) with Tunable Structures

2021 ◽  
Author(s):  
Qian Zhou ◽  
Yuangong Zhang ◽  
Liping Fang ◽  
Hao Guan ◽  
Xin Wen ◽  
...  
Keyword(s):  
Free Radical ◽  
Radical Polymerization ◽  
Free Radical Polymerization ◽  
One Pot

FREE RADICAL POLYMERIZATION OF METHYL METHACRYLATE IN THE PRESENCE OF PHASE TRANSFER CATALYST—A KINETIC STUDY

2004 ◽  
Vol 53 (1) ◽  
pp. 95-103 ◽  
Author(s):  
M. Dharmendira Kumar ◽  
P. Konguvel Thehazhnan ◽  
M. J. Umapathy ◽  
M. Rajendran
Keyword(s):  
Free Radical ◽  
Methyl Methacrylate ◽  
Kinetic Study ◽  
Radical Polymerization ◽  
Phase Transfer ◽  
Free Radical Polymerization ◽  
Phase Transfer Catalyst
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