The pesent paper decribed the effects of additive on temperature rising characteristic during coal pyrolysis at different temperature in microwave field. Different mixture rate of carboncoal with coal and different final temperature on coal pyrolysis tempereature rising characteristics were studied in the work. The results indicate: Coal is a poorly microwave absorbing material, and its pyrolysis in microwave field need to add a certain amount of microwave absorbent for higher heating rate; Because carbocoal can be fast heated in microwave field, so it can be used as additive for coal pyrolysis. Carbocoal otained from different pyrolysis temperature have different heating rate, along with the increase of carbocoal pyrolysis temperature, carbocoal heating rate increases in microwave field. Using charcoal as microwave absorbent for coal rapid pyrolysis in microwave field is feasible.