Increased power factors of organic–inorganic nanocomposite thermoelectric materials and the role of energy filtering

2017 ◽  
Vol 5 (30) ◽  
pp. 15891-15900 ◽  
Author(s):  
Zhiming Liang ◽  
Mathias J. Boland ◽  
Kamal Butrouna ◽  
Douglas R. Strachan ◽  
Kenneth R. Graham

Enhancements in the performance of organic–inorganic nanocomposite thermoelectrics may be obtained with both small and large energy barriers at the organic–inorganic interfaces.

2016 ◽  
Vol 6 (11) ◽  
pp. 3984-3996 ◽  
Author(s):  
Jithin John Varghese ◽  
Quang Thang Trinh ◽  
Samir H. Mushrif

Of the three mechanisms for activation of methane on copper and copper oxide surfaces, the under-coordinated Cu–O site pair mediated mechanism on CuO surfaces has the lowest activation energy barriers.


2017 ◽  
Vol 8 (1) ◽  
pp. 1701313 ◽  
Author(s):  
Junjie Yu ◽  
Chenguang Fu ◽  
Yintu Liu ◽  
Kaiyang Xia ◽  
Umut Aydemir ◽  
...  

2020 ◽  
Vol 22 (15) ◽  
pp. 7935-7941
Author(s):  
Chidozie Onwudinanti ◽  
Geert Brocks ◽  
Vianney Koelman ◽  
Thomas Morgan ◽  
Shuxia Tao

The energy barriers to hydrogen diffusion from near-surface interstitial sites in ruthenium are determined by the presence of adsorbates.


Entropy ◽  
2019 ◽  
Vol 21 (3) ◽  
pp. 224
Author(s):  
Carlos Badillo-Ruiz ◽  
Miguel Olivares-Robles ◽  
Jose Chanona-Perez

In recent years the interest for the harvest of energy with micro thermoelectric generators ( μ TEG) has increased, due to its advantages compared to technologies that use fossil fuels. There are three ways to improve the performance of the device, by modifying its structure, type of material and operation control. In this study, the role of the load resistance R L on the performance of a μ TEG with nanostructured materials is investigated. The interaction of the load resistance with the thermoelements exhibits interesting features, arising from the coupling of the temperature-dependent electrical and thermal transport properties at different temperature ranges and the architecture of nanostructured thermoelectric materials. This coupling results in inflections on the efficiency, i.e., maximum and minimum values of the efficiency at higher temperatures, 600–900 K. We show the explicit dependence of the performance of the μ TEG in terms of the load resistance and discuss the underlying physics. The unusual features of the efficiency of nanostructured thermoelectric materials are a result of the behavior of the power factor and the nonequilibrium properties of the system. We also analyze the effect of the geometric shape of the thermoelements on the device. We determine the performance of the μ TEG, evaluating the generation power and its efficiency. The results show that the efficiency of the device can decrease or increase depending on the value of R L , while the power decreases with an increase of the load resistance.


2017 ◽  
Vol 19 (3) ◽  
pp. 2175-2185 ◽  
Author(s):  
M. Monge-Palacios ◽  
Homayoon Rafatijo

We have identified a new initial reaction in hydrogen combustion with a low barrier height and thus competitive: 2O2 + H2 → 2HO2.


2016 ◽  
Vol 2 (8) ◽  
pp. 1600171 ◽  
Author(s):  
Tiejun Zhu ◽  
Guanting Yu ◽  
Jing Xu ◽  
Haijun Wu ◽  
Chenguang Fu ◽  
...  

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