Mg–Ti co-doping behavior of porous LiFePO4 microspheres for high-rate lithium-ion batteries

2017 ◽  
Vol 5 (32) ◽  
pp. 17021-17028 ◽  
Author(s):  
Jiguo Tu ◽  
Kai Wu ◽  
Hui Tang ◽  
Henghui Zhou ◽  
Shuqiang Jiao

Porous Mg–Ti co-doped LiFePO4 microspheres are successfully synthesized through the feasible carbothermic reduction reaction combined with the spray drying process, showing excellent high-rate cycling stability.

2021 ◽  
Author(s):  
H. Q. Wang ◽  
Anjie Lai ◽  
Dequan Huang ◽  
Youqi Chu ◽  
Si-Jiang Hu ◽  
...  

Lithium iron phosphate (LFP) has become one of the current mainstream cathode materials due to its high safety and low price. Most methods (e.g. ion doping, carbon coating and particle...


2018 ◽  
Vol 401 ◽  
pp. 142-148 ◽  
Author(s):  
Jiebing Wu ◽  
Youlong Xu ◽  
Yanjun Chen ◽  
Long Li ◽  
Hui Wang ◽  
...  

2018 ◽  
Vol 42 (16) ◽  
pp. 13667-13673 ◽  
Author(s):  
Shuting Sun ◽  
Ruhong Li ◽  
Deying Mu ◽  
Zeyu Lin ◽  
Yuanpeng Ji ◽  
...  

Combining XRD with 31P NMR, it is demonstrated that the Mg and Cl atoms of the new Mg and Cl co-doped Li3V2(PO4)3/C material occupy V and O sites in its structure, respectively.


2018 ◽  
Vol 44 (3) ◽  
pp. 2683-2690 ◽  
Author(s):  
Ji-Hyun Park ◽  
Seok-Won Kang ◽  
Tae-Soon Kwon ◽  
Ho Seok Park

2013 ◽  
Vol 724-725 ◽  
pp. 1067-1070
Author(s):  
Ning Yu Gu ◽  
Yang Li ◽  
Chao Li

To enhance the electrochemical performance of LiFePO4/C, Na and V have been co-doped in cathode material of the lithium ion batteries. A series of Na and V doped samples Li0.97Na0.03Fe(1-x)VxPO4/C (x=0, 0.01, 0.03, 0.05) cathode materials are synthesized by solid state method. Results show that the Li0.97Na0.03Fe0.97V0.03PO4/C exhibited the best electrochemical performances.


2020 ◽  
Vol 27 ◽  
pp. 387-395 ◽  
Author(s):  
Dongdong Wang ◽  
Hongxia Liu ◽  
Zhongqiang Shan ◽  
Dawei Xia ◽  
Ren Na ◽  
...  

2019 ◽  
Vol 11 (29) ◽  
pp. 25804-25816 ◽  
Author(s):  
Yanan Li ◽  
Qianlin Chen ◽  
Qiangqiang Meng ◽  
Shulai Lei ◽  
Cuiqin Li ◽  
...  

2021 ◽  
Vol 11 (1) ◽  
pp. 244-251
Author(s):  
Lifeng Cui ◽  
Haoyu Qi ◽  
Nannan Wang ◽  
Xin Gao ◽  
Chunyu Song ◽  
...  

Abstract The transition metal selenide can be used as a potential material for the negative electrode of lithium-ion batteries (LIBs) owing to its high density and conductivity. Unfortunately, a large volume change occurs in the transition metal selenide during the charging and discharging process, which eventually results in the poor rate performance and rapid capacity decay. In response to this, the N/S co-doped CoSe nanocubes (CoSe/C–NS) can be fabricated where the S-doped cobalt 2-methylimidazole (ZIF-67) as both sacrifice template and cobalt source to directly mix with selenium powder and followed by the annealing process. In the process, the carbon frameworks derived from ZIF-67 can establish a coating layer to protect the structure of materials, and simultaneously the N/S co-doping can enhance the conductivity and broaden the interlayer of frameworks. These can further accelerate the storage capacity and the Li+ insertion and deintercalation process. As a negative electrode material of LIBs, the CoSe/C–NS delivers the high capacity, high rate performance, and long-term cycle stability. This protocol opens up an approvable approach to fabricate efficient anode materials with persistent electrochemical stability in LIBs.


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